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Article: Versatile precursors for multinuclear platinum(II) alkynyl assembly - Synthesis, structural characterization and electrochemical studies of luminescent platinum(II) alkynyl complexes

TitleVersatile precursors for multinuclear platinum(II) alkynyl assembly - Synthesis, structural characterization and electrochemical studies of luminescent platinum(II) alkynyl complexes
Authors
Issue Date2003
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/njc
Citation
New Journal Of Chemistry, 2003, v. 27 n. 1, p. 150-154 How to Cite?
AbstractNewly synthesized diethynylcarbazole-bridged platinum(II) complex 3,6-{ClPt(PEt3)2C≡C}2-9-n BuCarb (nBuCarb = n-butylcarbazole) and terpyridyl-containing platinum(II) alkynyl complex [Pt(tBu3trpy)(C≡CC6H4 C≡CH)]OTf were shown to serve as versatile precursors for the assembly of a novel luminescent tetranuclear platinum(II) alkynyl complex [3,6-{Pt(tBu3trpy)(C≡CC6H4 C≡C)Pt(PEt3)2C≡C}2-9- nBuCarb](OTf)2. A divergent route can also be applied to synthesize the tetranuclear complex in three steps, involving the use of trimethylsilyl protecting groups on the alkynyl ligand.
Persistent Identifierhttp://hdl.handle.net/10722/68850
ISSN
2015 Impact Factor: 3.277
2015 SCImago Journal Rankings: 0.987
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorTao, CHen_HK
dc.contributor.authorWong, KMCen_HK
dc.contributor.authorZhu, Nen_HK
dc.contributor.authorYam, VWWen_HK
dc.date.accessioned2010-09-06T06:08:17Z-
dc.date.available2010-09-06T06:08:17Z-
dc.date.issued2003en_HK
dc.identifier.citationNew Journal Of Chemistry, 2003, v. 27 n. 1, p. 150-154en_HK
dc.identifier.issn1144-0546en_HK
dc.identifier.urihttp://hdl.handle.net/10722/68850-
dc.description.abstractNewly synthesized diethynylcarbazole-bridged platinum(II) complex 3,6-{ClPt(PEt3)2C≡C}2-9-n BuCarb (nBuCarb = n-butylcarbazole) and terpyridyl-containing platinum(II) alkynyl complex [Pt(tBu3trpy)(C≡CC6H4 C≡CH)]OTf were shown to serve as versatile precursors for the assembly of a novel luminescent tetranuclear platinum(II) alkynyl complex [3,6-{Pt(tBu3trpy)(C≡CC6H4 C≡C)Pt(PEt3)2C≡C}2-9- nBuCarb](OTf)2. A divergent route can also be applied to synthesize the tetranuclear complex in three steps, involving the use of trimethylsilyl protecting groups on the alkynyl ligand.en_HK
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/njcen_HK
dc.relation.ispartofNew Journal of Chemistryen_HK
dc.titleVersatile precursors for multinuclear platinum(II) alkynyl assembly - Synthesis, structural characterization and electrochemical studies of luminescent platinum(II) alkynyl complexesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1144-0546&volume=27&spage=150&epage=154&date=2003&atitle=Versatile+precursors+for+multinuclear+platinum(II)+alkynyl+assembly+-+synthesis,+structural+characterization+and+electrochemical+studies+of+luminescent+platinum(II)+alkynyl+complexesen_HK
dc.identifier.emailWong, KMC: wongmc@hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.emailYam, VWW: wwyam@hku.hken_HK
dc.identifier.authorityWong, KMC=rp00809en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/b210772ben_HK
dc.identifier.scopuseid_2-s2.0-0037240885en_HK
dc.identifier.hkuros83145en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0037240885&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume27en_HK
dc.identifier.issue1en_HK
dc.identifier.spage150en_HK
dc.identifier.epage154en_HK
dc.identifier.isiWOS:000180272200024-
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridTao, CH=7102146421en_HK
dc.identifier.scopusauthoridWong, KMC=8061067200en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK

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