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Article: Vibrational reorganizational energies of the A-band LMCT absorption in trans-dichlorobis (triphenylphosphine) palladium (II) determined from resonance Raman intensity analysis

TitleVibrational reorganizational energies of the A-band LMCT absorption in trans-dichlorobis (triphenylphosphine) palladium (II) determined from resonance Raman intensity analysis
Authors
Issue Date1998
PublisherTaylor & Francis Ltd. The Journal's web site is located at http://www.tandf.co.uk/journals/titles/00268976.asp
Citation
Molecular Physics, 1998, v. 94 n. 3, p. 547-554 How to Cite?
AbstractResonance Raman spectra including absolute resonance Raman cross section measurements have been recorded for four excitation wavelengths within the A-band ligand to metal charge transfer (LMCT) absorption at ∼ 340 nm of trans-dichlorobis(triphenylphosphine) palladium (II). A relatively simple model together with time-dependent wavepacket calculations were used to simulate simultaneously the absolute absorption and resonance Raman intensities in order to get an estimate of the vibrational reorganizational energies associated with the A-band absorption plus the homogeneous and inhomogeneous broadening to the absorption bandwidth. It seems that there is significant interaction of the triphenylphosphine ligands with the Cl/Pd chromophore of the LMCT absorption band. The results for transdichlorobis(triphenylphosphine) palladium(II) are compared with those of other inorganic compounds.
Persistent Identifierhttp://hdl.handle.net/10722/69139
ISSN
2015 Impact Factor: 1.837
2015 SCImago Journal Rankings: 0.781
References

 

DC FieldValueLanguage
dc.contributor.authorChoi, CLen_HK
dc.contributor.authorPhillips, DLen_HK
dc.date.accessioned2010-09-06T06:10:55Z-
dc.date.available2010-09-06T06:10:55Z-
dc.date.issued1998en_HK
dc.identifier.citationMolecular Physics, 1998, v. 94 n. 3, p. 547-554en_HK
dc.identifier.issn0026-8976en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69139-
dc.description.abstractResonance Raman spectra including absolute resonance Raman cross section measurements have been recorded for four excitation wavelengths within the A-band ligand to metal charge transfer (LMCT) absorption at ∼ 340 nm of trans-dichlorobis(triphenylphosphine) palladium (II). A relatively simple model together with time-dependent wavepacket calculations were used to simulate simultaneously the absolute absorption and resonance Raman intensities in order to get an estimate of the vibrational reorganizational energies associated with the A-band absorption plus the homogeneous and inhomogeneous broadening to the absorption bandwidth. It seems that there is significant interaction of the triphenylphosphine ligands with the Cl/Pd chromophore of the LMCT absorption band. The results for transdichlorobis(triphenylphosphine) palladium(II) are compared with those of other inorganic compounds.en_HK
dc.languageengen_HK
dc.publisherTaylor & Francis Ltd. The Journal's web site is located at http://www.tandf.co.uk/journals/titles/00268976.aspen_HK
dc.relation.ispartofMolecular Physicsen_HK
dc.titleVibrational reorganizational energies of the A-band LMCT absorption in trans-dichlorobis (triphenylphosphine) palladium (II) determined from resonance Raman intensity analysisen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0026-8976&volume=94&spage=547&epage=554&date=1998&atitle=Vibrational+reorganizational+energies+of+the+A-band+LMCT+absorption+in+trans-dichlorobis(triphenylphosphine)+palladium(II)+determined+from+resonance+Raman+intensity+analysisen_HK
dc.identifier.emailPhillips, DL:phillips@hku.hken_HK
dc.identifier.authorityPhillips, DL=rp00770en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.scopuseid_2-s2.0-0343037271en_HK
dc.identifier.hkuros31686en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0343037271&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume94en_HK
dc.identifier.issue3en_HK
dc.identifier.spage547en_HK
dc.identifier.epage554en_HK
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridChoi, CL=8233091400en_HK
dc.identifier.scopusauthoridPhillips, DL=7404519365en_HK

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