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Article: Organic polymer supports for synthesis and for reagent and catalyst immobilization

TitleOrganic polymer supports for synthesis and for reagent and catalyst immobilization
Authors
Issue Date2009
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/cr
Citation
Chemical Reviews, 2009, v. 109 n. 2, p. 815-838 How to Cite?
AbstractOrganic polymer supports for synthesis and for reagent and catalyst immobilization is studied. Some of the main considerations when choosing which polymer to use in a particular application include solvent compatibility and loading level. With regard to polymer loading level, it should be kept in mind that the maximum value for any polymer-supported reagent or catalyst is inversely proportional to the sum of the molecular weights of the reagent/catalyst group and the monomer used to prepare the polymer. Some of the greatest advancements in this field include the development of materials for heterogeneous metal catalyst encapsulation with which leaching of less than a part per million of the entrapped species is often observed. Polymers with desirable solubility profiles can be easily and quantitatively removed and reused using liquid/liquid biphasic separation methodologies, and it is anticipated that such materials will find increasing utility in the future.
Persistent Identifierhttp://hdl.handle.net/10722/58448
ISSN
2015 Impact Factor: 37.369
2015 SCImago Journal Rankings: 19.143
ISI Accession Number ID
Funding AgencyGrant Number
University of Hong Kong
Hong Kong Special Administrative Region, P. R. of ChinaHKU 704506P
HKU 704407P
HKU 704108P
Funding Information:

Our research is supported financially by the University of Hong Kong and by the Research Grants Council of the Hong Kong Special Administrative Region, P. R. of China (Project Nos. HKU 704506P, HKU 704407P, and HKU 704108P).

References
Grants

 

DC FieldValueLanguage
dc.contributor.authorLu, Jen_HK
dc.contributor.authorToy, PHen_HK
dc.date.accessioned2010-05-31T03:30:29Z-
dc.date.available2010-05-31T03:30:29Z-
dc.date.issued2009en_HK
dc.identifier.citationChemical Reviews, 2009, v. 109 n. 2, p. 815-838en_HK
dc.identifier.issn0009-2665en_HK
dc.identifier.urihttp://hdl.handle.net/10722/58448-
dc.description.abstractOrganic polymer supports for synthesis and for reagent and catalyst immobilization is studied. Some of the main considerations when choosing which polymer to use in a particular application include solvent compatibility and loading level. With regard to polymer loading level, it should be kept in mind that the maximum value for any polymer-supported reagent or catalyst is inversely proportional to the sum of the molecular weights of the reagent/catalyst group and the monomer used to prepare the polymer. Some of the greatest advancements in this field include the development of materials for heterogeneous metal catalyst encapsulation with which leaching of less than a part per million of the entrapped species is often observed. Polymers with desirable solubility profiles can be easily and quantitatively removed and reused using liquid/liquid biphasic separation methodologies, and it is anticipated that such materials will find increasing utility in the future.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/cren_HK
dc.relation.ispartofChemical Reviewsen_HK
dc.titleOrganic polymer supports for synthesis and for reagent and catalyst immobilizationen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0009-2665&volume=109&spage=815&epage=838&date=2009&atitle=Organic+Polymer+Supports+for+Synthesis+and+for+Reagent+and+Catalyst+Immobilization+en_HK
dc.identifier.emailToy, PH:phtoy@hkucc.hku.hken_HK
dc.identifier.authorityToy, PH=rp00791en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/cr8004444en_HK
dc.identifier.scopuseid_2-s2.0-65349139123en_HK
dc.identifier.hkuros155612en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-65349139123&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume109en_HK
dc.identifier.issue2en_HK
dc.identifier.spage815en_HK
dc.identifier.epage838en_HK
dc.identifier.isiWOS:000263562900016-
dc.publisher.placeUnited Statesen_HK
dc.relation.projectMultifunctional Polymeric Reagents and Catalysts for Organic Synthesis-
dc.relation.projectDevelopment and Optimization of Catalytic Versions of the Mitsunobu Reaction-
dc.identifier.scopusauthoridLu, J=26532871800en_HK
dc.identifier.scopusauthoridToy, PH=7006579247en_HK

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