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Article: Laser-induced fluorescence spectroscopy of CrS

TitleLaser-induced fluorescence spectroscopy of CrS
Authors
Issue Date2001
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett
Citation
Chemical Physics Letters, 2001, v. 339 n. 1-2, p. 154-160 How to Cite?
AbstractCrS molecules were produced in a supersonic free jet expansion by reacting laser ablated chromium atoms and carbon disulfide. High-resolution laser-induced fluorescence spectrum between 625 and 825 nm was recorded. Six bands have been observed, which display the rotational structure of a Ω ′=-1←Ω″=-1 transition. Isotopic displacement analysis of 52CrS and 53CrS confirms that these six bands form a vibrational progression in a single band system. Ab initio calculations yielded spectroscopic properties of the two low-lying 5Π states: X 5Π(11σ 15π 11δ 2) and B 5Π(12σ 15π 11δ 2). From the good agreement between calculated and measured spectroscopic properties, we assign the observed transition as the B 5Π -1-X 5Π -1. © 2001 Elsevier Science B.V.
Persistent Identifierhttp://hdl.handle.net/10722/69113
ISSN
2015 Impact Factor: 1.86
2015 SCImago Journal Rankings: 0.757
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorShi, Qen_HK
dc.contributor.authorRan, Qen_HK
dc.contributor.authorTam, WSen_HK
dc.contributor.authorLeung, JWHen_HK
dc.contributor.authorCheung, ASCen_HK
dc.date.accessioned2010-09-06T06:10:41Z-
dc.date.available2010-09-06T06:10:41Z-
dc.date.issued2001en_HK
dc.identifier.citationChemical Physics Letters, 2001, v. 339 n. 1-2, p. 154-160en_HK
dc.identifier.issn0009-2614en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69113-
dc.description.abstractCrS molecules were produced in a supersonic free jet expansion by reacting laser ablated chromium atoms and carbon disulfide. High-resolution laser-induced fluorescence spectrum between 625 and 825 nm was recorded. Six bands have been observed, which display the rotational structure of a Ω ′=-1←Ω″=-1 transition. Isotopic displacement analysis of 52CrS and 53CrS confirms that these six bands form a vibrational progression in a single band system. Ab initio calculations yielded spectroscopic properties of the two low-lying 5Π states: X 5Π(11σ 15π 11δ 2) and B 5Π(12σ 15π 11δ 2). From the good agreement between calculated and measured spectroscopic properties, we assign the observed transition as the B 5Π -1-X 5Π -1. © 2001 Elsevier Science B.V.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cpletten_HK
dc.relation.ispartofChemical Physics Lettersen_HK
dc.rightsChemical Physics Letters. Copyright © Elsevier BV.en_HK
dc.titleLaser-induced fluorescence spectroscopy of CrSen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0009-2614&volume=339&spage=154&epage=160&date=2001&atitle=Laser-induced+fluorescence+spectroscopy+of+CrSen_HK
dc.identifier.emailCheung, ASC:hrsccsc@hku.hken_HK
dc.identifier.authorityCheung, ASC=rp00676en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0009-2614(01)00293-7en_HK
dc.identifier.scopuseid_2-s2.0-0035805467en_HK
dc.identifier.hkuros62475en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0035805467&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume339en_HK
dc.identifier.issue1-2en_HK
dc.identifier.spage154en_HK
dc.identifier.epage160en_HK
dc.identifier.isiWOS:000168592000023-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridShi, Q=55144505800en_HK
dc.identifier.scopusauthoridRan, Q=7007145640en_HK
dc.identifier.scopusauthoridTam, WS=7102605536en_HK
dc.identifier.scopusauthoridLeung, JWH=7202180280en_HK
dc.identifier.scopusauthoridCheung, ASC=7401806538en_HK

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