File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Synthesis and characterization of luminescent rhenium(I)-platinum(II) polypyridine bichromophoric alkynyl-bridged molecular rods

TitleSynthesis and characterization of luminescent rhenium(I)-platinum(II) polypyridine bichromophoric alkynyl-bridged molecular rods
Authors
Issue Date2005
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallics
Citation
Organometallics, 2005, v. 24 n. 17, p. 4298-4305 How to Cite?
AbstractThe first class of luminescent heterobimetallic rhenium(I)-platinum(II) polypyridine alkynyl complexes, [(N∧N)(CO)3Re{C≡C-(C 6H4)n-C≡C}Pt(N∧N∧N)]OTf (N∧N = bpy, tBu2-bpy, (CF3)2bpy, NO 2phen; N∧N∧N = tpy, tBu3tpy; n = 0,1), has been successfully synthesized. The X-ray crystal structures of [(bpy)(CO)3Re{C≡C-C6H4-C≡C}Pt( tBu3tpy)]OTf (1) and [(NO2phen)(CO) 3Re{C≡C-C6H4-C≡C}Pt( tBu3tpy)]OTf (4) have been determined. Their photophysical and electrochemical behavior have also been studied and discussed. An unexpected localization of the lowest-energy emissive state on the platinum(II) terpyridyl moiety in these heterometallic bichromophoric systems was observed. © 2005 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/69010
ISSN
2015 Impact Factor: 4.186
2015 SCImago Journal Rankings: 2.043
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLam, SCFen_HK
dc.contributor.authorYam, VWWen_HK
dc.contributor.authorWong, KMCen_HK
dc.contributor.authorCheng, ECCen_HK
dc.contributor.authorZhu, Nen_HK
dc.date.accessioned2010-09-06T06:09:44Z-
dc.date.available2010-09-06T06:09:44Z-
dc.date.issued2005en_HK
dc.identifier.citationOrganometallics, 2005, v. 24 n. 17, p. 4298-4305en_HK
dc.identifier.issn0276-7333en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69010-
dc.description.abstractThe first class of luminescent heterobimetallic rhenium(I)-platinum(II) polypyridine alkynyl complexes, [(N∧N)(CO)3Re{C≡C-(C 6H4)n-C≡C}Pt(N∧N∧N)]OTf (N∧N = bpy, tBu2-bpy, (CF3)2bpy, NO 2phen; N∧N∧N = tpy, tBu3tpy; n = 0,1), has been successfully synthesized. The X-ray crystal structures of [(bpy)(CO)3Re{C≡C-C6H4-C≡C}Pt( tBu3tpy)]OTf (1) and [(NO2phen)(CO) 3Re{C≡C-C6H4-C≡C}Pt( tBu3tpy)]OTf (4) have been determined. Their photophysical and electrochemical behavior have also been studied and discussed. An unexpected localization of the lowest-energy emissive state on the platinum(II) terpyridyl moiety in these heterometallic bichromophoric systems was observed. © 2005 American Chemical Society.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallicsen_HK
dc.relation.ispartofOrganometallicsen_HK
dc.titleSynthesis and characterization of luminescent rhenium(I)-platinum(II) polypyridine bichromophoric alkynyl-bridged molecular rodsen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0276-7333&volume=24&spage=4298&epage=4305&date=2005&atitle=Synthesis+and+characterization+of+luminescent+rhenium(I)+--+platinum(II)+polypyridine+bichromophoric+alkynyl-bridged+molecular+rodsen_HK
dc.identifier.emailYam, VWW: wwyam@hku.hken_HK
dc.identifier.emailWong, KMC: wongmc@hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.identifier.authorityWong, KMC=rp00809en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/om0502887en_HK
dc.identifier.scopuseid_2-s2.0-23844450028en_HK
dc.identifier.hkuros117603en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-23844450028&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume24en_HK
dc.identifier.issue17en_HK
dc.identifier.spage4298en_HK
dc.identifier.epage4305en_HK
dc.identifier.isiWOS:000231124400030-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridLam, SCF=7402279761en_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK
dc.identifier.scopusauthoridWong, KMC=8061067200en_HK
dc.identifier.scopusauthoridCheng, ECC=7201743424en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats