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Article: Luminescence, electrochemistry and host-guest properties of dinuclear platinum(II) terpyridyl complexes of sulfur-containing bridging ligands

TitleLuminescence, electrochemistry and host-guest properties of dinuclear platinum(II) terpyridyl complexes of sulfur-containing bridging ligands
Authors
Issue Date2009
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Dalton Transactions, 2009 n. 20, p. 3911-3922 How to Cite?
AbstractA series of dinuclear platinum(ii) terpyridyl and terpyridyl-crown complexes with 2,2-dicyano-1,1-ethylenedithiolate (i-mnt), 1,3-benzenedithiolate (SC6H4S-1,3) and N,N-diethyldithiocarbamate (dtc) bridging ligands have been synthesized and characterized. Their photophysical and electrochemical properties, together with that of the related mononuclear platinum(ii) terpyridyl-crown complex and its crown-free analogue, have been studied. The ion-binding properties of the terpyridyl-crown complexes have been determined by electronic absorption spectroscopy and ESI-mass spectrometry. The X-ray crystal structures of [Pt(trpyCC-benzo-15-crown-5)Cl]PF6, [{Pt(trpy)}2(μ-SC6H4S-1,3)](PF 6)2 and [{Pt(trpy)}2{μ-(i-mnt)}](PF 6)2 have also been determined. © The Royal Society of Chemistry 2009.
Persistent Identifierhttp://hdl.handle.net/10722/58429
ISSN
2015 Impact Factor: 4.177
2015 SCImago Journal Rankings: 1.404
ISI Accession Number ID
Funding AgencyGrant Number
The University of Hong Kong
Strategic Research Theme on Molecular Materials
Faculty Development Fund of The University of Hong Kong
National Natural Science Foundation of China
Council of Hong Kong Joint Research SchemeN_HKU 737/06
Funding Information:

V.W.-W.Y. acknowledges support under the Distinguished Research Achievement Award Scheme from The University of Hong Kong. This work has been supported by the Strategic Research Theme on Molecular Materials, the Faculty Development Fund of The University of Hong Kong, and a National Natural Science Foundation of China and the Research Grants Council of Hong Kong Joint Research Scheme (NSFC-RGC project no. N_HKU 737/06) from the Research Grants Council of Hong Kong Special Administrative Region, P. R. China. Dr K.-K. Cheung is gratefully acknowledged for solving the crystal structures of 3 and 4. R. P.L. T. acknowledges the receipt of a postgraduate studentship, administered by The University of Hong Kong.

References
Grants

 

DC FieldValueLanguage
dc.contributor.authorTang, RPLen_HK
dc.contributor.authorWong, KMCen_HK
dc.contributor.authorZhu, Nen_HK
dc.contributor.authorYam, VWWen_HK
dc.date.accessioned2010-05-31T03:30:08Z-
dc.date.available2010-05-31T03:30:08Z-
dc.date.issued2009en_HK
dc.identifier.citationDalton Transactions, 2009 n. 20, p. 3911-3922en_HK
dc.identifier.issn1477-9226en_HK
dc.identifier.urihttp://hdl.handle.net/10722/58429-
dc.description.abstractA series of dinuclear platinum(ii) terpyridyl and terpyridyl-crown complexes with 2,2-dicyano-1,1-ethylenedithiolate (i-mnt), 1,3-benzenedithiolate (SC6H4S-1,3) and N,N-diethyldithiocarbamate (dtc) bridging ligands have been synthesized and characterized. Their photophysical and electrochemical properties, together with that of the related mononuclear platinum(ii) terpyridyl-crown complex and its crown-free analogue, have been studied. The ion-binding properties of the terpyridyl-crown complexes have been determined by electronic absorption spectroscopy and ESI-mass spectrometry. The X-ray crystal structures of [Pt(trpyCC-benzo-15-crown-5)Cl]PF6, [{Pt(trpy)}2(μ-SC6H4S-1,3)](PF 6)2 and [{Pt(trpy)}2{μ-(i-mnt)}](PF 6)2 have also been determined. © The Royal Society of Chemistry 2009.en_HK
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_HK
dc.relation.ispartofDalton Transactionsen_HK
dc.titleLuminescence, electrochemistry and host-guest properties of dinuclear platinum(II) terpyridyl complexes of sulfur-containing bridging ligandsen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1477-9226&volume=2009&spage=3911&epage=3922&date=2009&atitle=Luminescence,+Electrochemistry+and+Host-Guest+Properties+of+Dinuclear+Platinum(II)+Terpyridyl+Complexes+of+Sulfur-Containing+Bridging+Ligandsen_HK
dc.identifier.emailWong, KMC: wongmc@hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.emailYam, VWW: wwyam@hku.hken_HK
dc.identifier.authorityWong, KMC=rp00809en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/b821264cen_HK
dc.identifier.scopuseid_2-s2.0-65649095491en_HK
dc.identifier.hkuros158350en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-65649095491&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.issue20en_HK
dc.identifier.spage3911en_HK
dc.identifier.epage3922en_HK
dc.identifier.isiWOS:000266035000006-
dc.publisher.placeUnited Kingdomen_HK
dc.relation.projectSynthesis, aggregation and self-assembly of luminescent functional molecules - from solutions to polymers, ordered thin films, inorganic-organic hybrids, and supramolecular and nano-assemblies-
dc.identifier.scopusauthoridTang, RPL=7202300162en_HK
dc.identifier.scopusauthoridWong, KMC=8061067200en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK

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