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Article: A novel polynuclear gold-sulfur cube with an unusually large stokes shift

TitleA novel polynuclear gold-sulfur cube with an unusually large stokes shift
Authors
KeywordsCluster compounds
Gold
Luminescence
P ligands
Sulfur
Issue Date2001
PublisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home
Citation
Angewandte Chemie - International Edition, 2001, v. 40 n. 9, p. 1763-1765 How to Cite?
AbstractA 1.87-eV energy gap between the lowest energy excitation maximum and the emission maximum in solution was found for the novel hexanuclear gold(I) sulfido complex 1 (Ar =p-CH3C6H4), which has a heterocubane-type structure. Besides this abnormally large Stokes shift of around 15000cm-1, 1 exhibits intense orange luminescence in the solid state.
Persistent Identifierhttp://hdl.handle.net/10722/69161
ISSN
2015 Impact Factor: 11.709
2015 SCImago Journal Rankings: 6.229
References

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_HK
dc.contributor.authorCheng, ECCen_HK
dc.contributor.authorZhu, Nen_HK
dc.date.accessioned2010-09-06T06:11:07Z-
dc.date.available2010-09-06T06:11:07Z-
dc.date.issued2001en_HK
dc.identifier.citationAngewandte Chemie - International Edition, 2001, v. 40 n. 9, p. 1763-1765en_HK
dc.identifier.issn1433-7851en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69161-
dc.description.abstractA 1.87-eV energy gap between the lowest energy excitation maximum and the emission maximum in solution was found for the novel hexanuclear gold(I) sulfido complex 1 (Ar =p-CH3C6H4), which has a heterocubane-type structure. Besides this abnormally large Stokes shift of around 15000cm-1, 1 exhibits intense orange luminescence in the solid state.en_HK
dc.languageengen_HK
dc.publisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/homeen_HK
dc.relation.ispartofAngewandte Chemie - International Editionen_HK
dc.subjectCluster compoundsen_HK
dc.subjectGolden_HK
dc.subjectLuminescenceen_HK
dc.subjectP ligandsen_HK
dc.subjectSulfuren_HK
dc.titleA novel polynuclear gold-sulfur cube with an unusually large stokes shiften_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1433-7851&volume=40&issue=9&spage=1763&epage=1765&date=2001&atitle=A+novel+polynuclear+gold-sulfur+cube+with+an+unusually+large+stokes+shiften_HK
dc.identifier.emailYam, VWW: wwyam@hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/1521-3773(20010504)40:9<1763::AID-ANIE17630>3.0.CO;2-Oen_HK
dc.identifier.scopuseid_2-s2.0-0035805273en_HK
dc.identifier.hkuros62530en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0035805273&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume40en_HK
dc.identifier.issue9en_HK
dc.identifier.spage1763en_HK
dc.identifier.epage1765en_HK
dc.publisher.placeGermanyen_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK
dc.identifier.scopusauthoridCheng, ECC=7201743424en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK

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