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Article: Synthesis, characterization and photophysics of luminescent organogold(I) phosphines

TitleSynthesis, characterization and photophysics of luminescent organogold(I) phosphines
Authors
Yam, VWWChoi, SWK
Issue Date1994
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal Of The Chemical Society, Dalton Transactions, 1994 n. 14, p. 2057-2059 How to Cite?
DOI: http://dx.doi.org/10.1039/DT9940002057
AbstractReaction of [Au2(dmpm)Cl2] or [Au3(dmmp)Cl3] with an excess of organolithium reagent LiR in diethyl ether gave [Au2(dmpm)R2] or [Au3(dmmp)R3] in high yield [dmpm = Me2PCH2PMe2; dmmp = Me2PCH2P(Me)CH2PMe2; R = Me or C6H4OMe-p]. These compounds were found to be emissive both in the solid state and in fluid solutions. An excited-state redox potential of -2.0(1) V vs. sodium chloride saturated calomel electrode has been estimated for [Au3(dmmp)(C6H4OMe-p)3].
Persistent Identifierhttp://hdl.handle.net/10722/69052
ISSN
1472-7773
ISI Accession Number ID
WOS:A1994NZ16700004

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_HK
dc.contributor.authorChoi, SWKen_HK
dc.date.accessioned2010-09-06T06:10:06Z-
dc.date.available2010-09-06T06:10:06Z-
dc.date.issued1994en_HK
dc.identifier.citationJournal Of The Chemical Society, Dalton Transactions, 1994 n. 14, p. 2057-2059en_HK
dc.identifier.issn1472-7773en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69052-
dc.description.abstractReaction of [Au2(dmpm)Cl2] or [Au3(dmmp)Cl3] with an excess of organolithium reagent LiR in diethyl ether gave [Au2(dmpm)R2] or [Au3(dmmp)R3] in high yield [dmpm = Me2PCH2PMe2; dmmp = Me2PCH2P(Me)CH2PMe2; R = Me or C6H4OMe-p]. These compounds were found to be emissive both in the solid state and in fluid solutions. An excited-state redox potential of -2.0(1) V vs. sodium chloride saturated calomel electrode has been estimated for [Au3(dmmp)(C6H4OMe-p)3].en_HK
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_HK
dc.relation.ispartofJournal of the Chemical Society, Dalton Transactionsen_HK
dc.titleSynthesis, characterization and photophysics of luminescent organogold(I) phosphinesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1472-7773&volume=Issue No14&spage=2057&epage=2059&date=1994&atitle=Synthesis,+characterization+and+photophysics+of+luminescent+organogold+(I)+phosphinesen_HK
dc.identifier.emailYam, VWW:wwyam@hku.hken_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/DT9940002057en_HK
dc.identifier.scopuseid_2-s2.0-37049069945en_HK
dc.identifier.hkuros1368en_HK
dc.identifier.issue14en_HK
dc.identifier.spage2057en_HK
dc.identifier.epage2059en_HK
dc.identifier.isiWOS:A1994NZ16700004-
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK
dc.identifier.scopusauthoridChoi, SWK=14526815000en_HK
dc.identifier.issnl1364-5447-

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