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Article: Synthesis of rod-like ruthenium complexes of 1,2-naphthoquinone-1-oxime

TitleSynthesis of rod-like ruthenium complexes of 1,2-naphthoquinone-1-oxime
線型1,2-鄰二萘醌-1-肟(1-nqo)釕配合物的合成
Authors
KeywordsRuthenium (釕)
1; 2-naphthoquinone-1-oxime (1; 2-鄰二萘醌-1-肟)
Decarbonylated substitution (羰基取代)
Issue Date2002
PublisherScience Press (科學出版社). The Journal's web site is located at http://hxxb.periodicals.net.cn/default.html
Citation
Acta Chimica Sinica, 2002, v. 60 n. 6, p. 1058-1064 How to Cite?
化學學報, 2002, v. 60 n. 6, p. 1058-1064 How to Cite?
AbstractBy decarbonylated substitution reactions, rod-like ruthenium complexes of 1,2-naphthoquinone-1-oxime (1-nqo) are synthesized as trans-,cis- and cis-, cis-[Ru(1-nqo) 2(CO)(spy)] (3) and (4) which containing C 16 long alkyl chains in the molecules, cis-,cis-[Ru(1-nqo) 2(CO)(opy)] (5) and trans-,trans-[Ru(1-nqo) 2(opy) 2] (6) which containing C 18 long alkyl chains in the molecules. The complexes are characterized by IR, FAB MS, 1H- 1H COSY NMR and UV-visible spectra.
報道了含C1 6長碳鏈線型 1,2 鄰二萘醌 1 肟 (1 nqo)釕配合物trans ,cis 及cis ,cis [Ru(1 nqo) 2 (CO) (spy) ](3)及 (4 ) ,含C1 8長碳鏈線型 1 nqo釕配合物cis ,cis [Ru(1 nqo) 2 (CO) (opy) ](5 ) ,trans ,trans [Ru(1 nqo) 2 (opy) 2 ](6 )的合成 .利用紅外、FAB質譜、核磁共振氫譜及紫外 -可見吸收光譜表征配合物的結構 ,利用1 H 1 H偶合二維核磁技術對核磁共振峰進行指認
Persistent Identifierhttp://hdl.handle.net/10722/69283
ISSN
2015 Impact Factor: 1.843
2015 SCImago Journal Rankings: 0.417

 

DC FieldValueLanguage
dc.contributor.authorLiu, XXen_HK
dc.contributor.authorSun, Ken_HK
dc.contributor.authorWong, WTen_HK
dc.contributor.authorNiu, JJen_HK
dc.contributor.authorZhang, BYen_HK
dc.date.accessioned2010-09-06T06:12:14Z-
dc.date.available2010-09-06T06:12:14Z-
dc.date.issued2002en_HK
dc.identifier.citationActa Chimica Sinica, 2002, v. 60 n. 6, p. 1058-1064en_HK
dc.identifier.citation化學學報, 2002, v. 60 n. 6, p. 1058-1064-
dc.identifier.issn0567-7351-
dc.identifier.urihttp://hdl.handle.net/10722/69283-
dc.description.abstractBy decarbonylated substitution reactions, rod-like ruthenium complexes of 1,2-naphthoquinone-1-oxime (1-nqo) are synthesized as trans-,cis- and cis-, cis-[Ru(1-nqo) 2(CO)(spy)] (3) and (4) which containing C 16 long alkyl chains in the molecules, cis-,cis-[Ru(1-nqo) 2(CO)(opy)] (5) and trans-,trans-[Ru(1-nqo) 2(opy) 2] (6) which containing C 18 long alkyl chains in the molecules. The complexes are characterized by IR, FAB MS, 1H- 1H COSY NMR and UV-visible spectra.-
dc.description.abstract報道了含C1 6長碳鏈線型 1,2 鄰二萘醌 1 肟 (1 nqo)釕配合物trans ,cis 及cis ,cis [Ru(1 nqo) 2 (CO) (spy) ](3)及 (4 ) ,含C1 8長碳鏈線型 1 nqo釕配合物cis ,cis [Ru(1 nqo) 2 (CO) (opy) ](5 ) ,trans ,trans [Ru(1 nqo) 2 (opy) 2 ](6 )的合成 .利用紅外、FAB質譜、核磁共振氫譜及紫外 -可見吸收光譜表征配合物的結構 ,利用1 H 1 H偶合二維核磁技術對核磁共振峰進行指認-
dc.languageengen_HK
dc.publisherScience Press (科學出版社). The Journal's web site is located at http://hxxb.periodicals.net.cn/default.html-
dc.relation.ispartofActa Chimica Sinicaen_HK
dc.relation.ispartof化學學報-
dc.subjectRuthenium (釕)-
dc.subject1; 2-naphthoquinone-1-oxime (1; 2-鄰二萘醌-1-肟)-
dc.subjectDecarbonylated substitution (羰基取代)-
dc.titleSynthesis of rod-like ruthenium complexes of 1,2-naphthoquinone-1-oximeen_HK
dc.title線型1,2-鄰二萘醌-1-肟(1-nqo)釕配合物的合成-
dc.typeArticleen_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.hkuros76338en_HK
dc.identifier.volume60-
dc.identifier.issue6-
dc.identifier.spage1058-
dc.identifier.epage1064-
dc.publisher.placeBeijing (北京)-

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