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Article: Resonance Raman study of short-time photodissociation dynamics of the charge-transfer band absorption of nitrobenzene in cyclohexane solution

TitleResonance Raman study of short-time photodissociation dynamics of the charge-transfer band absorption of nitrobenzene in cyclohexane solution
Authors
Issue Date2005
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/jpca
Citation
Journal Of Physical Chemistry A, 2005, v. 109 n. 13, p. 3086-3093 How to Cite?
AbstractResonance Raman spectra were obtained for nitrobenzene in cyclohexane solution with excitation wavelengths in resonance with the charge-transfer (CT) band absorption spectrum. These spectra indicate that the Franck-Condon region photodissociation dynamics have multidimensional character with motion mainly along the nominal NO 2 symmetric stretch mode (ν 11), the nominal benzene ring stretch mode (ν 7), accompanied by a moderate degree of motion along the nominal ONO symmetry bend/benzene ring stretch mode (ν 23), the nominal C-N stretch/benzene ring breathing mode (ν 16), the nominal CCC bending mode (ν 20) and the nominal CCH in-plane bending mode (ν 14). A preliminary resonance Raman intensity analysis was done and the results for nitrobenzene were compared to previously reported results for several nitroalkanes. © 2005 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/69111
ISSN
2015 Impact Factor: 2.883
2015 SCImago Journal Rankings: 1.231
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorZhu, XMen_HK
dc.contributor.authorZhang, SQen_HK
dc.contributor.authorZheng, Xen_HK
dc.contributor.authorLee, DPen_HK
dc.date.accessioned2010-09-06T06:10:40Z-
dc.date.available2010-09-06T06:10:40Z-
dc.date.issued2005en_HK
dc.identifier.citationJournal Of Physical Chemistry A, 2005, v. 109 n. 13, p. 3086-3093en_HK
dc.identifier.issn1089-5639en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69111-
dc.description.abstractResonance Raman spectra were obtained for nitrobenzene in cyclohexane solution with excitation wavelengths in resonance with the charge-transfer (CT) band absorption spectrum. These spectra indicate that the Franck-Condon region photodissociation dynamics have multidimensional character with motion mainly along the nominal NO 2 symmetric stretch mode (ν 11), the nominal benzene ring stretch mode (ν 7), accompanied by a moderate degree of motion along the nominal ONO symmetry bend/benzene ring stretch mode (ν 23), the nominal C-N stretch/benzene ring breathing mode (ν 16), the nominal CCC bending mode (ν 20) and the nominal CCH in-plane bending mode (ν 14). A preliminary resonance Raman intensity analysis was done and the results for nitrobenzene were compared to previously reported results for several nitroalkanes. © 2005 American Chemical Society.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/jpcaen_HK
dc.relation.ispartofJournal of Physical Chemistry Aen_HK
dc.titleResonance Raman study of short-time photodissociation dynamics of the charge-transfer band absorption of nitrobenzene in cyclohexane solutionen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1089-5639&volume=109&issue=13&spage=3086&epage=3093&date=2005&atitle=Resonance+raman+study+of+short-time+photodissociation+dynamics+of+the+charge-transfer+band+absorption+of+nitrobenzene+in+cyclohexane+solutionen_HK
dc.identifier.emailLee, DP:phillips@hku.hken_HK
dc.identifier.authorityLee, DP=rp00770en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/jp0444114en_HK
dc.identifier.scopuseid_2-s2.0-17044407975en_HK
dc.identifier.hkuros99145en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-17044407975&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume109en_HK
dc.identifier.issue13en_HK
dc.identifier.spage3086en_HK
dc.identifier.epage3093en_HK
dc.identifier.isiWOS:000228110900013-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridZhu, XM=7406185563en_HK
dc.identifier.scopusauthoridZhang, SQ=7409370603en_HK
dc.identifier.scopusauthoridZheng, X=7404090253en_HK
dc.identifier.scopusauthoridLee, DP=7404519365en_HK

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