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Article: Metal containing polymers with heterocyclic rigid main chains

TitleMetal containing polymers with heterocyclic rigid main chains
Authors
KeywordsConjugated polymers
Heterocycles
Metal complexes
Opto-electronics
Issue Date2007
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ccr
Citation
Coordination Chemistry Reviews, 2007, v. 251 n. 17-20, p. 2104-2118 How to Cite?
AbstractThis paper provides an overview on some metal containing polymers that contain heterocyclic systems and metal complexes on the main chain. Heterocycles such as 1,3,4-oxadiazoles, quinoxaline, dipyridophenazine, and benzimidazole may enhance the electron carrier mobilities of the polymers, while the incorporation of ruthenium or rhenium diimine complexes to a conjugated polymer may change the photophysical properties of the resulting polymers significantly. The heterocyclic conjugated main chain can be constructed by condensation ring closure or metal catalyzed coupling reactions. Polymers that contain bidentate or tridentate ligands on the main chain were used for metal coordination. These metal containing polymers have found potential applications in organic opto-electronic devices such as light emitting diodes, optical detectors, and photovoltaic cells. Some metal containing rigid rod polymers based on non-conjugated main chain will also be presented. Metal containing polyimides, polyamides, and polyesters exhibit good thermal stability due to the rigid main chain. Some of them also exhibit thermotropic and lyotropic liquid crystal properties. The effect of incorporating metal complex to the physical properties of the polymers was investigated. © 2007 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/69447
ISSN
2015 Impact Factor: 12.994
2015 SCImago Journal Rankings: 4.100
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorChan, WKen_HK
dc.date.accessioned2010-09-06T06:13:45Z-
dc.date.available2010-09-06T06:13:45Z-
dc.date.issued2007en_HK
dc.identifier.citationCoordination Chemistry Reviews, 2007, v. 251 n. 17-20, p. 2104-2118en_HK
dc.identifier.issn0010-8545en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69447-
dc.description.abstractThis paper provides an overview on some metal containing polymers that contain heterocyclic systems and metal complexes on the main chain. Heterocycles such as 1,3,4-oxadiazoles, quinoxaline, dipyridophenazine, and benzimidazole may enhance the electron carrier mobilities of the polymers, while the incorporation of ruthenium or rhenium diimine complexes to a conjugated polymer may change the photophysical properties of the resulting polymers significantly. The heterocyclic conjugated main chain can be constructed by condensation ring closure or metal catalyzed coupling reactions. Polymers that contain bidentate or tridentate ligands on the main chain were used for metal coordination. These metal containing polymers have found potential applications in organic opto-electronic devices such as light emitting diodes, optical detectors, and photovoltaic cells. Some metal containing rigid rod polymers based on non-conjugated main chain will also be presented. Metal containing polyimides, polyamides, and polyesters exhibit good thermal stability due to the rigid main chain. Some of them also exhibit thermotropic and lyotropic liquid crystal properties. The effect of incorporating metal complex to the physical properties of the polymers was investigated. © 2007 Elsevier B.V. All rights reserved.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ccren_HK
dc.relation.ispartofCoordination Chemistry Reviewsen_HK
dc.rightsCoordination Chemistry Reviews. Copyright © Elsevier BV.en_HK
dc.subjectConjugated polymersen_HK
dc.subjectHeterocyclesen_HK
dc.subjectMetal complexesen_HK
dc.subjectOpto-electronicsen_HK
dc.titleMetal containing polymers with heterocyclic rigid main chainsen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0010-8545&volume=251&spage=2104&epage=2118&date=2007&atitle=Metal+containing+polymers+with+heterocyclic+rigid+main+chainsen_HK
dc.identifier.emailChan, WK:waichan@hku.hken_HK
dc.identifier.authorityChan, WK=rp00667en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.ccr.2007.03.002en_HK
dc.identifier.scopuseid_2-s2.0-34548543190en_HK
dc.identifier.hkuros144202en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-34548543190&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume251en_HK
dc.identifier.issue17-20en_HK
dc.identifier.spage2104en_HK
dc.identifier.epage2118en_HK
dc.identifier.isiWOS:000250605400002-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridChan, WK=13310083000en_HK

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