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Article: Methoxycarbene and allenylidene complexes of ruthenium with an oxygen tripod ligand

TitleMethoxycarbene and allenylidene complexes of ruthenium with an oxygen tripod ligand
Authors
Issue Date1998
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallics
Citation
Organometallics, 1998, v. 17 n. 6, p. 1245-1247 How to Cite?
AbstractInteraction of LOEt(PPh3)2RuCl (LOEt = (η5-C5H5)Co{P(OEt)2=O} 3] with Me3SiC≡CH and 2-phenyl-3-butyn-2-ol in the presence of NH4PF6 in MeOH/THF afforded the structurally characterized methoxycarbene [LOEt(PPh3)2Ru=C(OMe)Me]PF6 (1) and the allenylidene complex [LOEt(PPh3)2Ru=C=C=CPhMe]PF6 (2) respectively. The Ru-C distances in 1 and 2 are 1.876(6) and 1.86(2) Å, respectively. The cyclic voltammograms of 1 and 2 exhibit reversible Ru(III/II) couples at 0.58 and 0.64 V vs Cp2Fe+/0, respectively.
Persistent Identifierhttp://hdl.handle.net/10722/69234
ISSN
2015 Impact Factor: 4.186
2015 SCImago Journal Rankings: 2.043
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLeung, WHen_HK
dc.contributor.authorChan, EYYen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:11:48Z-
dc.date.available2010-09-06T06:11:48Z-
dc.date.issued1998en_HK
dc.identifier.citationOrganometallics, 1998, v. 17 n. 6, p. 1245-1247en_HK
dc.identifier.issn0276-7333en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69234-
dc.description.abstractInteraction of LOEt(PPh3)2RuCl (LOEt = (η5-C5H5)Co{P(OEt)2=O} 3] with Me3SiC≡CH and 2-phenyl-3-butyn-2-ol in the presence of NH4PF6 in MeOH/THF afforded the structurally characterized methoxycarbene [LOEt(PPh3)2Ru=C(OMe)Me]PF6 (1) and the allenylidene complex [LOEt(PPh3)2Ru=C=C=CPhMe]PF6 (2) respectively. The Ru-C distances in 1 and 2 are 1.876(6) and 1.86(2) Å, respectively. The cyclic voltammograms of 1 and 2 exhibit reversible Ru(III/II) couples at 0.58 and 0.64 V vs Cp2Fe+/0, respectively.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallicsen_HK
dc.relation.ispartofOrganometallicsen_HK
dc.titleMethoxycarbene and allenylidene complexes of ruthenium with an oxygen tripod liganden_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0276-7333&volume=17&spage=1245&epage=1247&date=1998&atitle=Methoxycarbene+and+Allenylidene+Complexes+of+Ruthenium+with+an+Oxygen+Tripod+Liganden_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/om970907e-
dc.identifier.scopuseid_2-s2.0-0001620028en_HK
dc.identifier.hkuros32566en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0001620028&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume17en_HK
dc.identifier.issue6en_HK
dc.identifier.spage1245en_HK
dc.identifier.epage1247en_HK
dc.identifier.isiWOS:000072615700039-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridLeung, WH=7201504510en_HK
dc.identifier.scopusauthoridChan, EYY=7401994108en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK

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