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Article: Synthesis of a novel planar hexaosmium carbonyl cluster: crystal structure of [HOs6(CO) 20(μ-η2-NC5H4CH=CH)]

TitleSynthesis of a novel planar hexaosmium carbonyl cluster: crystal structure of [HOs6(CO) 20(μ-η2-NC5H4CH=CH)]
Authors
KeywordsSynthesis
Carbonyl cluster
Crystal structure
Alkylidyne cluster
Issue Date1996
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal of Organometallic Chemistry, 1996, v. 513 n. 1-2, p. 27-29 How to Cite?
AbstractThe alkylidyne cluster [H2Os3(CO)9(μ-3-CNC5H4CH=CH2)] (1) reacts with the triosmium cluster [Os3(CO)10(NCMe)2] to yield the 94-electron organometallic cluster [HOs6(CO)20(μ-η2-NC5H4CH=CH)] (3). Complex 3 has been shown by X-ray structure analysis to possess an unprecedented planar Os6 metal geometry in which an open triosmium chain is fused to an edge of an osmium triangle through two Os-Os bonds and bridging hydride.
Persistent Identifierhttp://hdl.handle.net/10722/69452
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorWong, WYen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:13:47Z-
dc.date.available2010-09-06T06:13:47Z-
dc.date.issued1996en_HK
dc.identifier.citationJournal of Organometallic Chemistry, 1996, v. 513 n. 1-2, p. 27-29en_HK
dc.identifier.issn0022-328Xen_HK
dc.identifier.urihttp://hdl.handle.net/10722/69452-
dc.description.abstractThe alkylidyne cluster [H2Os3(CO)9(μ-3-CNC5H4CH=CH2)] (1) reacts with the triosmium cluster [Os3(CO)10(NCMe)2] to yield the 94-electron organometallic cluster [HOs6(CO)20(μ-η2-NC5H4CH=CH)] (3). Complex 3 has been shown by X-ray structure analysis to possess an unprecedented planar Os6 metal geometry in which an open triosmium chain is fused to an edge of an osmium triangle through two Os-Os bonds and bridging hydride.-
dc.languageengen_HK
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchemen_HK
dc.relation.ispartofJournal of Organometallic Chemistryen_HK
dc.rightsNOTICE: this is the author’s version of a work that was accepted for publication in <Journal title>. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in PUBLICATION, [VOL#, ISSUE#, (DATE)] DOI#-
dc.subjectSynthesis-
dc.subjectCarbonyl cluster-
dc.subjectCrystal structure-
dc.subjectAlkylidyne cluster-
dc.titleSynthesis of a novel planar hexaosmium carbonyl cluster: crystal structure of [HOs6(CO) 20(μ-η2-NC5H4CH=CH)]en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=513&spage=27&epage=29&date=1996&atitle=Synthesis+of+a+novel+planar+hexaosmium+carbonyl+cluster:++crystal+structure+of+[HOs6(CO)20(m-h2-NC5H4CH=CH)]en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1016/0022-328X(95)05824-9-
dc.identifier.scopuseid_2-s2.0-0030567464-
dc.identifier.hkuros21863en_HK
dc.identifier.volume513-
dc.identifier.issue1-2-
dc.identifier.spage27-
dc.identifier.epage29-
dc.identifier.isiWOS:A1996UP36400004-
dc.publisher.placeSwitzerland-

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