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Article: Solvation effects on the iodoform ultraviolet direct photodissociation reaction: Opening the photoisomerization channel

TitleSolvation effects on the iodoform ultraviolet direct photodissociation reaction: Opening the photoisomerization channel
Authors
Issue Date2000
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett
Citation
Chemical Physics Letters, 2000, v. 324 n. 1-3, p. 175-182 How to Cite?
AbstractWe present transient resonance Raman spectra that demonstrate that the iso-iodoform photoproduct is mainly associated with the ~400 nm transient absorption band observed following excitation of iodoform in the solution phase. Comparison of our present results with previously reported gas-phase experiments and results for the closely related diiodomethane molecular system suggests that solvation gives rise to noticeable formation of the iso-iodoform photoproduct by some recombination of the initially formed CHI2 and I photofragments within a solvent cage.
Persistent Identifierhttp://hdl.handle.net/10722/69351
ISSN
2015 Impact Factor: 1.86
2015 SCImago Journal Rankings: 0.757
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorZheng, Xen_HK
dc.contributor.authorPhillips, DLen_HK
dc.date.accessioned2010-09-06T06:12:52Z-
dc.date.available2010-09-06T06:12:52Z-
dc.date.issued2000en_HK
dc.identifier.citationChemical Physics Letters, 2000, v. 324 n. 1-3, p. 175-182en_HK
dc.identifier.issn0009-2614en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69351-
dc.description.abstractWe present transient resonance Raman spectra that demonstrate that the iso-iodoform photoproduct is mainly associated with the ~400 nm transient absorption band observed following excitation of iodoform in the solution phase. Comparison of our present results with previously reported gas-phase experiments and results for the closely related diiodomethane molecular system suggests that solvation gives rise to noticeable formation of the iso-iodoform photoproduct by some recombination of the initially formed CHI2 and I photofragments within a solvent cage.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cpletten_HK
dc.relation.ispartofChemical Physics Lettersen_HK
dc.rightsChemical Physics Letters. Copyright © Elsevier BV.en_HK
dc.titleSolvation effects on the iodoform ultraviolet direct photodissociation reaction: Opening the photoisomerization channelen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0009-2614&volume=324&spage=175&epage=182&date=2000&atitle=Solvation+effects+on+the+iodoform+ultraviolet+direct+photodissociation+reaction:+opening+the+photoisomerization+channelen_HK
dc.identifier.emailPhillips, DL:phillips@hku.hken_HK
dc.identifier.authorityPhillips, DL=rp00770en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0009-2614(00)00561-3-
dc.identifier.scopuseid_2-s2.0-0001263663en_HK
dc.identifier.hkuros51205en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0001263663&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume324en_HK
dc.identifier.issue1-3en_HK
dc.identifier.spage175en_HK
dc.identifier.epage182en_HK
dc.identifier.isiWOS:000087969900028-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridZheng, X=7404090253en_HK
dc.identifier.scopusauthoridPhillips, DL=7404519365en_HK

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