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Article: Luminescent cyclometalated diimine platinum (II) complexes: photophysical studies and applications

TitleLuminescent cyclometalated diimine platinum (II) complexes: photophysical studies and applications
Authors
KeywordsCyclometalation
Luminescence
OLED
Platinum
Sensors
Issue Date2004
PublisherSpringer-Verlag.
Citation
Topics in Current Chemistry, 2004, v. 241, p. 27-63 How to Cite?
AbstractThe photoluminescent properties of mono- and polynuclear cyclometalated platinum(II) complexes are discussed. Spectroscopic studies have revealed weak intra- or intermolecular metal-metal and ligand-ligand interactions that are affected by the molecular structure and microenvironment. The structure-emission relationships observed in these platinum(II) complexes are described and comparisons with palladium(II) analogues regarding the structural and photoluminescent properties are highlighted. With judicious modification of cyclometalated and/or ancillary ligands, robust platinum luminophores with tunable emission energies and lifetimes have been synthesized. These complexes can be employed as luminescent sensors and electrophosphorescent materials in organic light-emitting devices (OLED).
Persistent Identifierhttp://hdl.handle.net/10722/69148
ISSN
2015 Impact Factor: 4.014
2015 SCImago Journal Rankings: 1.144
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorLai, SWen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2010-09-06T06:11:00Z-
dc.date.available2010-09-06T06:11:00Z-
dc.date.issued2004en_HK
dc.identifier.citationTopics in Current Chemistry, 2004, v. 241, p. 27-63en_HK
dc.identifier.issn0340-1022en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69148-
dc.description.abstractThe photoluminescent properties of mono- and polynuclear cyclometalated platinum(II) complexes are discussed. Spectroscopic studies have revealed weak intra- or intermolecular metal-metal and ligand-ligand interactions that are affected by the molecular structure and microenvironment. The structure-emission relationships observed in these platinum(II) complexes are described and comparisons with palladium(II) analogues regarding the structural and photoluminescent properties are highlighted. With judicious modification of cyclometalated and/or ancillary ligands, robust platinum luminophores with tunable emission energies and lifetimes have been synthesized. These complexes can be employed as luminescent sensors and electrophosphorescent materials in organic light-emitting devices (OLED).-
dc.languageengen_HK
dc.publisherSpringer-Verlag.en_HK
dc.relation.ispartofTopics in Current Chemistryen_HK
dc.subjectCyclometalation-
dc.subjectLuminescence-
dc.subjectOLED-
dc.subjectPlatinum-
dc.subjectSensors-
dc.titleLuminescent cyclometalated diimine platinum (II) complexes: photophysical studies and applicationsen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0340-1022&volume=241&spage=27&epage=63&date=2004&atitle=Luminescent+cyclometalated+diimine+platinum(II)+complexes:+Photophysical+studies+and+applicationsen_HK
dc.identifier.emailLai, SW: swlai@hkucc.hku.hken_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.authorityLai, SW=rp00717en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.identifier.doi10.1007/b96859-
dc.identifier.hkuros105815en_HK
dc.identifier.volume241-
dc.identifier.spage27-
dc.identifier.epage63-
dc.identifier.isiWOS:000227916100002-

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