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Article: Synthesis, characterization, ion-binding properties, and fluorescence resonance energy transfer behavior of rhenium(I) complexes containing a coumarin-appended 2,2′-Bipyridine

TitleSynthesis, characterization, ion-binding properties, and fluorescence resonance energy transfer behavior of rhenium(I) complexes containing a coumarin-appended 2,2′-Bipyridine
Authors
Issue Date2009
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jpccck/
Citation
Journal Of Physical Chemistry C, 2009, v. 113 n. 27, p. 11674-11682 How to Cite?
Abstract
A series of luminescent rhenium(I) complexes of 2,2'-bipyridine appended with a coumarin fluorophore has been successfully synthesized and characterized. Their photophysical behavior, ion-binding properties, and fluorescence resonance energy transfer (FRET) behavior from the coumarin donor to the rhenium(I) bipyridyl acceptor were studied. The FRET efficiencies were found to vary upon addition of various metal ions with different sizes due to conformational changes. Their stability constants have been determined by both UV-visible and luminescence spectrophotometric methods. ©2009 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/69408
ISSN
2013 Impact Factor: 4.835
ISI Accession Number ID
Funding AgencyGrant Number
Jilin University
The University of Hong Kong
National Natural Science Foundation of China
Research Grants Council of Hong Kong Joint Research SchemeN_HKU 737/06
Funding Information:

V.W.-W.Y. acknowledges support under of the Disfinguished Research Achievement Achievement Award Scheme from The University of Hong Kong. We acknowledge support from Jilin University and The University of Hong Kong. This work has been supported by the National Natural Science Foundation of China and the Research Grants Council of Hong Kong Joint Research Scheme (NSFC-RGC Project No. N_HKU 737/06).

References
Grants

 

Author Affiliations
  1. Jilin University
  2. The University of Hong Kong
DC FieldValueLanguage
dc.contributor.authorYam, VWWen_HK
dc.contributor.authorSong, HOen_HK
dc.contributor.authorChan, STWen_HK
dc.contributor.authorZhu, Nen_HK
dc.contributor.authorTao, CHen_HK
dc.contributor.authorWong, KMCen_HK
dc.contributor.authorWu, LXen_HK
dc.date.accessioned2010-09-06T06:13:23Z-
dc.date.available2010-09-06T06:13:23Z-
dc.date.issued2009en_HK
dc.identifier.citationJournal Of Physical Chemistry C, 2009, v. 113 n. 27, p. 11674-11682en_HK
dc.identifier.issn1932-7447en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69408-
dc.description.abstractA series of luminescent rhenium(I) complexes of 2,2'-bipyridine appended with a coumarin fluorophore has been successfully synthesized and characterized. Their photophysical behavior, ion-binding properties, and fluorescence resonance energy transfer (FRET) behavior from the coumarin donor to the rhenium(I) bipyridyl acceptor were studied. The FRET efficiencies were found to vary upon addition of various metal ions with different sizes due to conformational changes. Their stability constants have been determined by both UV-visible and luminescence spectrophotometric methods. ©2009 American Chemical Society.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jpccck/en_HK
dc.relation.ispartofJournal of Physical Chemistry Cen_HK
dc.titleSynthesis, characterization, ion-binding properties, and fluorescence resonance energy transfer behavior of rhenium(I) complexes containing a coumarin-appended 2,2′-Bipyridineen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1932-7447&volume=113&issue=27&spage=11674&epage=11682&date=2009&atitle=Synthesis,+characterization,+ion-binding+properties,+and+fluorescence+resonance+energy+transfer+behavior+of+rhenium(I)+complexes+containing+a+coumarin-appended+2,2′-Bipyridineen_HK
dc.identifier.emailYam, VWW: wwyam@hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.emailWong, KMC: wongmc@hku.hken_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.identifier.authorityWong, KMC=rp00809en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/jp901561ven_HK
dc.identifier.scopuseid_2-s2.0-67650822671en_HK
dc.identifier.hkuros168994en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-67650822671&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume113en_HK
dc.identifier.issue27en_HK
dc.identifier.spage11674en_HK
dc.identifier.epage11682en_HK
dc.identifier.isiWOS:000267694900034-
dc.publisher.placeUnited Statesen_HK
dc.relation.projectSynthesis, aggregation and self-assembly of luminescent functional molecules - from solutions to polymers, ordered thin films, inorganic-organic hybrids, and supramolecular and nano-assemblies-
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK
dc.identifier.scopusauthoridSong, HO=28167839200en_HK
dc.identifier.scopusauthoridChan, STW=28067518900en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK
dc.identifier.scopusauthoridTao, CH=7102146421en_HK
dc.identifier.scopusauthoridWong, KMC=8061067200en_HK
dc.identifier.scopusauthoridWu, LX=7404902949en_HK

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