File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Time-resolved resonance Raman study of triplet arylnitrenes and their dimerization reaction

TitleTime-resolved resonance Raman study of triplet arylnitrenes and their dimerization reaction
Authors
Issue Date2003
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/jpca
Citation
Journal Of Physical Chemistry A, 2003, v. 107 n. 19, p. 3858-3865 How to Cite?
AbstractTime-resolved resonance Raman spectra for triplet 4-methoxyphenyl nitrene and 4-ethoxyphenyl nitrene and their dimerization reaction to form azo dimer products in acetonitrile solution on the nanosecond time scale are reported. As the 4-methoxyphenyl nitrene and 4-ethoxyphenyl nitrene Raman bands decay, the Raman bands for the azo dimer products increase in intensity. The triplet 4-methoxyphenyl nitrene and 4-ethoxyphenyl nitrene species and their reaction to produce azo products are compared to a recent study of the 2-fluorenyl nitrene species and its reaction to form dehydroazepine ring-expansion products. The properties of the singlet and triplet arylnitrenes and their reaction mechanisms to form azo dimer and ring-expansion products are briefly discussed.
Persistent Identifierhttp://hdl.handle.net/10722/69079
ISSN
2015 Impact Factor: 2.883
2015 SCImago Journal Rankings: 1.231
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorOng, SYen_HK
dc.contributor.authorChan, PYen_HK
dc.contributor.authorZhu, Pen_HK
dc.contributor.authorLeung, KHen_HK
dc.contributor.authorPhillips, DLen_HK
dc.date.accessioned2010-09-06T06:10:22Z-
dc.date.available2010-09-06T06:10:22Z-
dc.date.issued2003en_HK
dc.identifier.citationJournal Of Physical Chemistry A, 2003, v. 107 n. 19, p. 3858-3865en_HK
dc.identifier.issn1089-5639en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69079-
dc.description.abstractTime-resolved resonance Raman spectra for triplet 4-methoxyphenyl nitrene and 4-ethoxyphenyl nitrene and their dimerization reaction to form azo dimer products in acetonitrile solution on the nanosecond time scale are reported. As the 4-methoxyphenyl nitrene and 4-ethoxyphenyl nitrene Raman bands decay, the Raman bands for the azo dimer products increase in intensity. The triplet 4-methoxyphenyl nitrene and 4-ethoxyphenyl nitrene species and their reaction to produce azo products are compared to a recent study of the 2-fluorenyl nitrene species and its reaction to form dehydroazepine ring-expansion products. The properties of the singlet and triplet arylnitrenes and their reaction mechanisms to form azo dimer and ring-expansion products are briefly discussed.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/jpcaen_HK
dc.relation.ispartofJournal of Physical Chemistry Aen_HK
dc.titleTime-resolved resonance Raman study of triplet arylnitrenes and their dimerization reactionen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1089-5639&volume=107&issue=19&spage=3858&epage=3865&date=2003&atitle=Time-resolved+resonance+raman+study+of+triplet+arylnitrenes+and+their+dimerization+reactionen_HK
dc.identifier.emailPhillips, DL:phillips@hku.hken_HK
dc.identifier.authorityPhillips, DL=rp00770en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/jp021468men_HK
dc.identifier.scopuseid_2-s2.0-0038052177en_HK
dc.identifier.hkuros80987en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0038052177&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume107en_HK
dc.identifier.issue19en_HK
dc.identifier.spage3858en_HK
dc.identifier.epage3865en_HK
dc.identifier.isiWOS:000182893900037-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridOng, SY=7202336462en_HK
dc.identifier.scopusauthoridChan, PY=7403497922en_HK
dc.identifier.scopusauthoridZhu, P=7202169049en_HK
dc.identifier.scopusauthoridLeung, KH=7401860609en_HK
dc.identifier.scopusauthoridPhillips, DL=7404519365en_HK

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats