File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1016/S0040-4039(98)02130-3
- Scopus: eid_2-s2.0-0032506682
- WOS: WOS:000077192100033
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: A conjugate reduction-intramolecular aldol strategy toward the synthesis of pseudolaric acid A
Title | A conjugate reduction-intramolecular aldol strategy toward the synthesis of pseudolaric acid A |
---|---|
Authors | |
Keywords | Aldol reactions Copper and compounds Natural products |
Issue Date | 1998 |
Publisher | Pergamon. The Journal's web site is located at http://www.elsevier.com/locate/tetlet |
Citation | Tetrahedron Letters, 1998, v. 39 n. 50, p. 9229-9232 How to Cite? |
Abstract | An unprecedented tandem conjugate reduction-intramolecular aldol cyclization using Stryker's reagent produced diastereomers of 5 from the ketoester precursor 8. Compound 5c with the trans-fused perhydroazulene carboskeleton as in pseudolaric acid A was formed as a minor isomer, while the all-cis 5b was obtained as the major product. The structures of the two diastereomers have been determined by X-ray crystallography. |
Persistent Identifier | http://hdl.handle.net/10722/69432 |
ISSN | 2023 Impact Factor: 1.5 2023 SCImago Journal Rankings: 0.323 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Chiu, P | en_HK |
dc.contributor.author | Chen, B | en_HK |
dc.contributor.author | Cheng, KF | en_HK |
dc.date.accessioned | 2010-09-06T06:13:36Z | - |
dc.date.available | 2010-09-06T06:13:36Z | - |
dc.date.issued | 1998 | en_HK |
dc.identifier.citation | Tetrahedron Letters, 1998, v. 39 n. 50, p. 9229-9232 | en_HK |
dc.identifier.issn | 0040-4039 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/69432 | - |
dc.description.abstract | An unprecedented tandem conjugate reduction-intramolecular aldol cyclization using Stryker's reagent produced diastereomers of 5 from the ketoester precursor 8. Compound 5c with the trans-fused perhydroazulene carboskeleton as in pseudolaric acid A was formed as a minor isomer, while the all-cis 5b was obtained as the major product. The structures of the two diastereomers have been determined by X-ray crystallography. | en_HK |
dc.language | eng | en_HK |
dc.publisher | Pergamon. The Journal's web site is located at http://www.elsevier.com/locate/tetlet | en_HK |
dc.relation.ispartof | Tetrahedron Letters | en_HK |
dc.subject | Aldol reactions | en_HK |
dc.subject | Copper and compounds | en_HK |
dc.subject | Natural products | en_HK |
dc.title | A conjugate reduction-intramolecular aldol strategy toward the synthesis of pseudolaric acid A | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0040-4039&volume=39&spage=9229&epage=9232&date=1998&atitle=A+conjugate+reduction-intramolecular+aldol+strategy+toward+the+synthesis+of+pseudolaric+acid+A | en_HK |
dc.identifier.email | Chiu, P:pchiu@hku.hk | en_HK |
dc.identifier.authority | Chiu, P=rp00680 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/S0040-4039(98)02130-3 | - |
dc.identifier.scopus | eid_2-s2.0-0032506682 | en_HK |
dc.identifier.hkuros | 40351 | en_HK |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0032506682&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 39 | en_HK |
dc.identifier.issue | 50 | en_HK |
dc.identifier.spage | 9229 | en_HK |
dc.identifier.epage | 9232 | en_HK |
dc.identifier.isi | WOS:000077192100033 | - |
dc.publisher.place | United Kingdom | en_HK |
dc.identifier.scopusauthorid | Chiu, P=11140148700 | en_HK |
dc.identifier.scopusauthorid | Chen, B=7408611903 | en_HK |
dc.identifier.scopusauthorid | Cheng, KF=7402997838 | en_HK |
dc.identifier.issnl | 0040-4039 | - |