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Article: Coordination networks from a bifunctional molecule containing carboxyl and thioether groups

TitleCoordination networks from a bifunctional molecule containing carboxyl and thioether groups
Authors
Issue Date2008
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 2008, v. 47 n. 17, p. 7459-7461 How to Cite?
AbstractThe bifunctional molecule tetrakis(methylthio)-1,4-benzenedicarboxylic acid (TMBD) interacts with the increasingly harder metal ions of CuI, CdII, and ZnII to form the coordination networks of Cu2TMBD, CdTMBD, and Zn4O(H2O) 3(TMBD)3, where the carboxyl group consistently bonds to metal ions, while the softer methylthio group binds with preference to the softer metal ions (i.e., chelation to Cu+, single-fold coordination to Cd2+, and nonbonding to Zn2+). Diffuse-reflectance spectra show that the metal-thioether interaction is associated with smaller electronic band gaps of the solid-state networks. © 2008 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/58469
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873
ISI Accession Number ID
Funding AgencyGrant Number
City University of Hong Kong7002119
Research Grants Council of HKSAR9041109
CityU102406
NSF0087210
Ohio Board of RegentsCAP-491
Youngstown State University
Funding Information:

This work is supported by City University of Hong Kong (Project No. 7002119) and the Research Grants Council of HKSAR [Project 9041109 (CityU 102406)]. The diffractometer was funded by NSF Grant 0087210, by Ohio Board of Regents Grant CAP-491, and by Youngstown State University.

References

 

DC FieldValueLanguage
dc.contributor.authorZhou, XPen_HK
dc.contributor.authorXu, Zen_HK
dc.contributor.authorZeller, Men_HK
dc.contributor.authorHunter, ADen_HK
dc.contributor.authorChui, SSYen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2010-05-31T03:30:51Z-
dc.date.available2010-05-31T03:30:51Z-
dc.date.issued2008en_HK
dc.identifier.citationInorganic Chemistry, 2008, v. 47 n. 17, p. 7459-7461en_HK
dc.identifier.issn0020-1669en_HK
dc.identifier.urihttp://hdl.handle.net/10722/58469-
dc.description.abstractThe bifunctional molecule tetrakis(methylthio)-1,4-benzenedicarboxylic acid (TMBD) interacts with the increasingly harder metal ions of CuI, CdII, and ZnII to form the coordination networks of Cu2TMBD, CdTMBD, and Zn4O(H2O) 3(TMBD)3, where the carboxyl group consistently bonds to metal ions, while the softer methylthio group binds with preference to the softer metal ions (i.e., chelation to Cu+, single-fold coordination to Cd2+, and nonbonding to Zn2+). Diffuse-reflectance spectra show that the metal-thioether interaction is associated with smaller electronic band gaps of the solid-state networks. © 2008 American Chemical Society.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_HK
dc.relation.ispartofInorganic Chemistryen_HK
dc.titleCoordination networks from a bifunctional molecule containing carboxyl and thioether groupsen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0020-1669&volume=47&spage=7459&epage=7461&date=2008&atitle=Coordination+Networks+from+a+Bifunctional+Molecule+Containing+Carboxyl+and+Thioether+Groups+en_HK
dc.identifier.emailChui, SSY: chuissy@hkucc.hku.hken_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.authorityChui, SSY=rp00686en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ic800952zen_HK
dc.identifier.pmid18683918-
dc.identifier.scopuseid_2-s2.0-51849161400en_HK
dc.identifier.hkuros150206en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-51849161400&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume47en_HK
dc.identifier.issue17en_HK
dc.identifier.spage7459en_HK
dc.identifier.epage7461en_HK
dc.identifier.isiWOS:000258709500006-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridZhou, XP=7410089784en_HK
dc.identifier.scopusauthoridXu, Z=9843801700en_HK
dc.identifier.scopusauthoridZeller, M=8518298000en_HK
dc.identifier.scopusauthoridHunter, AD=7402779700en_HK
dc.identifier.scopusauthoridChui, SSY=8297453100en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK

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