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Article: Cyano-bridged molecular squares: Synthesis and structures of [Ni(cyclen)]2[Pt(CN)4]2·6H2O, [Ni(cyclen)]2[Ni(CN)4]2·6H2O and [Mn(cyclen)]2[Ni(CN)4]2·6H2O

TitleCyano-bridged molecular squares: Synthesis and structures of [Ni(cyclen)]2[Pt(CN)4]2·6H2O, [Ni(cyclen)]2[Ni(CN)4]2·6H2O and [Mn(cyclen)]2[Ni(CN)4]2·6H2O
Authors
KeywordsMagnetic properties
Manganese
Molecular square
Nickel
Platinum
Issue Date2006
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly
Citation
Polyhedron, 2006, v. 25 n. 5, p. 1256-1262 How to Cite?
AbstractThree cyano-bridged complexes [Ni(cyclen)]2[Pt(CN) 4]2 • 6H2O (1), [Ni(cyclen)] 2[Ni(CN)4]2 • 6H2O (2) and [Mn(cyclen)]2[Ni(CN)4]2 • 6H2O (3) (cyclen is 1,4,7,10-tetraazacyclododecane) have been synthesized and structurally characterized. These complexes have a cyclic tetranuclear structure, the so-called a molecular square, in which two cis-cyano groups of each tetracyanometalate, [M(CN)4]2-, (M = Ni, Pt) are linked to two [M′(cyclen)]2+ (M′=Ni, Mn) units. © 2005 Elsevier Ltd. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/69112
ISSN
2015 Impact Factor: 2.108
2015 SCImago Journal Rankings: 0.592
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorYeung, WFen_HK
dc.contributor.authorKwong, HKen_HK
dc.contributor.authorLau, TCen_HK
dc.contributor.authorGao, Sen_HK
dc.contributor.authorSzeto, Len_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:10:41Z-
dc.date.available2010-09-06T06:10:41Z-
dc.date.issued2006en_HK
dc.identifier.citationPolyhedron, 2006, v. 25 n. 5, p. 1256-1262en_HK
dc.identifier.issn0277-5387en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69112-
dc.description.abstractThree cyano-bridged complexes [Ni(cyclen)]2[Pt(CN) 4]2 • 6H2O (1), [Ni(cyclen)] 2[Ni(CN)4]2 • 6H2O (2) and [Mn(cyclen)]2[Ni(CN)4]2 • 6H2O (3) (cyclen is 1,4,7,10-tetraazacyclododecane) have been synthesized and structurally characterized. These complexes have a cyclic tetranuclear structure, the so-called a molecular square, in which two cis-cyano groups of each tetracyanometalate, [M(CN)4]2-, (M = Ni, Pt) are linked to two [M′(cyclen)]2+ (M′=Ni, Mn) units. © 2005 Elsevier Ltd. All rights reserved.-
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/polyen_HK
dc.relation.ispartofPolyhedronen_HK
dc.subjectMagnetic properties-
dc.subjectManganese-
dc.subjectMolecular square-
dc.subjectNickel-
dc.subjectPlatinum-
dc.titleCyano-bridged molecular squares: Synthesis and structures of [Ni(cyclen)]2[Pt(CN)4]2·6H2O, [Ni(cyclen)]2[Ni(CN)4]2·6H2O and [Mn(cyclen)]2[Ni(CN)4]2·6H2Oen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0277-5387&volume=25&spage=1256&epage=1262&date=2006&atitle=Cyano-bridged+molecular+squares:+Synthesis+and+structures+of+[Ni(cyclen]2[Pt(CN4]2.6H2O,+[Ni(cyclen]2[Ni(CN)4]2.6H2O+and+[Mn(cyclen)]2[Ni(CN4]2.6H2Oen_HK
dc.identifier.emailSzeto, L: lszeto@HKUCC.hku.hken_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1016/j.poly.2005.09.004-
dc.identifier.scopuseid_2-s2.0-33644653098-
dc.identifier.hkuros119937en_HK
dc.identifier.volume25-
dc.identifier.issue5-
dc.identifier.spage1256-
dc.identifier.epage1262-
dc.identifier.isiWOS:000236392900024-
dc.publisher.placeNetherlands-

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