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Article: Stereoselective formation of a single-stranded helicate: Structure of a bis(palladium-allyl)quaterpyridine complex and its use in catalytic enantioselective allylic substitution

TitleStereoselective formation of a single-stranded helicate: Structure of a bis(palladium-allyl)quaterpyridine complex and its use in catalytic enantioselective allylic substitution
Authors
Issue Date2006
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Chemical Communications, 2006 n. 46, p. 4841-4843 How to Cite?
AbstractChiral C2-symmetric quaterpyridine L reacts with [Pd(η3-C3H5)Cl]2 to form a chiral single-stranded helical binuclear palladium complex of formula [Pd 2(η3-C3H5)2(L)] 2+; the complex can efficiently catalyze allylic substitution of 1,3-diphenylprop-2-enyl acetate with dimethyl malonate with enantioselectivity up to 85%. © The Royal Society of Chemistry 2006.
Persistent Identifierhttp://hdl.handle.net/10722/69048
ISSN
2015 Impact Factor: 6.567
2015 SCImago Journal Rankings: 2.771
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorKwong, HLen_HK
dc.contributor.authorYeung, HLen_HK
dc.contributor.authorLee, WSen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:10:04Z-
dc.date.available2010-09-06T06:10:04Z-
dc.date.issued2006en_HK
dc.identifier.citationChemical Communications, 2006 n. 46, p. 4841-4843en_HK
dc.identifier.issn1359-7345en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69048-
dc.description.abstractChiral C2-symmetric quaterpyridine L reacts with [Pd(η3-C3H5)Cl]2 to form a chiral single-stranded helical binuclear palladium complex of formula [Pd 2(η3-C3H5)2(L)] 2+; the complex can efficiently catalyze allylic substitution of 1,3-diphenylprop-2-enyl acetate with dimethyl malonate with enantioselectivity up to 85%. © The Royal Society of Chemistry 2006.en_HK
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_HK
dc.relation.ispartofChemical Communicationsen_HK
dc.titleStereoselective formation of a single-stranded helicate: Structure of a bis(palladium-allyl)quaterpyridine complex and its use in catalytic enantioselective allylic substitutionen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1359-7345&volume=46&spage=4841&epage=4843&date=2006&atitle=Stereoselective+Formation+of+a+Single-stranded+Helicate:+Structure+of+a+Bis+(Palladium-allyl)+Quaterpyridine+Complex+and+its+use+in+Catalytic+Enantioselective+Allylic+Substitution+en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/b608481hen_HK
dc.identifier.scopuseid_2-s2.0-33751341025en_HK
dc.identifier.hkuros127617en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-33751341025&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.issue46en_HK
dc.identifier.spage4841en_HK
dc.identifier.epage4843en_HK
dc.identifier.isiWOS:000242220200018-
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridKwong, HL=35569416300en_HK
dc.identifier.scopusauthoridYeung, HL=13103321700en_HK
dc.identifier.scopusauthoridLee, WS=7407089119en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK

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