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Article: Reactions of SmI2(THF)x with [Cp'Mo(CO)3]2Hg(Cp' = C5H5- or C5Me5-): crystal and molecular structures of [(THF)4I2Sm(m-OC)Mo(CO)2(C2H5)] and [(C5Me5)Mo(CO)3]2

TitleReactions of SmI2(THF)x with [Cp'Mo(CO)3]2Hg(Cp' = C5H5- or C5Me5-): crystal and molecular structures of [(THF)4I2Sm(m-OC)Mo(CO)2(C2H5)] and [(C5Me5)Mo(CO)3]2
Authors
KeywordsCarbonyl
Crystal structure
Molybdenum
Samarium
Issue Date1996
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal of Organometallic Chemistry, 1996, v. 522 n. 2, p. 271-275 How to Cite?
AbstractThe reactions of SmI2(THF)x with [Cp′Mo(CO)3]2Hg (Cp′  C5H5− or C5Me5−) in THF at ambient temperature have been investigated. In the case of [(C5H5)Mo(CO)3]2Hg, a new complex of [(THF)4I2sm(μ-OC)Mo(CO)2(C5H5)] 1 was afforded, However, in the reaction involving [(C5Me5)Mo(CO)3]2Hg the analog cannot be obtained, but instead the dimeric [C5Me5)Mo(CO)3]22. Both complexes 1 and 2 have been characterized by X-ray crystallography. In 1 the cooperative activation of CO between Sm3+ and Mo was observed. The structure of complex 1 is the first example containing the “Sm(μ-OC)Mo” fragment.
Persistent Identifierhttp://hdl.handle.net/10722/69025
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorLin, GYen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:09:51Z-
dc.date.available2010-09-06T06:09:51Z-
dc.date.issued1996en_HK
dc.identifier.citationJournal of Organometallic Chemistry, 1996, v. 522 n. 2, p. 271-275en_HK
dc.identifier.issn0022-328Xen_HK
dc.identifier.urihttp://hdl.handle.net/10722/69025-
dc.description.abstractThe reactions of SmI2(THF)x with [Cp′Mo(CO)3]2Hg (Cp′  C5H5− or C5Me5−) in THF at ambient temperature have been investigated. In the case of [(C5H5)Mo(CO)3]2Hg, a new complex of [(THF)4I2sm(μ-OC)Mo(CO)2(C5H5)] 1 was afforded, However, in the reaction involving [(C5Me5)Mo(CO)3]2Hg the analog cannot be obtained, but instead the dimeric [C5Me5)Mo(CO)3]22. Both complexes 1 and 2 have been characterized by X-ray crystallography. In 1 the cooperative activation of CO between Sm3+ and Mo was observed. The structure of complex 1 is the first example containing the “Sm(μ-OC)Mo” fragment.-
dc.languageengen_HK
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchemen_HK
dc.relation.ispartofJournal of Organometallic Chemistryen_HK
dc.subjectCarbonyl-
dc.subjectCrystal structure-
dc.subjectMolybdenum-
dc.subjectSamarium-
dc.titleReactions of SmI2(THF)x with [Cp'Mo(CO)3]2Hg(Cp' = C5H5- or C5Me5-): crystal and molecular structures of [(THF)4I2Sm(m-OC)Mo(CO)2(C2H5)] and [(C5Me5)Mo(CO)3]2en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=522&spage=271&epage=275&date=1996&atitle=Reactions+of+SmI2(THF)x+with+[Cp%27Mo(CO)3]2+Hg(Cp%27+=+C5H5-+or+C5Me5-):++crystal+and+molecular+structures+of+[(THF)4I2Sm(m-OC)Mo(CO)2(C2H5)]+and+[(C5Me5)Mo(CO)3]2en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1016/0022-328X(96)06282-1-
dc.identifier.scopuseid_2-s2.0-0030595183-
dc.identifier.hkuros21867en_HK
dc.identifier.issue2-
dc.identifier.isiWOS:A1996VH20500014-

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