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- Publisher Website: 10.1039/DT9960002177
- Scopus: eid_2-s2.0-33749112464
- WOS: WOS:A1996UL96800023
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Article: Synthesis and characterization of triosmium clusters containing a nitrite ligand; crystal and molecular structures of [N(PPh3)2][Os3(CO)10(µ-η2-NO2)] and [Os3(µ-H)(CO)10(µ-η2-NO2)]
| Title | Synthesis and characterization of triosmium clusters containing a nitrite ligand; crystal and molecular structures of [N(PPh3)2][Os3(CO)10(µ-η2-NO2)] and [Os3(µ-H)(CO)10(µ-η2-NO2)] |
|---|---|
| Authors | |
| Issue Date | 1996 |
| Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton |
| Citation | Journal of the Chemical Society Dalton Transactions, 1996, n. 10, p. 2177-2178 How to Cite? |
| Abstract | The cluster [Os3(CO)10(NCMe)2] reacted with [N(PPh3)2]NO2 in CH2Cl2 to give a novel red-orange complex [N(PPh3)2][Os3(CO)10(µ-η2-NO2)] in moderate yield, which underwent protonation with HBF4·Et2O in CH2Cl2 to give the neutral complex [Os3(µ-H)(CO)10(µ-η2-NO2)] in high yield; X-ray crystal-structure analyses have shown that both clusters contain a µ-η2-bridging nitrite ligand. |
| Persistent Identifier | http://hdl.handle.net/10722/69195 |
| ISSN | |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Hui, BKM | en_HK |
| dc.contributor.author | Wong, WT | en_HK |
| dc.date.accessioned | 2010-09-06T06:11:26Z | - |
| dc.date.available | 2010-09-06T06:11:26Z | - |
| dc.date.issued | 1996 | en_HK |
| dc.identifier.citation | Journal of the Chemical Society Dalton Transactions, 1996, n. 10, p. 2177-2178 | en_HK |
| dc.identifier.issn | 1472-7773 | en_HK |
| dc.identifier.uri | http://hdl.handle.net/10722/69195 | - |
| dc.description.abstract | The cluster [Os3(CO)10(NCMe)2] reacted with [N(PPh3)2]NO2 in CH2Cl2 to give a novel red-orange complex [N(PPh3)2][Os3(CO)10(µ-η2-NO2)] in moderate yield, which underwent protonation with HBF4·Et2O in CH2Cl2 to give the neutral complex [Os3(µ-H)(CO)10(µ-η2-NO2)] in high yield; X-ray crystal-structure analyses have shown that both clusters contain a µ-η2-bridging nitrite ligand. | - |
| dc.language | eng | en_HK |
| dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton | en_HK |
| dc.relation.ispartof | Journal of the Chemical Society Dalton Transactions | en_HK |
| dc.title | Synthesis and characterization of triosmium clusters containing a nitrite ligand; crystal and molecular structures of [N(PPh3)2][Os3(CO)10(µ-η2-NO2)] and [Os3(µ-H)(CO)10(µ-η2-NO2)] | en_HK |
| dc.type | Article | en_HK |
| dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1472-7773&volume=&spage=2177&epage=2178&date=1996&atitle=Synthesis+and+characterization+of+triosmium+clusters+containing+a+nitrite+ligand;++crystal+and+molecular+structures+of+[N(PPh3)2][Os3(CO)10(m-h2-NO2)]+and+[Os3(m-H)(CO)10(m-h2-NO2)] | en_HK |
| dc.identifier.email | Wong, WT: wtwong@hku.hk | en_HK |
| dc.identifier.authority | Wong, WT=rp00811 | en_HK |
| dc.identifier.doi | 10.1039/DT9960002177 | - |
| dc.identifier.scopus | eid_2-s2.0-33749112464 | - |
| dc.identifier.hkuros | 21865 | en_HK |
| dc.identifier.issue | 10 | - |
| dc.identifier.spage | 2177 | - |
| dc.identifier.epage | 2178 | - |
| dc.identifier.isi | WOS:A1996UL96800023 | - |
| dc.publisher.place | United Kingdom | - |
| dc.identifier.issnl | 1364-5447 | - |