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Article: Synthesis and X-ray crystal structure of a chiral molybdenum porphyrin and its catalytic behaviour toward asymmetric epoxidation of aromatic alkenes

TitleSynthesis and X-ray crystal structure of a chiral molybdenum porphyrin and its catalytic behaviour toward asymmetric epoxidation of aromatic alkenes
Authors
KeywordsCatalyst
Epoxidation
Molybdenum
Porphyrin
Structure
Issue Date2001
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal Of Organometallic Chemistry, 2001, v. 634 n. 1, p. 34-38 How to Cite?
AbstractReaction of M(CO)6 with H2P* (5,10,15,20-tetrakis-{(1S,4R,5R,8S)-1,2,3,4,5,6,7,8-octahydro-1,4:5,8- dimethanoanthracene-9-yl}porphyrin) followed by treatment with methanol afforded [MoVO(P*)(OMe)] (1) in ~80% yield. Complex 1 was characterised by IR and ESR spectroscopy and X-ray structure determination. This chiral molybdenum porphyrin was found to catalyse the epoxidation of styrene, cis-β-methylstyrene, and 1,2-dihydronaphthalene with tert-butyl hydroperoxide in up to 29% ee. © 2001 Elsevier Science B.V.
Persistent Identifierhttp://hdl.handle.net/10722/69036
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLiu, WSen_HK
dc.contributor.authorZhang, Ren_HK
dc.contributor.authorHuang, JSen_HK
dc.contributor.authorChe, CMen_HK
dc.contributor.authorPeng, SMen_HK
dc.date.accessioned2010-09-06T06:09:58Z-
dc.date.available2010-09-06T06:09:58Z-
dc.date.issued2001en_HK
dc.identifier.citationJournal Of Organometallic Chemistry, 2001, v. 634 n. 1, p. 34-38en_HK
dc.identifier.issn0022-328Xen_HK
dc.identifier.urihttp://hdl.handle.net/10722/69036-
dc.description.abstractReaction of M(CO)6 with H2P* (5,10,15,20-tetrakis-{(1S,4R,5R,8S)-1,2,3,4,5,6,7,8-octahydro-1,4:5,8- dimethanoanthracene-9-yl}porphyrin) followed by treatment with methanol afforded [MoVO(P*)(OMe)] (1) in ~80% yield. Complex 1 was characterised by IR and ESR spectroscopy and X-ray structure determination. This chiral molybdenum porphyrin was found to catalyse the epoxidation of styrene, cis-β-methylstyrene, and 1,2-dihydronaphthalene with tert-butyl hydroperoxide in up to 29% ee. © 2001 Elsevier Science B.V.en_HK
dc.languageengen_HK
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchemen_HK
dc.relation.ispartofJournal of Organometallic Chemistryen_HK
dc.subjectCatalysten_HK
dc.subjectEpoxidationen_HK
dc.subjectMolybdenumen_HK
dc.subjectPorphyrinen_HK
dc.subjectStructureen_HK
dc.titleSynthesis and X-ray crystal structure of a chiral molybdenum porphyrin and its catalytic behaviour toward asymmetric epoxidation of aromatic alkenesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=634&spage=34&epage=38&date=2001&atitle=Synthesis+and+X-ray+crystal+structure+of+a+chiral+molybdenum+porphyrin+and+its+catalytic+behaviour+toward+asymmetric+epoxidation+of+aromatic+alkenesen_HK
dc.identifier.emailHuang, JS:jshuang@hkucc.hku.hken_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityHuang, JS=rp00709en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0022-328X(01)01075-0en_HK
dc.identifier.scopuseid_2-s2.0-0041903627en_HK
dc.identifier.hkuros71679en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0041903627&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume634en_HK
dc.identifier.issue1en_HK
dc.identifier.spage34en_HK
dc.identifier.epage38en_HK
dc.identifier.isiWOS:000171400300006-
dc.publisher.placeSwitzerlanden_HK
dc.identifier.scopusauthoridLiu, WS=8121250200en_HK
dc.identifier.scopusauthoridZhang, R=7404865969en_HK
dc.identifier.scopusauthoridHuang, JS=7407192639en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.scopusauthoridPeng, SM=35464852200en_HK

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