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Article: Synthesis, characterization, molecular and crystal structure of osmium-rhodium mixed-metal carbide cluster, [Os5Rh(µ5-C)(µ3-CO)(CO)13Cp*]

TitleSynthesis, characterization, molecular and crystal structure of osmium-rhodium mixed-metal carbide cluster, [Os5Rh(µ5-C)(µ3-CO)(CO)13Cp*]
Authors
KeywordsOsmium
Rhodium
Carbide
X-ray crystallography
Issue Date2003
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/inoche
Citation
Inorganic Chemistry Communications, 2003, v. 6 n. 6, p. 733-736 How to Cite?
AbstractThe hexanuclear osmium–rhodium carbonyl carbide cluster [Os5Rh(µ5-C)(µ3-CO)(CO)13Cp*]3 has been synthesized in 66% yield by the ionic coupling reaction of [N(PPh3)2]2[Os5C(CO)14]1 with [Rh2(Cp*)2][BF4)22. An X-ray analysis on 3 showed a square based pyramidal metal skeleton with a μ3-CO bridging a RhOs2 triangular face.
Persistent Identifierhttp://hdl.handle.net/10722/69437
ISSN
2015 Impact Factor: 1.762
2015 SCImago Journal Rankings: 0.489
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorLau, PKJen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:13:39Z-
dc.date.available2010-09-06T06:13:39Z-
dc.date.issued2003en_HK
dc.identifier.citationInorganic Chemistry Communications, 2003, v. 6 n. 6, p. 733-736en_HK
dc.identifier.issn1387-7003en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69437-
dc.description.abstractThe hexanuclear osmium–rhodium carbonyl carbide cluster [Os5Rh(µ5-C)(µ3-CO)(CO)13Cp*]3 has been synthesized in 66% yield by the ionic coupling reaction of [N(PPh3)2]2[Os5C(CO)14]1 with [Rh2(Cp*)2][BF4)22. An X-ray analysis on 3 showed a square based pyramidal metal skeleton with a μ3-CO bridging a RhOs2 triangular face.-
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/inocheen_HK
dc.relation.ispartofInorganic Chemistry Communicationsen_HK
dc.subjectOsmium-
dc.subjectRhodium-
dc.subjectCarbide-
dc.subjectX-ray crystallography-
dc.titleSynthesis, characterization, molecular and crystal structure of osmium-rhodium mixed-metal carbide cluster, [Os5Rh(µ5-C)(µ3-CO)(CO)13Cp*]en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1387-7003&volume=6&spage=733&epage=736&date=2003&atitle=Synthesis,+characterization,+molecular+and+crystal+structure+of+osmium-rhodium+mixed-metal+carbide+cluster,+[Os5Rh(m5-C)(m3-CO)(CO)13Cp*]en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1016/S1387-7003(03)00095-9-
dc.identifier.scopuseid_2-s2.0-0037730136-
dc.identifier.hkuros76342en_HK
dc.identifier.volume6-
dc.identifier.issue6-
dc.identifier.spage733-
dc.identifier.epage736-
dc.identifier.isiWOS:000182649500029-

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