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Article: A new supramolecular macrocyclici host incorporated with ruthenocene ionosphere-synthesis and X-ray crystal structure of N,N,N-tris(ruthenocenylmethyl)-1,4,7-triazacyclononane perchlorate

TitleA new supramolecular macrocyclici host incorporated with ruthenocene ionosphere-synthesis and X-ray crystal structure of N,N,N-tris(ruthenocenylmethyl)-1,4,7-triazacyclononane perchlorate
Authors
KeywordsRuthenocene
Tacn
Protonation
Molecular structure
Supramolecular host
Issue Date1997
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly
Citation
Polyhedron, 1997, v. 16 n. 16, p. 2889-2891 How to Cite?
AbstractThe supramolecular host molecule N,N′,N′-tris(ruthenocenylmethyl)-1,4,7-triazacyclononane perchlorate [LH] ClO4 was prepared and its molecular structure was determined by single crystal X-ray analysis. The guest proton was localized on one of the aza atoms of the macrocycle (N--H : 0.71 Å). Cyclic voltammetric measurement displays in irreversible oxidation wave at 0.84 V and is attributable to the oxidation of RuII to RuIII of the appended metallocenes.
Persistent Identifierhttp://hdl.handle.net/10722/68825
ISSN
2015 Impact Factor: 2.108
2015 SCImago Journal Rankings: 0.592
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorYin, YGen_HK
dc.contributor.authorCheung, KKen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:08:04Z-
dc.date.available2010-09-06T06:08:04Z-
dc.date.issued1997en_HK
dc.identifier.citationPolyhedron, 1997, v. 16 n. 16, p. 2889-2891en_HK
dc.identifier.issn0277-5387en_HK
dc.identifier.urihttp://hdl.handle.net/10722/68825-
dc.description.abstractThe supramolecular host molecule N,N′,N′-tris(ruthenocenylmethyl)-1,4,7-triazacyclononane perchlorate [LH] ClO4 was prepared and its molecular structure was determined by single crystal X-ray analysis. The guest proton was localized on one of the aza atoms of the macrocycle (N--H : 0.71 Å). Cyclic voltammetric measurement displays in irreversible oxidation wave at 0.84 V and is attributable to the oxidation of RuII to RuIII of the appended metallocenes.-
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/polyen_HK
dc.relation.ispartofPolyhedronen_HK
dc.rightsNOTICE: this is the author’s version of a work that was accepted for publication in <Journal title>. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in PUBLICATION, [VOL#, ISSUE#, (DATE)] DOI#en_HK
dc.subjectRuthenocene-
dc.subjectTacn-
dc.subjectProtonation-
dc.subjectMolecular structure-
dc.subjectSupramolecular host-
dc.titleA new supramolecular macrocyclici host incorporated with ruthenocene ionosphere-synthesis and X-ray crystal structure of N,N,N-tris(ruthenocenylmethyl)-1,4,7-triazacyclononane perchlorateen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0277-5387&volume=16&issue=16&spage=2889&epage=2891&date=1997&atitle=A+new+supramolecular+macrocyclici+host+incorporated+with+ruthenocene+ionosphere-synthesis+and+X-ray+crystal+structure+of+N,N%27N%27-tris(ruthenocenylmethyl)-1,4,7-triazacyclononane+perchlorateen_HK
dc.identifier.emailCheung, KK: kkcheung@hkucc.hku.hken_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1016/S0277-5387(97)00035-1-
dc.identifier.hkuros24986en_HK
dc.identifier.volume16-
dc.identifier.issue16-
dc.identifier.spage2889-
dc.identifier.epage2891-
dc.identifier.isiWOS:A1997XC47600028-
dc.publisher.placeNetherlands-

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