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- Publisher Website: 10.1016/S1387-7003(03)00095-9
- Scopus: eid_2-s2.0-0037730136
- WOS: WOS:000182649500029
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Article: Synthesis, characterization, molecular and crystal structure of osmium-rhodium mixed-metal carbide cluster, [Os5Rh(µ5-C)(µ3-CO)(CO)13Cp*]
| Title | Synthesis, characterization, molecular and crystal structure of osmium-rhodium mixed-metal carbide cluster, [Os5Rh(µ5-C)(µ3-CO)(CO)13Cp*] |
|---|---|
| Authors | |
| Keywords | Osmium Rhodium Carbide X-ray crystallography |
| Issue Date | 2003 |
| Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/inoche |
| Citation | Inorganic Chemistry Communications, 2003, v. 6 n. 6, p. 733-736 How to Cite? |
| Abstract | The hexanuclear osmium–rhodium carbonyl carbide cluster [Os5Rh(µ5-C)(µ3-CO)(CO)13Cp*]3 has been synthesized in 66% yield by the ionic coupling reaction of [N(PPh3)2]2[Os5C(CO)14]1 with [Rh2(Cp*)2][BF4)22. An X-ray analysis on 3 showed a square based pyramidal metal skeleton with a μ3-CO bridging a RhOs2 triangular face. |
| Persistent Identifier | http://hdl.handle.net/10722/69437 |
| ISSN | 2023 Impact Factor: 4.4 2023 SCImago Journal Rankings: 0.642 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Lau, PKJ | en_HK |
| dc.contributor.author | Wong, WT | en_HK |
| dc.date.accessioned | 2010-09-06T06:13:39Z | - |
| dc.date.available | 2010-09-06T06:13:39Z | - |
| dc.date.issued | 2003 | en_HK |
| dc.identifier.citation | Inorganic Chemistry Communications, 2003, v. 6 n. 6, p. 733-736 | en_HK |
| dc.identifier.issn | 1387-7003 | en_HK |
| dc.identifier.uri | http://hdl.handle.net/10722/69437 | - |
| dc.description.abstract | The hexanuclear osmium–rhodium carbonyl carbide cluster [Os5Rh(µ5-C)(µ3-CO)(CO)13Cp*]3 has been synthesized in 66% yield by the ionic coupling reaction of [N(PPh3)2]2[Os5C(CO)14]1 with [Rh2(Cp*)2][BF4)22. An X-ray analysis on 3 showed a square based pyramidal metal skeleton with a μ3-CO bridging a RhOs2 triangular face. | - |
| dc.language | eng | en_HK |
| dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/inoche | en_HK |
| dc.relation.ispartof | Inorganic Chemistry Communications | en_HK |
| dc.subject | Osmium | - |
| dc.subject | Rhodium | - |
| dc.subject | Carbide | - |
| dc.subject | X-ray crystallography | - |
| dc.title | Synthesis, characterization, molecular and crystal structure of osmium-rhodium mixed-metal carbide cluster, [Os5Rh(µ5-C)(µ3-CO)(CO)13Cp*] | en_HK |
| dc.type | Article | en_HK |
| dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1387-7003&volume=6&spage=733&epage=736&date=2003&atitle=Synthesis,+characterization,+molecular+and+crystal+structure+of+osmium-rhodium+mixed-metal+carbide+cluster,+[Os5Rh(m5-C)(m3-CO)(CO)13Cp*] | en_HK |
| dc.identifier.email | Wong, WT: wtwong@hku.hk | en_HK |
| dc.identifier.authority | Wong, WT=rp00811 | en_HK |
| dc.identifier.doi | 10.1016/S1387-7003(03)00095-9 | - |
| dc.identifier.scopus | eid_2-s2.0-0037730136 | - |
| dc.identifier.hkuros | 76342 | en_HK |
| dc.identifier.volume | 6 | - |
| dc.identifier.issue | 6 | - |
| dc.identifier.spage | 733 | - |
| dc.identifier.epage | 736 | - |
| dc.identifier.isi | WOS:000182649500029 | - |
| dc.identifier.issnl | 1387-7003 | - |