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Article: Oxo-bridged metal carbene complexes. Synthesis, structure and reactivities of {[Os(Por)(CPh2)]2O} (Por = porphyrinato dianion)

TitleOxo-bridged metal carbene complexes. Synthesis, structure and reactivities of {[Os(Por)(CPh2)]2O} (Por = porphyrinato dianion)
Authors
Issue Date2003
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Chemical Communications, 2003, v. 9 n. 12, p. 1362-1363 How to Cite?
AbstractDinuclear μ-oxo osmium porphyrins containing terminal Os=CPh2 bonds with a linear C=Os-O-Os=C moiety were prepared, which are reactive toward pyridine to form [Os(Por)(CPh2)(py)] and are active catalysts for inter- and intra-molecular cyclopropanation of alkenes and for carbene insertion into saturated C-H bonds.
Persistent Identifierhttp://hdl.handle.net/10722/68759
ISSN
2015 Impact Factor: 6.567
2015 SCImago Journal Rankings: 2.771
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLi, Yen_HK
dc.contributor.authorHuang, JSen_HK
dc.contributor.authorZhou, ZYen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2010-09-06T06:07:27Z-
dc.date.available2010-09-06T06:07:27Z-
dc.date.issued2003en_HK
dc.identifier.citationChemical Communications, 2003, v. 9 n. 12, p. 1362-1363en_HK
dc.identifier.issn1359-7345en_HK
dc.identifier.urihttp://hdl.handle.net/10722/68759-
dc.description.abstractDinuclear μ-oxo osmium porphyrins containing terminal Os=CPh2 bonds with a linear C=Os-O-Os=C moiety were prepared, which are reactive toward pyridine to form [Os(Por)(CPh2)(py)] and are active catalysts for inter- and intra-molecular cyclopropanation of alkenes and for carbene insertion into saturated C-H bonds.en_HK
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_HK
dc.relation.ispartofChemical Communicationsen_HK
dc.titleOxo-bridged metal carbene complexes. Synthesis, structure and reactivities of {[Os(Por)(CPh2)]2O} (Por = porphyrinato dianion)en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1359-7345&volume=&spage=1362&epage=1363&date=2003&atitle=Oxo-bridged+metal+carbene+complexes.++Synthesis,+structure+and+reactivities+of+{[Os(Por)(CPh2)]2O}+(Por+=+porphyrinato+dianion)en_HK
dc.identifier.emailHuang, JS:jshuang@hkucc.hku.hken_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityHuang, JS=rp00709en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/B300441D-
dc.identifier.pmid12841242-
dc.identifier.scopuseid_2-s2.0-0038040772en_HK
dc.identifier.hkuros81081en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0038040772&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume9en_HK
dc.identifier.issue12en_HK
dc.identifier.spage1362en_HK
dc.identifier.epage1363en_HK
dc.identifier.isiWOS:000183215200019-
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridLi, Y=35187394200en_HK
dc.identifier.scopusauthoridHuang, JS=7407192639en_HK
dc.identifier.scopusauthoridZhou, ZY=7406096262en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK

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