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Article: Synthesis, crystal structure and nonlinear optical properties of two novel linear cluster polymers {[MoOS3Cu3(CN)(py)3].0.5C6H6}n and [WOS3Cu3(CN)(py)4]n

TitleSynthesis, crystal structure and nonlinear optical properties of two novel linear cluster polymers {[MoOS3Cu3(CN)(py)3].0.5C6H6}n and [WOS3Cu3(CN)(py)4]n
Authors
Issue Date1999
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal of the Chemical Society Dalton Transactions, 1999, p. 2953-2957 How to Cite?
AbstractCluster polymers {[MoOS3Cu3(CN)(py)3]·0.5C6H6}n 1 and [WOS3Cu3(CN)(py)4]n 2 were synthesized by the reaction of (NH4)2MO2S2 (M = Mo, W) and CuCN with py. Their structures have been characterized by X-ray diffraction. Both of them show neutral nest-shaped structural units, and every structural unit forms two Cu1–N1–C1–Cu3 bridges with two other structural units leading to infinite one-dimensional polymers. In every unit cell of {[MoOS3Cu3(CN)(py)3]·0.5C6H6}n there are four [MoOS3Cu3(CN)(py)3] structural units and two benzene molecules, and the four structural units are from four independent linear polymer molecules which are parallel. In every unit cell of polymer 2, there are four [WOS3Cu3(CN)(py)4] structural units too, but they are only from two parallel linear polymer molecules. Polymer 1 shows good nonlinear optical (NLO) absorptive and NLO refractive properties, whereas strong NLO properties of polymer 2 are not observed.
Persistent Identifierhttp://hdl.handle.net/10722/69327
ISSN
2002 Impact Factor: 3.023
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorHou, Hen_HK
dc.contributor.authorZheng, Hen_HK
dc.contributor.authorAng, HGen_HK
dc.contributor.authorFan, Yen_HK
dc.contributor.authorLow, MKMen_HK
dc.contributor.authorZhu, Yen_HK
dc.contributor.authorWang, Wen_HK
dc.contributor.authorXin, XQen_HK
dc.contributor.authorJi, Wen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:12:38Z-
dc.date.available2010-09-06T06:12:38Z-
dc.date.issued1999en_HK
dc.identifier.citationJournal of the Chemical Society Dalton Transactions, 1999, p. 2953-2957en_HK
dc.identifier.issn1472-7773en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69327-
dc.description.abstractCluster polymers {[MoOS3Cu3(CN)(py)3]·0.5C6H6}n 1 and [WOS3Cu3(CN)(py)4]n 2 were synthesized by the reaction of (NH4)2MO2S2 (M = Mo, W) and CuCN with py. Their structures have been characterized by X-ray diffraction. Both of them show neutral nest-shaped structural units, and every structural unit forms two Cu1–N1–C1–Cu3 bridges with two other structural units leading to infinite one-dimensional polymers. In every unit cell of {[MoOS3Cu3(CN)(py)3]·0.5C6H6}n there are four [MoOS3Cu3(CN)(py)3] structural units and two benzene molecules, and the four structural units are from four independent linear polymer molecules which are parallel. In every unit cell of polymer 2, there are four [WOS3Cu3(CN)(py)4] structural units too, but they are only from two parallel linear polymer molecules. Polymer 1 shows good nonlinear optical (NLO) absorptive and NLO refractive properties, whereas strong NLO properties of polymer 2 are not observed.-
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_HK
dc.relation.ispartofJournal of the Chemical Society Dalton Transactionsen_HK
dc.titleSynthesis, crystal structure and nonlinear optical properties of two novel linear cluster polymers {[MoOS3Cu3(CN)(py)3].0.5C6H6}n and [WOS3Cu3(CN)(py)4]nen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1472-7773&volume=&spage=2953&epage=2957&date=1999&atitle=Synthesis,+crystal+structure+and+nonlinear+optical+properties+of+two+novel+linear+cluster+polymers+{[MoOS3Cu3(CN)(py)3].0.5C6H6}n+and+[WOS3Cu3(CN)(py)4]nen_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1039/A902352F-
dc.identifier.scopuseid_2-s2.0-33749096415-
dc.identifier.hkuros53786en_HK
dc.identifier.isiWOS:000082424800013-

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