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Article: Transient resonance Raman and density functional theory investigation of the 4-acetamidophenylnitrenium ion

TitleTransient resonance Raman and density functional theory investigation of the 4-acetamidophenylnitrenium ion
Authors
Issue Date2003
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/joc
Citation
Journal Of Organic Chemistry, 2003, v. 68 n. 13, p. 5265-5273 How to Cite?
AbstractThis paper reports a transient resonance Raman and density functional theory study of the 4-acetamidophenylnitrenium ion in a mostly aqueous solvent. The transient Raman bands combined with results from density functional theory calculations indicate that the spectrum should be assigned to the singlet state of the 4-acetamidophenylnitrenium ion. The 4-acetamidophenylnitrenium ion was found to have a substantial iminocyclohexadienyl character comparable to previously studied para-phenyl-substituted phenylnitrenium ions and noticeable charge on both the acetamido and nitrenium moieties. The structure and properties of the 4-acetamidophenylnitrenium ion are compared to those of other arylnitrenium ions. We briefly discuss the chemical reactivity and selectivity of the para-acetamido-substituted phenylnitrenium ions compared to para-phenyl- or para-alkoxy-substituted phenylnitrenium ions.
Persistent Identifierhttp://hdl.handle.net/10722/69375
ISSN
2015 Impact Factor: 4.785
2015 SCImago Journal Rankings: 2.095
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorChan, PYen_HK
dc.contributor.authorOng, SYen_HK
dc.contributor.authorZhu, Pen_HK
dc.contributor.authorLeung, KHen_HK
dc.contributor.authorPhillips, DLen_HK
dc.date.accessioned2010-09-06T06:13:05Z-
dc.date.available2010-09-06T06:13:05Z-
dc.date.issued2003en_HK
dc.identifier.citationJournal Of Organic Chemistry, 2003, v. 68 n. 13, p. 5265-5273en_HK
dc.identifier.issn0022-3263en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69375-
dc.description.abstractThis paper reports a transient resonance Raman and density functional theory study of the 4-acetamidophenylnitrenium ion in a mostly aqueous solvent. The transient Raman bands combined with results from density functional theory calculations indicate that the spectrum should be assigned to the singlet state of the 4-acetamidophenylnitrenium ion. The 4-acetamidophenylnitrenium ion was found to have a substantial iminocyclohexadienyl character comparable to previously studied para-phenyl-substituted phenylnitrenium ions and noticeable charge on both the acetamido and nitrenium moieties. The structure and properties of the 4-acetamidophenylnitrenium ion are compared to those of other arylnitrenium ions. We briefly discuss the chemical reactivity and selectivity of the para-acetamido-substituted phenylnitrenium ions compared to para-phenyl- or para-alkoxy-substituted phenylnitrenium ions.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/jocen_HK
dc.relation.ispartofJournal of Organic Chemistryen_HK
dc.titleTransient resonance Raman and density functional theory investigation of the 4-acetamidophenylnitrenium ionen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-3263&volume=68&issue=13&spage=5265&epage=5273&date=2003&atitle=Transient+resonance+raman+and+density+functional+theory+investigation+of+the+4-acetamidophenylnitrenium+ionen_HK
dc.identifier.emailPhillips, DL:phillips@hku.hken_HK
dc.identifier.authorityPhillips, DL=rp00770en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/jo0300439en_HK
dc.identifier.scopuseid_2-s2.0-0038548096en_HK
dc.identifier.hkuros80997en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0038548096&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume68en_HK
dc.identifier.issue13en_HK
dc.identifier.spage5265en_HK
dc.identifier.epage5273en_HK
dc.identifier.isiWOS:000183669800036-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridChan, PY=7403497922en_HK
dc.identifier.scopusauthoridOng, SY=7202336462en_HK
dc.identifier.scopusauthoridZhu, P=7202169049en_HK
dc.identifier.scopusauthoridLeung, KH=7401860609en_HK
dc.identifier.scopusauthoridPhillips, DL=7404519365en_HK

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