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Article: Self-assembly of a cyclic metalladecapyridine from the reaction of 2,6-bis(bis(2-pyridyl)methoxymethane)pyridine with silver(I)

TitleSelf-assembly of a cyclic metalladecapyridine from the reaction of 2,6-bis(bis(2-pyridyl)methoxymethane)pyridine with silver(I)
Authors
Issue Date2008
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 2008, v. 47 n. 13, p. 5727-5735 How to Cite?
AbstractReaction of Ag(p-MeC 6H 4SO 3) with 2,6-bis(bis(2-pyridyl)methoxymethane)pyridine (PY5) in CH 2Cl 2 gave [Ag I 2(PY5) 2](p-MeC 6H 4SO 3) 2 (1). Treatment of 2,6-bis(bis(2-pyridyl)hydroxymethane)pyridine (PY5-OH) with AgNO 3 in MeOH gave [Ag I 2(PY5-OH) 2](NO 3) 2 (2); in the presence of PPh 3, this reaction afforded [Ag I(PY5-OH)(PPh 3)]NO 3 (3). The structures of 1-3 have been determined by X-ray crystal analysis, revealing four-coordinate Ag I ions in these complexes. Both 1 and 2 feature a quadruply branched 28-membered C 16N 10M 2 metallamacrocycle fused to 10 pyridyl groups. On the basis of 1H NMR measurements, the dinuclear 1 and 2 dissociate into a mononuclear complex upon dissolving in MeCN but in MeOH an equilibrium between the mono- and dinuclear species can be detected. © 2008 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/69423
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorHuang, JSen_HK
dc.contributor.authorXie, Jen_HK
dc.contributor.authorKui, SCFen_HK
dc.contributor.authorFang, GSen_HK
dc.contributor.authorZhu, Nen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2010-09-06T06:13:31Z-
dc.date.available2010-09-06T06:13:31Z-
dc.date.issued2008en_HK
dc.identifier.citationInorganic Chemistry, 2008, v. 47 n. 13, p. 5727-5735en_HK
dc.identifier.issn0020-1669en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69423-
dc.description.abstractReaction of Ag(p-MeC 6H 4SO 3) with 2,6-bis(bis(2-pyridyl)methoxymethane)pyridine (PY5) in CH 2Cl 2 gave [Ag I 2(PY5) 2](p-MeC 6H 4SO 3) 2 (1). Treatment of 2,6-bis(bis(2-pyridyl)hydroxymethane)pyridine (PY5-OH) with AgNO 3 in MeOH gave [Ag I 2(PY5-OH) 2](NO 3) 2 (2); in the presence of PPh 3, this reaction afforded [Ag I(PY5-OH)(PPh 3)]NO 3 (3). The structures of 1-3 have been determined by X-ray crystal analysis, revealing four-coordinate Ag I ions in these complexes. Both 1 and 2 feature a quadruply branched 28-membered C 16N 10M 2 metallamacrocycle fused to 10 pyridyl groups. On the basis of 1H NMR measurements, the dinuclear 1 and 2 dissociate into a mononuclear complex upon dissolving in MeCN but in MeOH an equilibrium between the mono- and dinuclear species can be detected. © 2008 American Chemical Society.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_HK
dc.relation.ispartofInorganic Chemistryen_HK
dc.titleSelf-assembly of a cyclic metalladecapyridine from the reaction of 2,6-bis(bis(2-pyridyl)methoxymethane)pyridine with silver(I)en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0020-1669&volume=47&spage=5727&epage=5735&date=2008&atitle=Self-assembly+of+a+Cyclic+Metalladecapyridine+from+the+Reaction+of+2,6-Bis(bis(2-Pyridyl)Methoxymethane)+Pyridine+with+Silver(I)+en_HK
dc.identifier.emailHuang, JS: jshuang@hku.hken_HK
dc.identifier.emailKui, SCF: stevenku@hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.authorityHuang, JS=rp00709en_HK
dc.identifier.authorityKui, SCF=rp00715en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ic8000043en_HK
dc.identifier.pmid18549201en_HK
dc.identifier.scopuseid_2-s2.0-47949133573en_HK
dc.identifier.hkuros145185en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-47949133573&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume47en_HK
dc.identifier.issue13en_HK
dc.identifier.spage5727en_HK
dc.identifier.epage5735en_HK
dc.identifier.eissn1520-510X-
dc.identifier.isiWOS:000257278000035-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridHuang, JS=7407192639en_HK
dc.identifier.scopusauthoridXie, J=55478195600en_HK
dc.identifier.scopusauthoridKui, SCF=6506763660en_HK
dc.identifier.scopusauthoridFang, GS=7201871289en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK

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