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Article: Self-assembled monolayer formed by a rhenium complex containing hyperbranched polymer

TitleSelf-assembled monolayer formed by a rhenium complex containing hyperbranched polymer
Authors
KeywordsHyperbranched
Metal-polymer complexes
Rhenium
Self-assembly
Issue Date2004
PublisherWiley - V C H Verlag GmbH & Co KGaA.
Citation
Macromolecular Rapid Communications, 2004, v. 25 n. 14, p. 1335-1339 How to Cite?
AbstractThe synthesis of a hyperbranched polymer containing a rhenium bipyridine complex is reported. The polymer was synthesized from a monomer that contains two chlorotricarbonyl rhenium(I) bipyridine moieties and a stilbazole ligand, and the polymer was formed by the coordination reaction in one single step. Gel permeation chromatography results showed that the resulting polymer had a strong interaction with the column packing material, which was reduced when the eluent was added with an electrolyte. Both atomic force microscopy and laser light scattering showed that the size of the polymer molecules was in the range between 25-30 nm. A monolayer of polymer molecules could form on a pretreated substrate by the self-assembly process, which can serve as the building block for multilayer ultrathin film devices.
Persistent Identifierhttp://hdl.handle.net/10722/69248
ISSN
2015 Impact Factor: 4.638
2015 SCImago Journal Rankings: 1.869
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorTse, CWen_HK
dc.contributor.authorCheng, KWen_HK
dc.contributor.authorChan, WKen_HK
dc.contributor.authorDjurišic, ABen_HK
dc.date.accessioned2010-09-06T06:11:55Z-
dc.date.available2010-09-06T06:11:55Z-
dc.date.issued2004en_HK
dc.identifier.citationMacromolecular Rapid Communications, 2004, v. 25 n. 14, p. 1335-1339en_HK
dc.identifier.issn1022-1336en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69248-
dc.description.abstractThe synthesis of a hyperbranched polymer containing a rhenium bipyridine complex is reported. The polymer was synthesized from a monomer that contains two chlorotricarbonyl rhenium(I) bipyridine moieties and a stilbazole ligand, and the polymer was formed by the coordination reaction in one single step. Gel permeation chromatography results showed that the resulting polymer had a strong interaction with the column packing material, which was reduced when the eluent was added with an electrolyte. Both atomic force microscopy and laser light scattering showed that the size of the polymer molecules was in the range between 25-30 nm. A monolayer of polymer molecules could form on a pretreated substrate by the self-assembly process, which can serve as the building block for multilayer ultrathin film devices.en_HK
dc.languageengen_HK
dc.publisherWiley - V C H Verlag GmbH & Co KGaA.en_HK
dc.relation.ispartofMacromolecular Rapid Communicationsen_HK
dc.subjectHyperbrancheden_HK
dc.subjectMetal-polymer complexesen_HK
dc.subjectRheniumen_HK
dc.subjectSelf-assemblyen_HK
dc.titleSelf-assembled monolayer formed by a rhenium complex containing hyperbranched polymeren_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1022-1336&volume=25&spage=1335&epage=1339&date=2004&atitle=Self-assembled+monolayer+formed+by+a+rhenium+complex+containing+hyperbranched+polymeren_HK
dc.identifier.emailChan, WK: waichan@hku.hken_HK
dc.identifier.emailDjurišic, AB: dalek@hku.hken_HK
dc.identifier.authorityChan, WK=rp00667en_HK
dc.identifier.authorityDjurišic, AB=rp00690en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/marc.200400103en_HK
dc.identifier.scopuseid_2-s2.0-4544230373en_HK
dc.identifier.hkuros92007en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-4544230373&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume25en_HK
dc.identifier.issue14en_HK
dc.identifier.spage1335en_HK
dc.identifier.epage1339en_HK
dc.identifier.isiWOS:000223015200009-
dc.publisher.placeGermanyen_HK
dc.identifier.scopusauthoridTse, CW=36958765800en_HK
dc.identifier.scopusauthoridCheng, KW=36439221300en_HK
dc.identifier.scopusauthoridChan, WK=13310083000en_HK
dc.identifier.scopusauthoridDjurišic, AB=7004904830en_HK

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