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Article: A novel prismane cluster. Synthesis and crystal structure of a dimer of [(triphenylphosphine) copper(2-picoline)copper] oxotrithiomolybdenum, [Cu4Mo2S6][C6H5 3P]2(C6H7N)2O2·2C6H7N

TitleA novel prismane cluster. Synthesis and crystal structure of a dimer of [(triphenylphosphine) copper(2-picoline)copper] oxotrithiomolybdenum, [Cu4Mo2S6][C6H5 3P]2(C6H7N)2O2·2C6H7N
Authors
KeywordsMo-Cu-S cluster
Prismane cluster
Synthesis
X-ray structure
Issue Date1998
PublisherTaylor & Francis Ltd. The Journal's web site is located at http://www.tandf.co.uk/journals/titles/00958972.asp
Citation
Journal Of Coordination Chemistry, 1998, v. 46 n. 1, p. 43-49 How to Cite?
AbstractThe prismane cluster [Cu4Mo2S6][(C6H5) 3P]2(C6H7N)2O2 · 2C6H7N has been prepared by the reaction of [NH4]2MoO2S2 with CuBr and PPh3 in 2-picoline. Its molecular structure was determined by single-crystal X-ray analysis. The compound crystallizes in the monoclinic space group P2I/n with a = 12.149(2), b = 17.152(2), c = 15.793(2)Å, β = 105.40(2)°, and Z = 2. The X-ray structure (R; Ru = 0.046; 0.048) revealed a 12-atom Cu4Mo2S6 prismane which can be envisaged as consisting of two MoOS3 units connected on adjacent edges by two different groups, [C6H7NCu] and [(C6H5)3PCu].
Persistent Identifierhttp://hdl.handle.net/10722/69012
ISSN
2015 Impact Factor: 1.756
2015 SCImago Journal Rankings: 0.404
References

 

DC FieldValueLanguage
dc.contributor.authorLiu, Yen_HK
dc.contributor.authorXin, XQen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:09:45Z-
dc.date.available2010-09-06T06:09:45Z-
dc.date.issued1998en_HK
dc.identifier.citationJournal Of Coordination Chemistry, 1998, v. 46 n. 1, p. 43-49en_HK
dc.identifier.issn0095-8972en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69012-
dc.description.abstractThe prismane cluster [Cu4Mo2S6][(C6H5) 3P]2(C6H7N)2O2 · 2C6H7N has been prepared by the reaction of [NH4]2MoO2S2 with CuBr and PPh3 in 2-picoline. Its molecular structure was determined by single-crystal X-ray analysis. The compound crystallizes in the monoclinic space group P2I/n with a = 12.149(2), b = 17.152(2), c = 15.793(2)Å, β = 105.40(2)°, and Z = 2. The X-ray structure (R; Ru = 0.046; 0.048) revealed a 12-atom Cu4Mo2S6 prismane which can be envisaged as consisting of two MoOS3 units connected on adjacent edges by two different groups, [C6H7NCu] and [(C6H5)3PCu].en_HK
dc.languageengen_HK
dc.publisherTaylor & Francis Ltd. The Journal's web site is located at http://www.tandf.co.uk/journals/titles/00958972.aspen_HK
dc.relation.ispartofJournal of Coordination Chemistryen_HK
dc.subjectMo-Cu-S clusteren_HK
dc.subjectPrismane clusteren_HK
dc.subjectSynthesisen_HK
dc.subjectX-ray structureen_HK
dc.titleA novel prismane cluster. Synthesis and crystal structure of a dimer of [(triphenylphosphine) copper(2-picoline)copper] oxotrithiomolybdenum, [Cu4Mo2S6][C6H5 3P]2(C6H7N)2O2·2C6H7Nen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0095-8972&volume=46&spage=43&epage=49&date=1998&atitle=A+novel+prismane+cluster.++Synthesis+and+crystal+structure+of+a+dimer+of+[(Triphenylphosphine)copper(2-picoline)copper]oxotrithiomolybdenum,+[(Cu4Mo2S6][(C6H5)3P]2(C6H7N)2O2.2C6H7Nen_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1080/00958979808047193-
dc.identifier.scopuseid_2-s2.0-2742578454en_HK
dc.identifier.hkuros40337en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-2742578454&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume46en_HK
dc.identifier.issue1en_HK
dc.identifier.spage43en_HK
dc.identifier.epage49en_HK
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridLiu, Y=36012292400en_HK
dc.identifier.scopusauthoridXin, XQ=7102700870en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK

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