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- Scopus: eid_2-s2.0-0347240297
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Article: Synthesis and characterization of triosmium clusters containing the 2-(benzylthio)benzoyl ligand
Title | Synthesis and characterization of triosmium clusters containing the 2-(benzylthio)benzoyl ligand |
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Authors | |
Keywords | Osmium Crystal structure Acyl Carbonyl Cluster |
Issue Date | 1995 |
Publisher | Elsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem |
Citation | Journal of Organometallic Chemistry, 1995, v. 494 n. 1-2, p. 273-278 How to Cite? |
Abstract | Reaction of [Os3(CO)10(MeCN)2] with an equimolar proportion of 2-(benzylthio)-benzaldehyde (1) gives three new compounds: two yellow isomers of [Os3(CO)10(μ-H)(C14H11OS)] (2a and 2b) and an orange crystalline compound [Os3(CO)9(μ-H)C14H11OS)] (3). The molecular structures of 2b and 3 are presented. Two different kinds of bonding mode of the ligand were observed, bidentate through S and C(O) in 2 and terdentate through S, C(O) and O in 3. |
Persistent Identifier | http://hdl.handle.net/10722/69362 |
ISSN | 2023 Impact Factor: 2.1 2023 SCImago Journal Rankings: 0.359 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Lee, SM | en_HK |
dc.contributor.author | Cheung, KK | en_HK |
dc.contributor.author | Wong, WT | en_HK |
dc.date.accessioned | 2010-09-06T06:12:58Z | - |
dc.date.available | 2010-09-06T06:12:58Z | - |
dc.date.issued | 1995 | en_HK |
dc.identifier.citation | Journal of Organometallic Chemistry, 1995, v. 494 n. 1-2, p. 273-278 | en_HK |
dc.identifier.issn | 0022-328X | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/69362 | - |
dc.description.abstract | Reaction of [Os3(CO)10(MeCN)2] with an equimolar proportion of 2-(benzylthio)-benzaldehyde (1) gives three new compounds: two yellow isomers of [Os3(CO)10(μ-H)(C14H11OS)] (2a and 2b) and an orange crystalline compound [Os3(CO)9(μ-H)C14H11OS)] (3). The molecular structures of 2b and 3 are presented. Two different kinds of bonding mode of the ligand were observed, bidentate through S and C(O) in 2 and terdentate through S, C(O) and O in 3. | - |
dc.language | eng | en_HK |
dc.publisher | Elsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem | en_HK |
dc.relation.ispartof | Journal of Organometallic Chemistry | en_HK |
dc.subject | Osmium | - |
dc.subject | Crystal structure | - |
dc.subject | Acyl | - |
dc.subject | Carbonyl | - |
dc.subject | Cluster | - |
dc.title | Synthesis and characterization of triosmium clusters containing the 2-(benzylthio)benzoyl ligand | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=494&issue=1-2&spage=273&epage=278&date=1995&atitle=Synthesis+and+characterization+of+triosmium+clusters+containing+2-(phenylmethylthio)benzoyl+ligand | en_HK |
dc.identifier.email | Cheung, KK: kkcheung@hkucc.hku.hk | en_HK |
dc.identifier.email | Wong, WT: wtwong@hku.hk | en_HK |
dc.identifier.authority | Wong, WT=rp00811 | en_HK |
dc.identifier.doi | 10.1016/0022-328X(95)05430-W | - |
dc.identifier.scopus | eid_2-s2.0-0347240297 | - |
dc.identifier.hkuros | 1504 | en_HK |
dc.identifier.volume | 494 | - |
dc.identifier.issue | 1-2 | - |
dc.identifier.spage | 273 | - |
dc.identifier.epage | 278 | - |
dc.identifier.isi | WOS:A1995RA32900036 | - |
dc.identifier.issnl | 0022-328X | - |