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Article: Facile N...N Coupling of Manganese(V) Imido Species

TitleFacile N...N Coupling of Manganese(V) Imido Species
Authors
Issue Date2007
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.html
Citation
Journal of the American Chemical Society, 2007, v. 129 n. 4, p. 803-809 How to Cite?
Abstract(Salen)manganese(V) nitrido species are activated by electrophiles such as trifluoroacetic anhydride (TFAA) or trifluoroacetic acid (TFA) to produce N2. Mechanistic studies suggest that the manganese(V) nitrido species first react with TFAA or TFA to produce an imido species, which then undergoes N...N coupling. It is proposed that the resulting manganese(III) mu-diazene species decomposes via internal redox to give N2 and manganese(II). The manganese(II) species is then rapidly oxidized by manganese(V) imide to give manganese(III) and CF3CONH2 (for TFAA) or NH3 (for TFA).
Persistent Identifierhttp://hdl.handle.net/10722/69433
ISSN
2015 Impact Factor: 13.038
2015 SCImago Journal Rankings: 7.123
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorYiu, SMen_HK
dc.contributor.authorLam, WWYen_HK
dc.contributor.authorHo, CMen_HK
dc.contributor.authorLau, TCen_HK
dc.date.accessioned2010-09-06T06:13:37Z-
dc.date.available2010-09-06T06:13:37Z-
dc.date.issued2007en_HK
dc.identifier.citationJournal of the American Chemical Society, 2007, v. 129 n. 4, p. 803-809en_HK
dc.identifier.issn0002-7863en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69433-
dc.description.abstract(Salen)manganese(V) nitrido species are activated by electrophiles such as trifluoroacetic anhydride (TFAA) or trifluoroacetic acid (TFA) to produce N2. Mechanistic studies suggest that the manganese(V) nitrido species first react with TFAA or TFA to produce an imido species, which then undergoes N...N coupling. It is proposed that the resulting manganese(III) mu-diazene species decomposes via internal redox to give N2 and manganese(II). The manganese(II) species is then rapidly oxidized by manganese(V) imide to give manganese(III) and CF3CONH2 (for TFAA) or NH3 (for TFA).-
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.htmlen_HK
dc.relation.ispartofJournal of the American Chemical Societyen_HK
dc.subject.meshImides - chemistry-
dc.subject.meshManganese - chemistry-
dc.subject.meshNitrogen - chemistry-
dc.subject.meshOrganometallic Compounds - chemistry-
dc.subject.meshTrifluoroacetic Acid - chemistry-
dc.titleFacile N...N Coupling of Manganese(V) Imido Speciesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0002-7863&volume=129&spage=803&epage=&date=2007&atitle=Facile+N...N+Coupling+of+Manganese(V)+Imido+Speciesen_HK
dc.identifier.emailHo, CM: rickyho@hkucc.hku.hken_HK
dc.identifier.authorityHo, CM=rp00705en_HK
dc.identifier.doi10.1021/ja066440t-
dc.identifier.pmid17243816-
dc.identifier.scopuseid_2-s2.0-33846598539-
dc.identifier.hkuros131667en_HK
dc.identifier.volume129-
dc.identifier.issue4-
dc.identifier.spage803-
dc.identifier.epage809-
dc.identifier.isiWOS:000243683800032-
dc.publisher.placeUnited States-

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