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Article: Synthesis, characterization and photophysics of luminescent organogold(I) phosphines

TitleSynthesis, characterization and photophysics of luminescent organogold(I) phosphines
Authors
Issue Date1994
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal Of The Chemical Society, Dalton Transactions, 1994 n. 14, p. 2057-2059 How to Cite?
AbstractReaction of [Au2(dmpm)Cl2] or [Au3(dmmp)Cl3] with an excess of organolithium reagent LiR in diethyl ether gave [Au2(dmpm)R2] or [Au3(dmmp)R3] in high yield [dmpm = Me2PCH2PMe2; dmmp = Me2PCH2P(Me)CH2PMe2; R = Me or C6H4OMe-p]. These compounds were found to be emissive both in the solid state and in fluid solutions. An excited-state redox potential of -2.0(1) V vs. sodium chloride saturated calomel electrode has been estimated for [Au3(dmmp)(C6H4OMe-p)3].
Persistent Identifierhttp://hdl.handle.net/10722/69052
ISSN
2002 Impact Factor: 3.023
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_HK
dc.contributor.authorChoi, SWKen_HK
dc.date.accessioned2010-09-06T06:10:06Z-
dc.date.available2010-09-06T06:10:06Z-
dc.date.issued1994en_HK
dc.identifier.citationJournal Of The Chemical Society, Dalton Transactions, 1994 n. 14, p. 2057-2059en_HK
dc.identifier.issn1472-7773en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69052-
dc.description.abstractReaction of [Au2(dmpm)Cl2] or [Au3(dmmp)Cl3] with an excess of organolithium reagent LiR in diethyl ether gave [Au2(dmpm)R2] or [Au3(dmmp)R3] in high yield [dmpm = Me2PCH2PMe2; dmmp = Me2PCH2P(Me)CH2PMe2; R = Me or C6H4OMe-p]. These compounds were found to be emissive both in the solid state and in fluid solutions. An excited-state redox potential of -2.0(1) V vs. sodium chloride saturated calomel electrode has been estimated for [Au3(dmmp)(C6H4OMe-p)3].en_HK
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_HK
dc.relation.ispartofJournal of the Chemical Society, Dalton Transactionsen_HK
dc.titleSynthesis, characterization and photophysics of luminescent organogold(I) phosphinesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1472-7773&volume=Issue No14&spage=2057&epage=2059&date=1994&atitle=Synthesis,+characterization+and+photophysics+of+luminescent+organogold+(I)+phosphinesen_HK
dc.identifier.emailYam, VWW:wwyam@hku.hken_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/DT9940002057en_HK
dc.identifier.scopuseid_2-s2.0-37049069945en_HK
dc.identifier.hkuros1368en_HK
dc.identifier.issue14en_HK
dc.identifier.spage2057en_HK
dc.identifier.epage2059en_HK
dc.identifier.isiWOS:A1994NZ16700004-
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK
dc.identifier.scopusauthoridChoi, SWK=14526815000en_HK

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