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Article: Synthesis and characterization of triosmium clusters containing a nitrite ligand; crystal and molecular structures of [N(PPh3)2][Os3(CO)10(µ-η2-NO2)] and [Os3(µ-H)(CO)10(µ-η2-NO2)]

TitleSynthesis and characterization of triosmium clusters containing a nitrite ligand; crystal and molecular structures of [N(PPh3)2][Os3(CO)10(µ-η2-NO2)] and [Os3(µ-H)(CO)10(µ-η2-NO2)]
Authors
Issue Date1996
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal of the Chemical Society Dalton Transactions, 1996, n. 10, p. 2177-2178 How to Cite?
AbstractThe cluster [Os3(CO)10(NCMe)2] reacted with [N(PPh3)2]NO2 in CH2Cl2 to give a novel red-orange complex [N(PPh3)2][Os3(CO)10(µ-η2-NO2)] in moderate yield, which underwent protonation with HBF4·Et2O in CH2Cl2 to give the neutral complex [Os3(µ-H)(CO)10(µ-η2-NO2)] in high yield; X-ray crystal-structure analyses have shown that both clusters contain a µ-η2-bridging nitrite ligand.
Persistent Identifierhttp://hdl.handle.net/10722/69195
ISSN
2002 Impact Factor: 3.023
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorHui, BKMen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:11:26Z-
dc.date.available2010-09-06T06:11:26Z-
dc.date.issued1996en_HK
dc.identifier.citationJournal of the Chemical Society Dalton Transactions, 1996, n. 10, p. 2177-2178en_HK
dc.identifier.issn1472-7773en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69195-
dc.description.abstractThe cluster [Os3(CO)10(NCMe)2] reacted with [N(PPh3)2]NO2 in CH2Cl2 to give a novel red-orange complex [N(PPh3)2][Os3(CO)10(µ-η2-NO2)] in moderate yield, which underwent protonation with HBF4·Et2O in CH2Cl2 to give the neutral complex [Os3(µ-H)(CO)10(µ-η2-NO2)] in high yield; X-ray crystal-structure analyses have shown that both clusters contain a µ-η2-bridging nitrite ligand.-
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_HK
dc.relation.ispartofJournal of the Chemical Society Dalton Transactionsen_HK
dc.titleSynthesis and characterization of triosmium clusters containing a nitrite ligand; crystal and molecular structures of [N(PPh3)2][Os3(CO)10(µ-η2-NO2)] and [Os3(µ-H)(CO)10(µ-η2-NO2)]en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1472-7773&volume=&spage=2177&epage=2178&date=1996&atitle=Synthesis+and+characterization+of+triosmium+clusters+containing+a+nitrite+ligand;++crystal+and+molecular+structures+of+[N(PPh3)2][Os3(CO)10(m-h2-NO2)]+and+[Os3(m-H)(CO)10(m-h2-NO2)]en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1039/DT9960002177-
dc.identifier.hkuros21865en_HK
dc.identifier.issue10-
dc.identifier.spage2177-
dc.identifier.epage2178-
dc.identifier.isiWOS:A1996UL96800023-
dc.publisher.placeUnited Kingdom-

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