File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Reaction of the 4-biphenylnitrenium ion with 4-biphenyl azide to produce a 4,4′-azobisbiphenyl stable product: A time-resolved resonance Raman and density functional theory study

TitleReaction of the 4-biphenylnitrenium ion with 4-biphenyl azide to produce a 4,4′-azobisbiphenyl stable product: A time-resolved resonance Raman and density functional theory study
Authors
Issue Date2008
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/jpca
Citation
Journal Of Physical Chemistry A, 2008, v. 112 n. 46, p. 11582-11589 How to Cite?
AbstractA time-resolved resonance Raman (TR 3) and density functional theory (DFT) study of the reaction of the 4-biphenylnitrenium ion with 4-biphenyl azide in a mixed aqueous solution is reported. The reaction of the 4-biphenylnitrenium ion with its unphotolyzed precursor 4-biphenyl azide in a mixed aqueous solution generates a 4,4′-azobisbiphenyl stable product via an intermediate species. With the aid of DFT calculations for likely transient species, this intermediate was tentatively assigned to a 4,4′- azobisbiphenyl cation. The DFT calculations predict this reaction can take place via two pathways that compete with one another to produce the trans and cis 4,4′-azobisbiphenyl product. The observation of the 4,4′- azobisbiphenyl cation intermediate demonstrates that the reaction of the arylnitrenium ion with its aryl azide to produce a stable azo product occurs via a stepwise mechanism. © 2008 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/58368
ISSN
2015 Impact Factor: 2.883
2015 SCImago Journal Rankings: 1.231
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorXue, Jen_HK
dc.contributor.authorDu, Yen_HK
dc.contributor.authorGuan, Xen_HK
dc.contributor.authorGuo, Zen_HK
dc.contributor.authorPhillips, DLen_HK
dc.date.accessioned2010-05-31T03:29:05Z-
dc.date.available2010-05-31T03:29:05Z-
dc.date.issued2008en_HK
dc.identifier.citationJournal Of Physical Chemistry A, 2008, v. 112 n. 46, p. 11582-11589en_HK
dc.identifier.issn1089-5639en_HK
dc.identifier.urihttp://hdl.handle.net/10722/58368-
dc.description.abstractA time-resolved resonance Raman (TR 3) and density functional theory (DFT) study of the reaction of the 4-biphenylnitrenium ion with 4-biphenyl azide in a mixed aqueous solution is reported. The reaction of the 4-biphenylnitrenium ion with its unphotolyzed precursor 4-biphenyl azide in a mixed aqueous solution generates a 4,4′-azobisbiphenyl stable product via an intermediate species. With the aid of DFT calculations for likely transient species, this intermediate was tentatively assigned to a 4,4′- azobisbiphenyl cation. The DFT calculations predict this reaction can take place via two pathways that compete with one another to produce the trans and cis 4,4′-azobisbiphenyl product. The observation of the 4,4′- azobisbiphenyl cation intermediate demonstrates that the reaction of the arylnitrenium ion with its aryl azide to produce a stable azo product occurs via a stepwise mechanism. © 2008 American Chemical Society.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/jpcaen_HK
dc.relation.ispartofJournal of Physical Chemistry Aen_HK
dc.subject.meshAminobiphenyl Compounds - chemistryen_HK
dc.subject.meshAzides - chemistryen_HK
dc.subject.meshAzo Compounds - chemistryen_HK
dc.subject.meshBiphenyl Compounds - chemistryen_HK
dc.subject.meshQuantum Theoryen_HK
dc.subject.meshSpectrum Analysis, Ramanen_HK
dc.subject.meshStereoisomerismen_HK
dc.subject.meshTime Factorsen_HK
dc.titleReaction of the 4-biphenylnitrenium ion with 4-biphenyl azide to produce a 4,4′-azobisbiphenyl stable product: A time-resolved resonance Raman and density functional theory studyen_HK
dc.typeArticleen_HK
dc.identifier.emailPhillips, DL:phillips@hku.hken_HK
dc.identifier.authorityPhillips, DL=rp00770en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/jp805353qen_HK
dc.identifier.pmid18956852-
dc.identifier.scopuseid_2-s2.0-57249092739en_HK
dc.identifier.hkuros157115en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-57249092739&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume112en_HK
dc.identifier.issue46en_HK
dc.identifier.spage11582en_HK
dc.identifier.epage11589en_HK
dc.identifier.isiWOS:000260926700011-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridXue, J=23007272500en_HK
dc.identifier.scopusauthoridDu, Y=35310175500en_HK
dc.identifier.scopusauthoridGuan, X=8313149700en_HK
dc.identifier.scopusauthoridGuo, Z=36554069300en_HK
dc.identifier.scopusauthoridPhillips, DL=7404519365en_HK

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats