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Article: Synthesis and characterization of triosmium clusters containing the 2-(benzylthio)benzoyl ligand

TitleSynthesis and characterization of triosmium clusters containing the 2-(benzylthio)benzoyl ligand
Authors
KeywordsOsmium
Crystal structure
Acyl
Carbonyl
Cluster
Issue Date1995
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal of Organometallic Chemistry, 1995, v. 494 n. 1-2, p. 273-278 How to Cite?
AbstractReaction of [Os3(CO)10(MeCN)2] with an equimolar proportion of 2-(benzylthio)-benzaldehyde (1) gives three new compounds: two yellow isomers of [Os3(CO)10(μ-H)(C14H11OS)] (2a and 2b) and an orange crystalline compound [Os3(CO)9(μ-H)C14H11OS)] (3). The molecular structures of 2b and 3 are presented. Two different kinds of bonding mode of the ligand were observed, bidentate through S and C(O) in 2 and terdentate through S, C(O) and O in 3.
Persistent Identifierhttp://hdl.handle.net/10722/69362
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorLee, SMen_HK
dc.contributor.authorCheung, KKen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:12:58Z-
dc.date.available2010-09-06T06:12:58Z-
dc.date.issued1995en_HK
dc.identifier.citationJournal of Organometallic Chemistry, 1995, v. 494 n. 1-2, p. 273-278en_HK
dc.identifier.issn0022-328Xen_HK
dc.identifier.urihttp://hdl.handle.net/10722/69362-
dc.description.abstractReaction of [Os3(CO)10(MeCN)2] with an equimolar proportion of 2-(benzylthio)-benzaldehyde (1) gives three new compounds: two yellow isomers of [Os3(CO)10(μ-H)(C14H11OS)] (2a and 2b) and an orange crystalline compound [Os3(CO)9(μ-H)C14H11OS)] (3). The molecular structures of 2b and 3 are presented. Two different kinds of bonding mode of the ligand were observed, bidentate through S and C(O) in 2 and terdentate through S, C(O) and O in 3.-
dc.languageengen_HK
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchemen_HK
dc.relation.ispartofJournal of Organometallic Chemistryen_HK
dc.subjectOsmium-
dc.subjectCrystal structure-
dc.subjectAcyl-
dc.subjectCarbonyl-
dc.subjectCluster-
dc.titleSynthesis and characterization of triosmium clusters containing the 2-(benzylthio)benzoyl liganden_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=494&issue=1-2&spage=273&epage=278&date=1995&atitle=Synthesis+and+characterization+of+triosmium+clusters+containing+2-(phenylmethylthio)benzoyl+liganden_HK
dc.identifier.emailCheung, KK: kkcheung@hkucc.hku.hken_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1016/0022-328X(95)05430-W-
dc.identifier.hkuros1504en_HK
dc.identifier.volume494-
dc.identifier.issue1-2-
dc.identifier.spage273-
dc.identifier.epage278-
dc.identifier.isiWOS:A1995RA32900036-

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