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Article: Intramolecular cyclization of benzyl-substituted cyclopentadienyl titanium dichlorides promoted by boron tribromide

TitleIntramolecular cyclization of benzyl-substituted cyclopentadienyl titanium dichlorides promoted by boron tribromide
Authors
KeywordsChemical modification
Chemical reaction
Chemical structure
Complex formation
Controlled study
Issue Date2002
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal of Organometallic Chemistry, 2002, v. 645 n. 1-2, p. 59-64 How to Cite?
AbstractIntramolecular cyclization of α,α-alkyl-ortho-methoxybenzylcyclopentadienyl titanium complexes to form titanoxacycle complexes promoted by BBr3 has been studied. A probable two-step mechanism involving halogen exchange and intramolecular elimination was proposed. Four related benzyl-substituted cyclopentadienyl titanium complexes have been studied by X-ray crystallography.
Persistent Identifierhttp://hdl.handle.net/10722/68776
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorQian, Yen_HK
dc.contributor.authorHuang, Jen_HK
dc.contributor.authorDing, Ken_HK
dc.contributor.authorZhang, Yen_HK
dc.contributor.authorHuang, Qen_HK
dc.contributor.authorChen, XPen_HK
dc.contributor.authorChan, ASCen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:07:37Z-
dc.date.available2010-09-06T06:07:37Z-
dc.date.issued2002en_HK
dc.identifier.citationJournal of Organometallic Chemistry, 2002, v. 645 n. 1-2, p. 59-64en_HK
dc.identifier.issn0022-328Xen_HK
dc.identifier.urihttp://hdl.handle.net/10722/68776-
dc.description.abstractIntramolecular cyclization of α,α-alkyl-ortho-methoxybenzylcyclopentadienyl titanium complexes to form titanoxacycle complexes promoted by BBr3 has been studied. A probable two-step mechanism involving halogen exchange and intramolecular elimination was proposed. Four related benzyl-substituted cyclopentadienyl titanium complexes have been studied by X-ray crystallography.-
dc.languageengen_HK
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchemen_HK
dc.relation.ispartofJournal of Organometallic Chemistryen_HK
dc.subjectChemical modification-
dc.subjectChemical reaction-
dc.subjectChemical structure-
dc.subjectComplex formation-
dc.subjectControlled study-
dc.titleIntramolecular cyclization of benzyl-substituted cyclopentadienyl titanium dichlorides promoted by boron tribromideen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=645&spage=59&epage=64&date=2002&atitle=Intramolecular+cyclization+of+benzyl-substituted+cyclopentadienyl+titanium+dichlorides+promoted+by+boron+tribromideen_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1016/S0022-328X(01)01397-3-
dc.identifier.scopuseid_2-s2.0-0036159354-
dc.identifier.hkuros68283en_HK
dc.identifier.volume645-
dc.identifier.issue1-2-
dc.identifier.spage59-
dc.identifier.epage64-
dc.identifier.isiWOS:000174467200008-

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