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Article: 8-Quinolinolato complexes of ruthenium(II) and (III)

Title8-Quinolinolato complexes of ruthenium(II) and (III)
Authors
Keywords8-Quinolinolate
Alkene
Nitrogen ligands
Ruthenium
Issue Date2009
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ica
Citation
Inorganica Chimica Acta, 2009, v. 362 n. 4, p. 1149-1157 How to Cite?
AbstractReduction of RuQ3 (1a, Q = 8-quinolinolato) with Zn/Hg in the presence of various π-acceptor ligands in ethanol affords RuQ2L2 (L2 = (dimethylsulfoxide)2 (2); (4-picoline)2 (3); N,N′-dimethyl-1,4-diazabuta-1,3-diene, dab (4); cyclooctadiene, COD (5); norborna-2,5-diene, nbd (6)). Compound 6 is isolated as an equimolar mixture of cis,trans (6a) and trans,cis (6b) isomers, which can be separated by column chromatography. DFT calculations have been performed on 6a and 6b. Oxidation of 3 and 6b affords the corresponding ruthenium(III) species 7 and 8, respectively. The structures of 2, 3, 4 and 6 have been determined by X-ray crystallography. © 2008 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/58419
ISSN
2015 Impact Factor: 1.918
2015 SCImago Journal Rankings: 0.584
ISI Accession Number ID
Funding AgencyGrant Number
Research Grants Council of Hong KongCityU 101403
City University of Hong Kong7001925
Funding Information:

The work described in this paper was supported by the Research Grants Council of Hong Kong (CityU 101403) and the City University of Hong Kong (7001925).

References

 

DC FieldValueLanguage
dc.contributor.authorLeung, CFen_HK
dc.contributor.authorWong, CYen_HK
dc.contributor.authorKo, CCen_HK
dc.contributor.authorYuen, MCen_HK
dc.contributor.authorWong, WTen_HK
dc.contributor.authorWong, WYen_HK
dc.contributor.authorLau, TCen_HK
dc.date.accessioned2010-05-31T03:29:58Z-
dc.date.available2010-05-31T03:29:58Z-
dc.date.issued2009en_HK
dc.identifier.citationInorganica Chimica Acta, 2009, v. 362 n. 4, p. 1149-1157en_HK
dc.identifier.issn0020-1693en_HK
dc.identifier.urihttp://hdl.handle.net/10722/58419-
dc.description.abstractReduction of RuQ3 (1a, Q = 8-quinolinolato) with Zn/Hg in the presence of various π-acceptor ligands in ethanol affords RuQ2L2 (L2 = (dimethylsulfoxide)2 (2); (4-picoline)2 (3); N,N′-dimethyl-1,4-diazabuta-1,3-diene, dab (4); cyclooctadiene, COD (5); norborna-2,5-diene, nbd (6)). Compound 6 is isolated as an equimolar mixture of cis,trans (6a) and trans,cis (6b) isomers, which can be separated by column chromatography. DFT calculations have been performed on 6a and 6b. Oxidation of 3 and 6b affords the corresponding ruthenium(III) species 7 and 8, respectively. The structures of 2, 3, 4 and 6 have been determined by X-ray crystallography. © 2008 Elsevier B.V. All rights reserved.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/icaen_HK
dc.relation.ispartofInorganica Chimica Actaen_HK
dc.rightsInorganica Chimica Acta. Copyright © Elsevier BV.en_HK
dc.subject8-Quinolinolateen_HK
dc.subjectAlkeneen_HK
dc.subjectNitrogen ligandsen_HK
dc.subjectRutheniumen_HK
dc.title8-Quinolinolato complexes of ruthenium(II) and (III)en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0020-1693&volume=362&spage=1149&epage=1157&date=2009&atitle=8-Quinolinolato+Complexes+of+Ruthenium(II)+and+(III)en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.ica.2008.05.036en_HK
dc.identifier.scopuseid_2-s2.0-59649115384en_HK
dc.identifier.hkuros156626en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-59649115384&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume362en_HK
dc.identifier.issue4en_HK
dc.identifier.spage1149en_HK
dc.identifier.epage1157en_HK
dc.identifier.isiWOS:000263322200018-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridLeung, CF=8280665000en_HK
dc.identifier.scopusauthoridWong, CY=7404954160en_HK
dc.identifier.scopusauthoridKo, CC=7202596455en_HK
dc.identifier.scopusauthoridYuen, MC=24473842100en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK
dc.identifier.scopusauthoridWong, WY=7403972153en_HK
dc.identifier.scopusauthoridLau, TC=7102222310en_HK

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