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Article: Solid-state synthesis of cluster compound [MoCu3OS3(PPh3)(CH3COO)] with its structure, reactivity and optical non-linearities

TitleSolid-state synthesis of cluster compound [MoCu3OS3(PPh3)(CH3COO)] with its structure, reactivity and optical non-linearities
Authors
Issue Date1998
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ica
Citation
Inorganica Chimica Acta, 1998, v. 279, p. 172-177 How to Cite?
AbstractA novel acetate-containing cluster compound [MoCu3OS3(PPh3)3(CH3COO−)] was synthesized via a low-heating solid-state synthetic method. For the first time, the O-containing ligand was introduced into the Mo(W)Cu(Ag)S clusters with the O atoms acting as the coordinating atoms. The structure of this compound has been characterized by X-ray diffraction: space group P-1, Z = 4, R = 0.052, Rw = 0.058. A series of reactions manifest the possible role of the binuclear structure of Cu(CH3COO)2·H2O in the synthetic process as well as the relative weak affinity of the acetate group for Cu(I) compared with that of the halogen atoms. Z-scan measurements show that this compound exhibits interesting non-linear optical (NLO) effects.
Persistent Identifierhttp://hdl.handle.net/10722/69093
ISSN
2015 Impact Factor: 1.918
2015 SCImago Journal Rankings: 0.584

 

DC FieldValueLanguage
dc.contributor.authorZeng, DXen_HK
dc.contributor.authorJi, Wen_HK
dc.contributor.authorWong, WTen_HK
dc.contributor.authorWong, WYen_HK
dc.contributor.authorXin, XQen_HK
dc.date.accessioned2010-09-06T06:10:30Z-
dc.date.available2010-09-06T06:10:30Z-
dc.date.issued1998en_HK
dc.identifier.citationInorganica Chimica Acta, 1998, v. 279, p. 172-177en_HK
dc.identifier.issn0020-1693en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69093-
dc.description.abstractA novel acetate-containing cluster compound [MoCu3OS3(PPh3)3(CH3COO−)] was synthesized via a low-heating solid-state synthetic method. For the first time, the O-containing ligand was introduced into the Mo(W)Cu(Ag)S clusters with the O atoms acting as the coordinating atoms. The structure of this compound has been characterized by X-ray diffraction: space group P-1, Z = 4, R = 0.052, Rw = 0.058. A series of reactions manifest the possible role of the binuclear structure of Cu(CH3COO)2·H2O in the synthetic process as well as the relative weak affinity of the acetate group for Cu(I) compared with that of the halogen atoms. Z-scan measurements show that this compound exhibits interesting non-linear optical (NLO) effects.-
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/icaen_HK
dc.relation.ispartofInorganica Chimica Actaen_HK
dc.rightsInorganica Chimica Acta. Copyright © Elsevier BV.en_HK
dc.titleSolid-state synthesis of cluster compound [MoCu3OS3(PPh3)(CH3COO)] with its structure, reactivity and optical non-linearitiesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0020-1693&volume=279&spage=172&epage=177&date=1998&atitle=Solid-state+synthesis+of+cluster+compound+[MoCu3OS3(PPh3)(CH3COO)]+with+its+structure,+reactivity+and+optical+non-linearitiesen_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1016/S0020-1693(98)00119-4-
dc.identifier.scopuseid_2-s2.0-0001021060-
dc.identifier.hkuros40334en_HK

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