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- Publisher Website: 10.1039/B203077B
- Scopus: eid_2-s2.0-0036376176
- WOS: WOS:000177603300003
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Article: A novel one-dimensional Ni(II)-Fe(II) polymer containing µ3-cyanides: [Ni(cyclen]2[Fe(CN)6].8H2O
| Title | A novel one-dimensional Ni(II)-Fe(II) polymer containing µ3-cyanides: [Ni(cyclen]2[Fe(CN)6].8H2O |
|---|---|
| Authors | |
| Keywords | Chemical binding Magnetism Molecular dynamics Temperature dependence X ray crystallography |
| Issue Date | 2002 |
| Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/njc |
| Citation | New Journal of Chemistry, 2002, v. 26, p. 1099-1101 How to Cite? |
| Abstract | Reaction of K4[Fe(CN)6] with Ni(CH3COO)2 and cyclen produced an unusual one-dimensional paramagnetic complex, [Ni(cyclen)]2[Fe(CN)6]·8H2O (cyclen = 1,4,7,10-tetraazacyclododecane), that consists of [Ni(cyclen)]2 dimers bridged by μ3-cyanides from [Fe(CN)6]4−. The NiNi distance is 3.303 Å, which is significantly shorter than the corresponding distance of 3.449 Å in [Ni2(μ-N3)2(232-tet)2](PF6)2. Moderate antiferromagnetic coupling occurs between the Ni2+ ions. |
| Persistent Identifier | http://hdl.handle.net/10722/69459 |
| ISSN | 2023 Impact Factor: 2.7 2023 SCImago Journal Rankings: 0.521 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Shek, IPY | en_HK |
| dc.contributor.author | Wong, WT | en_HK |
| dc.contributor.author | Gao, S | en_HK |
| dc.contributor.author | Lau, TC | en_HK |
| dc.date.accessioned | 2010-09-06T06:13:51Z | - |
| dc.date.available | 2010-09-06T06:13:51Z | - |
| dc.date.issued | 2002 | en_HK |
| dc.identifier.citation | New Journal of Chemistry, 2002, v. 26, p. 1099-1101 | en_HK |
| dc.identifier.issn | 1144-0546 | en_HK |
| dc.identifier.uri | http://hdl.handle.net/10722/69459 | - |
| dc.description.abstract | Reaction of K4[Fe(CN)6] with Ni(CH3COO)2 and cyclen produced an unusual one-dimensional paramagnetic complex, [Ni(cyclen)]2[Fe(CN)6]·8H2O (cyclen = 1,4,7,10-tetraazacyclododecane), that consists of [Ni(cyclen)]2 dimers bridged by μ3-cyanides from [Fe(CN)6]4−. The NiNi distance is 3.303 Å, which is significantly shorter than the corresponding distance of 3.449 Å in [Ni2(μ-N3)2(232-tet)2](PF6)2. Moderate antiferromagnetic coupling occurs between the Ni2+ ions. | - |
| dc.language | eng | en_HK |
| dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/njc | en_HK |
| dc.relation.ispartof | New Journal of Chemistry | en_HK |
| dc.subject | Chemical binding | - |
| dc.subject | Magnetism | - |
| dc.subject | Molecular dynamics | - |
| dc.subject | Temperature dependence | - |
| dc.subject | X ray crystallography | - |
| dc.title | A novel one-dimensional Ni(II)-Fe(II) polymer containing µ3-cyanides: [Ni(cyclen]2[Fe(CN)6].8H2O | en_HK |
| dc.type | Article | en_HK |
| dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1144-0546&volume=26&spage=1099&epage=1101&date=2002&atitle=A+novel+one-dimensional+Ni(II)-Fe(II)+polymer+containing+m3-cyanides:++[Ni(cyclen]2[Fe(CN)6].8H2O | en_HK |
| dc.identifier.email | Wong, WT: wtwong@hku.hk | en_HK |
| dc.identifier.authority | Wong, WT=rp00811 | en_HK |
| dc.identifier.doi | 10.1039/B203077B | - |
| dc.identifier.scopus | eid_2-s2.0-0036376176 | - |
| dc.identifier.hkuros | 75905 | en_HK |
| dc.identifier.volume | 26 | - |
| dc.identifier.spage | 1099 | - |
| dc.identifier.epage | 1101 | - |
| dc.identifier.isi | WOS:000177603300003 | - |
| dc.publisher.place | United Kingdom | - |
| dc.identifier.issnl | 1144-0546 | - |