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Article: Synthesis and characterization of high-nuclearity osmium–rhodium mixed-metal carbonyl clusters; molecular and crystal structures of [Os12Rh9(CO)44(µ3-Cl)]·2CH2Cl2 and [Os4Rh3(µ3-H)(CO)14(µ3-CO)(η4-C7H8)2]

TitleSynthesis and characterization of high-nuclearity osmium–rhodium mixed-metal carbonyl clusters; molecular and crystal structures of [Os12Rh9(CO)44(µ3-Cl)]·2CH2Cl2 and [Os4Rh3(µ3-H)(CO)14(µ3-CO)(η4-C7H8)2]
Authors
Issue Date1997
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Chemical Communications, 1997, n. 21, p. 2099-2100 How to Cite?
AbstractThe anionic triosmium cluster [N(PPh3)2][Os3(µ-H)(CO)11] reacts with [Rh(nbd)Cl)2 (nbd = norbornadiene) in the presence of AgPF6 to give two new high-nuclearity osmium–rhodium clusters [Os12Rh9(CO)44(µ3-Cl)] 1 and [Os4Rh3(µ3-H)(CO)14(µ3-CO)(η4-C7H8)2] 2 in moderate yields.
Persistent Identifierhttp://hdl.handle.net/10722/69414
ISSN
2015 Impact Factor: 6.567
2015 SCImago Journal Rankings: 2.771
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorHung, SYWen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:13:26Z-
dc.date.available2010-09-06T06:13:26Z-
dc.date.issued1997en_HK
dc.identifier.citationChemical Communications, 1997, n. 21, p. 2099-2100en_HK
dc.identifier.issn1359-7345en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69414-
dc.description.abstractThe anionic triosmium cluster [N(PPh3)2][Os3(µ-H)(CO)11] reacts with [Rh(nbd)Cl)2 (nbd = norbornadiene) in the presence of AgPF6 to give two new high-nuclearity osmium–rhodium clusters [Os12Rh9(CO)44(µ3-Cl)] 1 and [Os4Rh3(µ3-H)(CO)14(µ3-CO)(η4-C7H8)2] 2 in moderate yields.-
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_HK
dc.relation.ispartofChemical Communicationsen_HK
dc.titleSynthesis and characterization of high-nuclearity osmium–rhodium mixed-metal carbonyl clusters; molecular and crystal structures of [Os12Rh9(CO)44(µ3-Cl)]·2CH2Cl2 and [Os4Rh3(µ3-H)(CO)14(µ3-CO)(η4-C7H8)2]en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1359-7345&volume=&spage=2099&epage=2100&date=1997&atitle=Synthesis+and+characterization+of+high-nuclearity+osmium-rhodium+mixed-metal+carbonyl+clusters;++molecular+and+crystal+structures+of+[Os12Rh9(CO)44(m3-Cl)].2CH2Cl2+and+[Os4Rh3(m3-H)(CO)14(m3-CO)(h4en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1039/A706080G-
dc.identifier.hkuros31382en_HK
dc.identifier.issue21-
dc.identifier.spage2099-
dc.identifier.epage2100-
dc.identifier.isiWOS:A1997YE61100040-
dc.publisher.placeUnited Kingdom-

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