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Article: Bulky thioureas as new ligands for gold(I)-catalyzed cyclization of acetylenic 1,3-dicarbonyl compounds

TitleBulky thioureas as new ligands for gold(I)-catalyzed cyclization of acetylenic 1,3-dicarbonyl compounds
Authors
Pan, JHYang, MGao, QZhu, NYYang, D
Keywords1,3-dicarbonyl compounds
Alkynes
Catalysis
Cyclizations
Ligands
Issue Date2007
PublisherGeorg Thieme Verlag. The Journal's web site is located at www.thieme-chemistry.com
Citation
Synthesis, 2007 n. 16, p. 2539-2544 How to Cite?
DOI: http://dx.doi.org/10.1055/s-2007-983804
AbstractWe illustrate the first use of bulky N,N′-disubstituted cyclic thioureas as ligands for gold(I) catalysis. X-ray crystal structures of the thiourea-gold(I) complexes presented important information about the nature of the complexation. These complexes were found to be active catalysts for the cyclization of 1,3-dicarbonyl compounds with alkynes (Conia-ene reaction). Various acetylenic 1,3-dicarbonyl compounds underwent cycloisomerization to give mono- and bicyclic olefinic cyclopentanes in the presence of one mol% of a thiourea-gold(I) chloride complex and silver triflate. © Georg Thieme Verlag Stuttgart.
Persistent Identifierhttp://hdl.handle.net/10722/69231
ISSN
0039-7881
2023 Impact Factor: 2.2
2023 SCImago Journal Rankings: 0.582
ISI Accession Number ID
WOS:000249272900015
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorPan, JHen_HK
dc.contributor.authorYang, Men_HK
dc.contributor.authorGao, Qen_HK
dc.contributor.authorZhu, NYen_HK
dc.contributor.authorYang, Den_HK
dc.date.accessioned2010-09-06T06:11:46Z-
dc.date.available2010-09-06T06:11:46Z-
dc.date.issued2007en_HK
dc.identifier.citationSynthesis, 2007 n. 16, p. 2539-2544en_HK
dc.identifier.issn0039-7881en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69231-
dc.description.abstractWe illustrate the first use of bulky N,N′-disubstituted cyclic thioureas as ligands for gold(I) catalysis. X-ray crystal structures of the thiourea-gold(I) complexes presented important information about the nature of the complexation. These complexes were found to be active catalysts for the cyclization of 1,3-dicarbonyl compounds with alkynes (Conia-ene reaction). Various acetylenic 1,3-dicarbonyl compounds underwent cycloisomerization to give mono- and bicyclic olefinic cyclopentanes in the presence of one mol% of a thiourea-gold(I) chloride complex and silver triflate. © Georg Thieme Verlag Stuttgart.en_HK
dc.languageengen_HK
dc.publisherGeorg Thieme Verlag. The Journal's web site is located at www.thieme-chemistry.comen_HK
dc.relation.ispartofSynthesisen_HK
dc.subject1,3-dicarbonyl compoundsen_HK
dc.subjectAlkynesen_HK
dc.subjectCatalysisen_HK
dc.subjectCyclizationsen_HK
dc.subjectLigandsen_HK
dc.titleBulky thioureas as new ligands for gold(I)-catalyzed cyclization of acetylenic 1,3-dicarbonyl compoundsen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0039-7857&volume=&spage=2539&epage=2544&date=2007&atitle=Bulky+Thioureas+as+New+Ligands+for+Gold(I)-Catalyzed+Cyclization+of+Acetylenic+1,3-Dicarbonyl+Compounds+en_HK
dc.identifier.emailZhu, NY: nzhu@hkucc.hku.hken_HK
dc.identifier.emailYang, D: yangdan@hku.hken_HK
dc.identifier.authorityZhu, NY=rp00845en_HK
dc.identifier.authorityYang, D=rp00825en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1055/s-2007-983804en_HK
dc.identifier.scopuseid_2-s2.0-34548361964en_HK
dc.identifier.hkuros135032en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-34548361964&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.issue16en_HK
dc.identifier.spage2539en_HK
dc.identifier.epage2544en_HK
dc.identifier.isiWOS:000249272900015-
dc.publisher.placeGermanyen_HK
dc.identifier.scopusauthoridPan, JH=7404098731en_HK
dc.identifier.scopusauthoridYang, M=8984637400en_HK
dc.identifier.scopusauthoridGao, Q=7202743913en_HK
dc.identifier.scopusauthoridZhu, NY=7201449530en_HK
dc.identifier.scopusauthoridYang, D=7404800756en_HK
dc.identifier.issnl0039-7881-

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