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Article: Luminescent cyclometalated diimine platinum (II) complexes: photophysical studies and applications
Title | Luminescent cyclometalated diimine platinum (II) complexes: photophysical studies and applications |
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Authors | |
Keywords | Cyclometalation Luminescence OLED Platinum Sensors |
Issue Date | 2004 |
Publisher | Springer-Verlag. |
Citation | Topics in Current Chemistry, 2004, v. 241, p. 27-63 How to Cite? |
Abstract | The photoluminescent properties of mono- and polynuclear cyclometalated platinum(II) complexes are discussed. Spectroscopic studies have revealed weak intra- or intermolecular metal-metal and ligand-ligand interactions that are affected by the molecular structure and microenvironment. The structure-emission relationships observed in these platinum(II) complexes are described and comparisons with palladium(II) analogues regarding the structural and photoluminescent properties are highlighted. With judicious modification of cyclometalated and/or ancillary ligands, robust platinum luminophores with tunable emission energies and lifetimes have been synthesized. These complexes can be employed as luminescent sensors and electrophosphorescent materials in organic light-emitting devices (OLED). |
Persistent Identifier | http://hdl.handle.net/10722/69148 |
ISSN | 2015 Impact Factor: 4.014 2020 SCImago Journal Rankings: 1.944 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Lai, SW | en_HK |
dc.contributor.author | Che, CM | en_HK |
dc.date.accessioned | 2010-09-06T06:11:00Z | - |
dc.date.available | 2010-09-06T06:11:00Z | - |
dc.date.issued | 2004 | en_HK |
dc.identifier.citation | Topics in Current Chemistry, 2004, v. 241, p. 27-63 | en_HK |
dc.identifier.issn | 0340-1022 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/69148 | - |
dc.description.abstract | The photoluminescent properties of mono- and polynuclear cyclometalated platinum(II) complexes are discussed. Spectroscopic studies have revealed weak intra- or intermolecular metal-metal and ligand-ligand interactions that are affected by the molecular structure and microenvironment. The structure-emission relationships observed in these platinum(II) complexes are described and comparisons with palladium(II) analogues regarding the structural and photoluminescent properties are highlighted. With judicious modification of cyclometalated and/or ancillary ligands, robust platinum luminophores with tunable emission energies and lifetimes have been synthesized. These complexes can be employed as luminescent sensors and electrophosphorescent materials in organic light-emitting devices (OLED). | - |
dc.language | eng | en_HK |
dc.publisher | Springer-Verlag. | en_HK |
dc.relation.ispartof | Topics in Current Chemistry | en_HK |
dc.subject | Cyclometalation | - |
dc.subject | Luminescence | - |
dc.subject | OLED | - |
dc.subject | Platinum | - |
dc.subject | Sensors | - |
dc.title | Luminescent cyclometalated diimine platinum (II) complexes: photophysical studies and applications | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0340-1022&volume=241&spage=27&epage=63&date=2004&atitle=Luminescent+cyclometalated+diimine+platinum(II)+complexes:+Photophysical+studies+and+applications | en_HK |
dc.identifier.email | Lai, SW: swlai@hkucc.hku.hk | en_HK |
dc.identifier.email | Che, CM: cmche@hku.hk | en_HK |
dc.identifier.authority | Lai, SW=rp00717 | en_HK |
dc.identifier.authority | Che, CM=rp00670 | en_HK |
dc.identifier.doi | 10.1007/b96859 | - |
dc.identifier.hkuros | 105815 | en_HK |
dc.identifier.volume | 241 | - |
dc.identifier.spage | 27 | - |
dc.identifier.epage | 63 | - |
dc.identifier.isi | WOS:000227916100002 | - |
dc.identifier.issnl | 0340-1022 | - |