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Article: A novel one-dimensional Ni(II)-Fe(II) polymer containing µ3-cyanides: [Ni(cyclen]2[Fe(CN)6].8H2O

TitleA novel one-dimensional Ni(II)-Fe(II) polymer containing µ3-cyanides: [Ni(cyclen]2[Fe(CN)6].8H2O
Authors
KeywordsChemical binding
Magnetism
Molecular dynamics
Temperature dependence
X ray crystallography
Issue Date2002
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/njc
Citation
New Journal of Chemistry, 2002, v. 26, p. 1099-1101 How to Cite?
AbstractReaction of K4[Fe(CN)6] with Ni(CH3COO)2 and cyclen produced an unusual one-dimensional paramagnetic complex, [Ni(cyclen)]2[Fe(CN)6]·8H2O (cyclen = 1,4,7,10-tetraazacyclododecane), that consists of [Ni(cyclen)]2 dimers bridged by μ3-cyanides from [Fe(CN)6]4−. The NiNi distance is 3.303 Å, which is significantly shorter than the corresponding distance of 3.449 Å in [Ni2(μ-N3)2(232-tet)2](PF6)2. Moderate antiferromagnetic coupling occurs between the Ni2+ ions.
Persistent Identifierhttp://hdl.handle.net/10722/69459
ISSN
2015 Impact Factor: 3.277
2015 SCImago Journal Rankings: 0.987
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorShek, IPYen_HK
dc.contributor.authorWong, WTen_HK
dc.contributor.authorGao, Sen_HK
dc.contributor.authorLau, TCen_HK
dc.date.accessioned2010-09-06T06:13:51Z-
dc.date.available2010-09-06T06:13:51Z-
dc.date.issued2002en_HK
dc.identifier.citationNew Journal of Chemistry, 2002, v. 26, p. 1099-1101en_HK
dc.identifier.issn1144-0546en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69459-
dc.description.abstractReaction of K4[Fe(CN)6] with Ni(CH3COO)2 and cyclen produced an unusual one-dimensional paramagnetic complex, [Ni(cyclen)]2[Fe(CN)6]·8H2O (cyclen = 1,4,7,10-tetraazacyclododecane), that consists of [Ni(cyclen)]2 dimers bridged by μ3-cyanides from [Fe(CN)6]4−. The NiNi distance is 3.303 Å, which is significantly shorter than the corresponding distance of 3.449 Å in [Ni2(μ-N3)2(232-tet)2](PF6)2. Moderate antiferromagnetic coupling occurs between the Ni2+ ions.-
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/njcen_HK
dc.relation.ispartofNew Journal of Chemistryen_HK
dc.subjectChemical binding-
dc.subjectMagnetism-
dc.subjectMolecular dynamics-
dc.subjectTemperature dependence-
dc.subjectX ray crystallography-
dc.titleA novel one-dimensional Ni(II)-Fe(II) polymer containing µ3-cyanides: [Ni(cyclen]2[Fe(CN)6].8H2Oen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1144-0546&volume=26&spage=1099&epage=1101&date=2002&atitle=A+novel+one-dimensional+Ni(II)-Fe(II)+polymer+containing+m3-cyanides:++[Ni(cyclen]2[Fe(CN)6].8H2Oen_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1039/B203077B-
dc.identifier.scopuseid_2-s2.0-0036376176-
dc.identifier.hkuros75905en_HK
dc.identifier.volume26-
dc.identifier.spage1099-
dc.identifier.epage1101-
dc.identifier.isiWOS:000177603300003-
dc.publisher.placeUnited Kingdom-

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