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Article: Syntheses and characterizaton of high-nuclearity osmium-palladium mixed-metal carbonyl clusters; molecular structures of [Os4Pd6(CO)8(µ-CO)5(µ3-CO)3(µ-dppm)2]·0.5C6H14 and [Os5Pd4(µ6-C)(CO)12(µ-CO)3(µ-dppm)2]·CH2Cl2

TitleSyntheses and characterizaton of high-nuclearity osmium-palladium mixed-metal carbonyl clusters; molecular structures of [Os4Pd6(CO)8(µ-CO)5(µ3-CO)3(µ-dppm)2]·0.5C6H14 and [Os5Pd4(µ6-C)(CO)12(µ-CO)3(µ-dppm)2]·CH2Cl2
Authors
Issue Date1998
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal of the Chemical Society Dalton Transactions, 1998, n. 12, p. 2065-2070 How to Cite?
AbstractTreatment of [Os3(CO)10(µ-H)2] with [Pd2(µ-dppm)2Cl2] afforded the novel high-nuclearity osmium–palladium mixed-metal carbonyl clusters [Os5Pd6(CO)13(µ-CO)5(µ-H)2(µ-dppm)2] 1, [Os5Pd6(CO)13(µ-CO)6(µ-dppm)2] 2 and [Os4Pd6(CO)8(µ-CO)8(µ-dppm)2] 3 in low yield, while the reaction of [Os5(µ5-C)(CO)15] with [Pd2(µ-dppm)2Cl2] afforded [Os5Pd4(µ6-C)(CO)12(µ-CO)3(µ-dppm)2] 4 and [Os5(µ5-C)(CO)13(µ-dppm)] 5 in moderate yields. The molecular structures of clusters 3 and 4 have been determined.
Persistent Identifierhttp://hdl.handle.net/10722/68764
ISSN
2002 Impact Factor: 3.023

 

DC FieldValueLanguage
dc.contributor.authorHui, JWSen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:07:30Z-
dc.date.available2010-09-06T06:07:30Z-
dc.date.issued1998en_HK
dc.identifier.citationJournal of the Chemical Society Dalton Transactions, 1998, n. 12, p. 2065-2070en_HK
dc.identifier.issn1472-7773en_HK
dc.identifier.urihttp://hdl.handle.net/10722/68764-
dc.description.abstractTreatment of [Os3(CO)10(µ-H)2] with [Pd2(µ-dppm)2Cl2] afforded the novel high-nuclearity osmium–palladium mixed-metal carbonyl clusters [Os5Pd6(CO)13(µ-CO)5(µ-H)2(µ-dppm)2] 1, [Os5Pd6(CO)13(µ-CO)6(µ-dppm)2] 2 and [Os4Pd6(CO)8(µ-CO)8(µ-dppm)2] 3 in low yield, while the reaction of [Os5(µ5-C)(CO)15] with [Pd2(µ-dppm)2Cl2] afforded [Os5Pd4(µ6-C)(CO)12(µ-CO)3(µ-dppm)2] 4 and [Os5(µ5-C)(CO)13(µ-dppm)] 5 in moderate yields. The molecular structures of clusters 3 and 4 have been determined.-
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_HK
dc.relation.ispartofJournal of the Chemical Society Dalton Transactionsen_HK
dc.titleSyntheses and characterizaton of high-nuclearity osmium-palladium mixed-metal carbonyl clusters; molecular structures of [Os4Pd6(CO)8(µ-CO)5(µ3-CO)3(µ-dppm)2]·0.5C6H14 and [Os5Pd4(µ6-C)(CO)12(µ-CO)3(µ-dppm)2]·CH2Cl2en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1472-7773&volume=&spage=2065&epage=2070&date=1998&atitle=Syntheses+and+characterizaton+of+high-nuclearity+osmium-palladium+mixed-metal+carbonyl+clusters;++molecular+structures+of+[Os4Pd6(CO)8-(m-CO)5(m3-CO)3(m-dppm)2].0.5C6H14+and+[Os5Pd4(m6-C)(CO)12en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1039/A800817E-
dc.identifier.hkuros32604en_HK
dc.identifier.issue12-

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