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Article: Conformation selective electronic excitation of iodocyclohexane and Franck-Condon region photodissociation dynamics from emission spectroscopy

TitleConformation selective electronic excitation of iodocyclohexane and Franck-Condon region photodissociation dynamics from emission spectroscopy
Authors
Issue Date1997
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett
Citation
Chemical Physics Letters, 1997, v. 276 n. 3-4, p. 224-232 How to Cite?
AbstractConformation selective resonance emission spectra are reported for gas-phase iodocyclohexane with excitation wave-lengths of 199.8 and 204.2 nm. These spectra reveal seven Franck-Condon active vibrational modes for the axial conformation and eleven Franck-Condon vibrations for the equatorial conformation, and indicate that the initial dynamics on the B-and C-states have a complex multidimensional character with contributions from the CCC, CCH and HCI bending motions, torsional motions, and C-I, C-C, and C-H stretching motions for both conformations. The resonance emission spectra are generally consistent with the previously reported assignments of the far ultraviolet absorption spectra. © 1997 Elsevier Science B.V.
Persistent Identifierhttp://hdl.handle.net/10722/69037
ISSN
2015 Impact Factor: 1.86
2015 SCImago Journal Rankings: 0.757
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorZheng, Xen_HK
dc.contributor.authorPhillips, DLen_HK
dc.date.accessioned2010-09-06T06:09:58Z-
dc.date.available2010-09-06T06:09:58Z-
dc.date.issued1997en_HK
dc.identifier.citationChemical Physics Letters, 1997, v. 276 n. 3-4, p. 224-232en_HK
dc.identifier.issn0009-2614en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69037-
dc.description.abstractConformation selective resonance emission spectra are reported for gas-phase iodocyclohexane with excitation wave-lengths of 199.8 and 204.2 nm. These spectra reveal seven Franck-Condon active vibrational modes for the axial conformation and eleven Franck-Condon vibrations for the equatorial conformation, and indicate that the initial dynamics on the B-and C-states have a complex multidimensional character with contributions from the CCC, CCH and HCI bending motions, torsional motions, and C-I, C-C, and C-H stretching motions for both conformations. The resonance emission spectra are generally consistent with the previously reported assignments of the far ultraviolet absorption spectra. © 1997 Elsevier Science B.V.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cpletten_HK
dc.relation.ispartofChemical Physics Lettersen_HK
dc.rightsChemical Physics Letters. Copyright © Elsevier BV.en_HK
dc.titleConformation selective electronic excitation of iodocyclohexane and Franck-Condon region photodissociation dynamics from emission spectroscopyen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0009-2614&volume=276&spage=224&epage=232&date=1997&atitle=Conformation+selective+electronic+excitation+of+iodocyclohexane+and+Franck-Condon+region+photodissociation+dynamics+from+emission+spectroscopyen_HK
dc.identifier.emailPhillips, DL:phillips@hku.hken_HK
dc.identifier.authorityPhillips, DL=rp00770en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0009-2614(97)00837-3-
dc.identifier.scopuseid_2-s2.0-0031578414en_HK
dc.identifier.hkuros31682en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0031578414&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume276en_HK
dc.identifier.issue3-4en_HK
dc.identifier.spage224en_HK
dc.identifier.epage232en_HK
dc.identifier.isiWOS:A1997XY27700008-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridZheng, X=7404090253en_HK
dc.identifier.scopusauthoridPhillips, DL=7404519365en_HK

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