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Article: Lanthanide perchlorate complexes with 1,4-bis(phenylsulfinyl)butane: Structures and luminescent properties

TitleLanthanide perchlorate complexes with 1,4-bis(phenylsulfinyl)butane: Structures and luminescent properties
Authors
Issue Date2004
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/njc
Citation
New Journal Of Chemistry, 2004, v. 28 n. 2, p. 261-265 How to Cite?
AbstractFive representative lanthanide coordination compounds with a disulfoxide ligand [L = 1,4-bis(phenylsulfinyl)butane], [Ln(L)4](ClO 4)3 (Ln = La, 1; Eu, 2; Gd, 3; Tb, 4; Yb, 5), have been synthesized and structurally characterized by single-crystal X-ray diffraction. These compounds have isostructural mononuclear structures, in which the ligand L coordinates to the metal ions through O donors in chelating coordination mode. The luminescence studies of 2 and 4 in the solid state and solution exhibit the usual metal-centred emission spectra arising from ligand-to-metal energy transfer, and their intensity and lifetimes are increased compared to those of previously reported analogous complexes {[Ln(L)2(DMF) 4](ClO4)3·nH2O} ∞ (Ln = Eu, n = 4, 6; Ln = Tb, n = 3, 7). The stability of these complexes in solution was also investigated.
Persistent Identifierhttp://hdl.handle.net/10722/68806
ISSN
2015 Impact Factor: 3.277
2015 SCImago Journal Rankings: 0.987
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLi, JRen_HK
dc.contributor.authorBu, XHen_HK
dc.contributor.authorZhang, RHen_HK
dc.contributor.authorDuan, CYen_HK
dc.contributor.authorWong, KMCen_HK
dc.contributor.authorYam, VWWen_HK
dc.date.accessioned2010-09-06T06:07:54Z-
dc.date.available2010-09-06T06:07:54Z-
dc.date.issued2004en_HK
dc.identifier.citationNew Journal Of Chemistry, 2004, v. 28 n. 2, p. 261-265en_HK
dc.identifier.issn1144-0546en_HK
dc.identifier.urihttp://hdl.handle.net/10722/68806-
dc.description.abstractFive representative lanthanide coordination compounds with a disulfoxide ligand [L = 1,4-bis(phenylsulfinyl)butane], [Ln(L)4](ClO 4)3 (Ln = La, 1; Eu, 2; Gd, 3; Tb, 4; Yb, 5), have been synthesized and structurally characterized by single-crystal X-ray diffraction. These compounds have isostructural mononuclear structures, in which the ligand L coordinates to the metal ions through O donors in chelating coordination mode. The luminescence studies of 2 and 4 in the solid state and solution exhibit the usual metal-centred emission spectra arising from ligand-to-metal energy transfer, and their intensity and lifetimes are increased compared to those of previously reported analogous complexes {[Ln(L)2(DMF) 4](ClO4)3·nH2O} ∞ (Ln = Eu, n = 4, 6; Ln = Tb, n = 3, 7). The stability of these complexes in solution was also investigated.en_HK
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/njcen_HK
dc.relation.ispartofNew Journal of Chemistryen_HK
dc.titleLanthanide perchlorate complexes with 1,4-bis(phenylsulfinyl)butane: Structures and luminescent propertiesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1144-0546&volume=28&spage=261&epage=265&date=2004&atitle=Lanthanide+perchlorate+complexes+with+1,4-bis(phenylsulfinyl)butane:+structures+and+luminescent+propertiesen_HK
dc.identifier.emailWong, KMC:wongmc@hku.hken_HK
dc.identifier.emailYam, VWW:wwyam@hku.hken_HK
dc.identifier.authorityWong, KMC=rp00809en_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/b308473fen_HK
dc.identifier.scopuseid_2-s2.0-1542299109en_HK
dc.identifier.hkuros92794en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-1542299109&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume28en_HK
dc.identifier.issue2en_HK
dc.identifier.spage261en_HK
dc.identifier.epage265en_HK
dc.identifier.isiWOS:000189352700016-
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridLi, JR=35604205800en_HK
dc.identifier.scopusauthoridBu, XH=7103052967en_HK
dc.identifier.scopusauthoridZhang, RH=7404864496en_HK
dc.identifier.scopusauthoridDuan, CY=7202652564en_HK
dc.identifier.scopusauthoridWong, KMC=8061067200en_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK

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