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Article: Photocatalytic and aerobic oxidation of saturated alkanes by a neutral luminescent trans-dioxoosmium(vi) complex [OsO2(CN)2(dpphen)]

TitlePhotocatalytic and aerobic oxidation of saturated alkanes by a neutral luminescent trans-dioxoosmium(vi) complex [OsO2(CN)2(dpphen)]
Authors
Issue Date1997
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Chemical Communications, 1997 n. 15, p. 1443-1444 How to Cite?
AbstractA neutral trans-dioxoosmium(vi) complex [OsO2(CN)2(dp-phen)] (dpphen = 4,7-diphenyl-1,10-phenanthroline) is prepared and characterized by X-ray crystal analysis; the excited state is long-lived, emissive and oxidizing [E°(OsVI-V) = 2.15 V vs. NHE; lifetime = 0.95 μs; quantum yield = 5 × 10-4; λem(max.) = 650 nm]; under UV-VIS irradiation and in the presence of dioxygen, cyclohexane is oxidized to cyclohexanol and cyclohexanone with a turnover number of 16; secondary C-H bonds of propane and primary C-H bonds of n-hexane are also oxidized.
Persistent Identifierhttp://hdl.handle.net/10722/69463
ISSN
2015 Impact Factor: 6.567
2015 SCImago Journal Rankings: 2.771
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorCheng, JYKen_HK
dc.contributor.authorCheung, KKen_HK
dc.contributor.authorChe, CMen_HK
dc.contributor.authorLau, TCen_HK
dc.date.accessioned2010-09-06T06:13:53Z-
dc.date.available2010-09-06T06:13:53Z-
dc.date.issued1997en_HK
dc.identifier.citationChemical Communications, 1997 n. 15, p. 1443-1444en_HK
dc.identifier.issn1359-7345en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69463-
dc.description.abstractA neutral trans-dioxoosmium(vi) complex [OsO2(CN)2(dp-phen)] (dpphen = 4,7-diphenyl-1,10-phenanthroline) is prepared and characterized by X-ray crystal analysis; the excited state is long-lived, emissive and oxidizing [E°(OsVI-V) = 2.15 V vs. NHE; lifetime = 0.95 μs; quantum yield = 5 × 10-4; λem(max.) = 650 nm]; under UV-VIS irradiation and in the presence of dioxygen, cyclohexane is oxidized to cyclohexanol and cyclohexanone with a turnover number of 16; secondary C-H bonds of propane and primary C-H bonds of n-hexane are also oxidized.en_HK
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_HK
dc.relation.ispartofChemical Communicationsen_HK
dc.titlePhotocatalytic and aerobic oxidation of saturated alkanes by a neutral luminescent trans-dioxoosmium(vi) complex [OsO2(CN)2(dpphen)]en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-4936&volume=&spage=1443&epage=1444&date=1997&atitle=Photocatalytic+and+aerobic+oxidation+of+saturated+alkanes+by+a+neutral+luminescent+trans-dioxoosmium(VI)+complex+[OsO2(CN)2(dpphen)]en_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/A700702G-
dc.identifier.scopuseid_2-s2.0-0042810209en_HK
dc.identifier.hkuros27142en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0042810209&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.issue15en_HK
dc.identifier.spage1443en_HK
dc.identifier.epage1444en_HK
dc.identifier.isiWOS:A1997XP04700054-
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridCheng, JYK=7405940807en_HK
dc.identifier.scopusauthoridCheung, KK=7402406613en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.scopusauthoridLau, TC=7102222310en_HK

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