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Article: Versatile precursors for multinuclear platinum(II) alkynyl assembly - Synthesis, structural characterization and electrochemical studies of luminescent platinum(II) alkynyl complexes
Title | Versatile precursors for multinuclear platinum(II) alkynyl assembly - Synthesis, structural characterization and electrochemical studies of luminescent platinum(II) alkynyl complexes |
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Authors | |
Issue Date | 2003 |
Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/njc |
Citation | New Journal Of Chemistry, 2003, v. 27 n. 1, p. 150-154 How to Cite? |
Abstract | Newly synthesized diethynylcarbazole-bridged platinum(II) complex 3,6-{ClPt(PEt3)2C≡C}2-9-n BuCarb (nBuCarb = n-butylcarbazole) and terpyridyl-containing platinum(II) alkynyl complex [Pt(tBu3trpy)(C≡CC6H4 C≡CH)]OTf were shown to serve as versatile precursors for the assembly of a novel luminescent tetranuclear platinum(II) alkynyl complex [3,6-{Pt(tBu3trpy)(C≡CC6H4 C≡C)Pt(PEt3)2C≡C}2-9- nBuCarb](OTf)2. A divergent route can also be applied to synthesize the tetranuclear complex in three steps, involving the use of trimethylsilyl protecting groups on the alkynyl ligand. |
Persistent Identifier | http://hdl.handle.net/10722/68850 |
ISSN | 2023 Impact Factor: 2.7 2023 SCImago Journal Rankings: 0.521 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Tao, CH | en_HK |
dc.contributor.author | Wong, KMC | en_HK |
dc.contributor.author | Zhu, N | en_HK |
dc.contributor.author | Yam, VWW | en_HK |
dc.date.accessioned | 2010-09-06T06:08:17Z | - |
dc.date.available | 2010-09-06T06:08:17Z | - |
dc.date.issued | 2003 | en_HK |
dc.identifier.citation | New Journal Of Chemistry, 2003, v. 27 n. 1, p. 150-154 | en_HK |
dc.identifier.issn | 1144-0546 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/68850 | - |
dc.description.abstract | Newly synthesized diethynylcarbazole-bridged platinum(II) complex 3,6-{ClPt(PEt3)2C≡C}2-9-n BuCarb (nBuCarb = n-butylcarbazole) and terpyridyl-containing platinum(II) alkynyl complex [Pt(tBu3trpy)(C≡CC6H4 C≡CH)]OTf were shown to serve as versatile precursors for the assembly of a novel luminescent tetranuclear platinum(II) alkynyl complex [3,6-{Pt(tBu3trpy)(C≡CC6H4 C≡C)Pt(PEt3)2C≡C}2-9- nBuCarb](OTf)2. A divergent route can also be applied to synthesize the tetranuclear complex in three steps, involving the use of trimethylsilyl protecting groups on the alkynyl ligand. | en_HK |
dc.language | eng | en_HK |
dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/njc | en_HK |
dc.relation.ispartof | New Journal of Chemistry | en_HK |
dc.title | Versatile precursors for multinuclear platinum(II) alkynyl assembly - Synthesis, structural characterization and electrochemical studies of luminescent platinum(II) alkynyl complexes | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1144-0546&volume=27&spage=150&epage=154&date=2003&atitle=Versatile+precursors+for+multinuclear+platinum(II)+alkynyl+assembly+-+synthesis,+structural+characterization+and+electrochemical+studies+of+luminescent+platinum(II)+alkynyl+complexes | en_HK |
dc.identifier.email | Wong, KMC: wongmc@hku.hk | en_HK |
dc.identifier.email | Zhu, N: nzhu@hkucc.hku.hk | en_HK |
dc.identifier.email | Yam, VWW: wwyam@hku.hk | en_HK |
dc.identifier.authority | Wong, KMC=rp00809 | en_HK |
dc.identifier.authority | Zhu, N=rp00845 | en_HK |
dc.identifier.authority | Yam, VWW=rp00822 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1039/b210772b | en_HK |
dc.identifier.scopus | eid_2-s2.0-0037240885 | en_HK |
dc.identifier.hkuros | 83145 | en_HK |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0037240885&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 27 | en_HK |
dc.identifier.issue | 1 | en_HK |
dc.identifier.spage | 150 | en_HK |
dc.identifier.epage | 154 | en_HK |
dc.identifier.isi | WOS:000180272200024 | - |
dc.publisher.place | United Kingdom | en_HK |
dc.identifier.scopusauthorid | Tao, CH=7102146421 | en_HK |
dc.identifier.scopusauthorid | Wong, KMC=8061067200 | en_HK |
dc.identifier.scopusauthorid | Zhu, N=7201449530 | en_HK |
dc.identifier.scopusauthorid | Yam, VWW=18539304700 | en_HK |
dc.identifier.issnl | 1144-0546 | - |