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Article: Synthesis and luminescence behaviour of mixed-metal rhenium(I)-copper(I) and -silver(I) alkynyl complexes

TitleSynthesis and luminescence behaviour of mixed-metal rhenium(I)-copper(I) and -silver(I) alkynyl complexes
Authors
KeywordsBuilding block
Metal alkynyl
Mixed-metal
MLCT and luminescence behaviour
Issue Date2003
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ccr
Citation
Coordination Chemistry Reviews, 2003, v. 245 n. 1-2, p. 39-47 How to Cite?
AbstractA series of luminescent mixed-metal acetylide complexes, [Cu 3(μ-LL) 3{μ 3-η 1-C≡ CC 6H 2R 2C≡C-p-Re(NN)(CO) 3} 2] + (LL=dppm, nPrPNP; NN = bpy, tBu 2bpy; R = H, Me) and [M 3(μ-LL) 3{μ- 3-η 1-C≡CC≡ C-Re(NN)(CO) 3} 2] + (M = Cu, Ag; LL = dppm, dppa; NN = bpy, Me 2bpy, tBu 2bpy) have been synthesized and characterized. All of them display rich photoluminescence and their low-energy emission are assigned as derived from states of 3MLCT [dτ(Re)→τ*(NN)] character. The X-ray crystal structures of [Cu 3(μ-dppm) 3{μ 3-η 1C≡CC≡C-Re(Me 2bpy)(CO) 3} 2]PF 6 and [Ag 3(μ-dppm) 3{μ 3-η 1-C≡CC≡ C-Re(bpy)(CO) 3} 2]PF 6 have been determined. © 2003 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/69326
ISSN
2015 Impact Factor: 12.994
2015 SCImago Journal Rankings: 4.100
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorWingWah Yam, Ven_HK
dc.contributor.authorLo, WYen_HK
dc.contributor.authorLam, CHen_HK
dc.contributor.authorKitMai Fung, Wen_HK
dc.contributor.authorManChung Wong, Ken_HK
dc.contributor.authorChorYue Lau, Ven_HK
dc.contributor.authorZhu, Nen_HK
dc.date.accessioned2010-09-06T06:12:37Z-
dc.date.available2010-09-06T06:12:37Z-
dc.date.issued2003en_HK
dc.identifier.citationCoordination Chemistry Reviews, 2003, v. 245 n. 1-2, p. 39-47en_HK
dc.identifier.issn0010-8545en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69326-
dc.description.abstractA series of luminescent mixed-metal acetylide complexes, [Cu 3(μ-LL) 3{μ 3-η 1-C≡ CC 6H 2R 2C≡C-p-Re(NN)(CO) 3} 2] + (LL=dppm, nPrPNP; NN = bpy, tBu 2bpy; R = H, Me) and [M 3(μ-LL) 3{μ- 3-η 1-C≡CC≡ C-Re(NN)(CO) 3} 2] + (M = Cu, Ag; LL = dppm, dppa; NN = bpy, Me 2bpy, tBu 2bpy) have been synthesized and characterized. All of them display rich photoluminescence and their low-energy emission are assigned as derived from states of 3MLCT [dτ(Re)→τ*(NN)] character. The X-ray crystal structures of [Cu 3(μ-dppm) 3{μ 3-η 1C≡CC≡C-Re(Me 2bpy)(CO) 3} 2]PF 6 and [Ag 3(μ-dppm) 3{μ 3-η 1-C≡CC≡ C-Re(bpy)(CO) 3} 2]PF 6 have been determined. © 2003 Elsevier B.V. All rights reserved.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ccren_HK
dc.relation.ispartofCoordination Chemistry Reviewsen_HK
dc.rightsCoordination Chemistry Reviews. Copyright © Elsevier BV.en_HK
dc.subjectBuilding blocken_HK
dc.subjectMetal alkynylen_HK
dc.subjectMixed-metalen_HK
dc.subjectMLCT and luminescence behaviouren_HK
dc.titleSynthesis and luminescence behaviour of mixed-metal rhenium(I)-copper(I) and -silver(I) alkynyl complexesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0010-8545&volume=245&spage=39&epage=47&date=2003&atitle=Synthesis+and+luminescence+behaviour+of+mixed-metal+rhenium(I)-copper(I)+and+-silver(I)+alkynyl+complexes++++en_HK
dc.identifier.emailWingWah Yam, V: wwyam@hku.hken_HK
dc.identifier.emailManChung Wong, K: wongmc@hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.authorityWingWah Yam, V=rp00822en_HK
dc.identifier.authorityManChung Wong, K=rp00809en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0010-8545(03)00032-8en_HK
dc.identifier.scopuseid_2-s2.0-0345275988en_HK
dc.identifier.hkuros91161en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0345275988&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume245en_HK
dc.identifier.issue1-2en_HK
dc.identifier.spage39en_HK
dc.identifier.epage47en_HK
dc.identifier.isiWOS:000186961500006-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridWingWah Yam, V=18539304700en_HK
dc.identifier.scopusauthoridLo, WY=36923784500en_HK
dc.identifier.scopusauthoridLam, CH=24525955200en_HK
dc.identifier.scopusauthoridKitMai Fung, W=6504295039en_HK
dc.identifier.scopusauthoridManChung Wong, K=8061067200en_HK
dc.identifier.scopusauthoridChorYue Lau, V=6505631244en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK

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