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Article: Molecular design of transition metal alkynyl complexes as building blocks for luminescent metal-based materials: Structural and photophysical aspects

TitleMolecular design of transition metal alkynyl complexes as building blocks for luminescent metal-based materials: Structural and photophysical aspects
Authors
Issue Date2002
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/achre4/about.html
Citation
Accounts Of Chemical Research, 2002, v. 35 n. 7, p. 555-563 How to Cite?
AbstractIn this Account, the design and successful isolation of a series of soluble di- and polynuclear alkynyl complexes of selected metals with d8 and d10 electronic configurations are described. These organometallic complexes are found to exhibit rich photophysical and photochemical properties that are unique to the presence of the alkynyl ligand. By a systematic variation of the nature of the ligands, the metal centers, and certain structural features, the photophysical properties could be readily varied and their spectroscopic origins elucidated. Some of these complexes have been shown to be ideal building blocks for the design of luminescent organometallic oligomers and metal-based functional materials.
Persistent Identifierhttp://hdl.handle.net/10722/69357
ISSN
2015 Impact Factor: 22.003
2015 SCImago Journal Rankings: 11.465
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_HK
dc.date.accessioned2010-09-06T06:12:55Z-
dc.date.available2010-09-06T06:12:55Z-
dc.date.issued2002en_HK
dc.identifier.citationAccounts Of Chemical Research, 2002, v. 35 n. 7, p. 555-563en_HK
dc.identifier.issn0001-4842en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69357-
dc.description.abstractIn this Account, the design and successful isolation of a series of soluble di- and polynuclear alkynyl complexes of selected metals with d8 and d10 electronic configurations are described. These organometallic complexes are found to exhibit rich photophysical and photochemical properties that are unique to the presence of the alkynyl ligand. By a systematic variation of the nature of the ligands, the metal centers, and certain structural features, the photophysical properties could be readily varied and their spectroscopic origins elucidated. Some of these complexes have been shown to be ideal building blocks for the design of luminescent organometallic oligomers and metal-based functional materials.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/achre4/about.htmlen_HK
dc.relation.ispartofAccounts of Chemical Researchen_HK
dc.titleMolecular design of transition metal alkynyl complexes as building blocks for luminescent metal-based materials: Structural and photophysical aspectsen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0001-4842&volume=35&issue=7&spage=555&epage=563&date=2002&atitle=Molecular+design+of+transition+metal+alkynyl+complexes+as+building+blocks+for+luminescent+metal-based+materials:+structural+and+photophysical+aspectsen_HK
dc.identifier.emailYam, VWW:wwyam@hku.hken_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ar0000758en_HK
dc.identifier.pmid12118995-
dc.identifier.scopuseid_2-s2.0-0036078689en_HK
dc.identifier.hkuros83122en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0036078689&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume35en_HK
dc.identifier.issue7en_HK
dc.identifier.spage555en_HK
dc.identifier.epage563en_HK
dc.identifier.isiWOS:000178100400008-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK

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