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Article: A noncentrosymmetric 3D coordination polymer of metallocalix[4]arene

TitleA noncentrosymmetric 3D coordination polymer of metallocalix[4]arene
Authors
Liu, YJHuang, JSChui, SSYLi, CHZuo, JLZhu, NChe, CM
Issue Date2008
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 2008, v. 47 n. 24, p. 11514-11518 How to Cite?
DOI: http://dx.doi.org/10.1021/ic8008859
AbstractSequential reaction of a lower-rim functionalized calix[4]arene, 25,27-bis(hydroxycarbonylmethoxy)-26,28-dimethoxy-p-tert-butylcalix[4]arene (H 2L C4), with K 2CO 3 and CoCl 2·6H 2O in ethanol afforded a 3D coordination polymer [K 3Co 2(L C4) 3(EtOH) 6]Cl (1). X-ray crystal analysis revealed that 1 features a noninterpenetrated (10,3)-a net structure wherein octahedral Co 2+ ions serve as the three-connecting nodes and [K(L C4)] - units function as the bridges between the Co 2+ ions. The calixarene ligands in 1 adopt a 1,3-alternate conformation, and there are considerable cation-π interactions between the K + ion and the phenyl rings within each [K(L C4)] - unit. © 2008 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/58348
ISSN
0020-1669
2023 Impact Factor: 4.3
2023 SCImago Journal Rankings: 0.928
ISI Accession Number ID
WOS:000261510100012
Funding AgencyGrant Number
Nanjing University
The University of Hong Kong
Hong Kong Research Grants CouncilHKU 7027/05P
Funding Information:

This work was supported by Nanjing University, The University of Hong Kong (University Development Fund; Strategic Research Theme on Bionanotechnology), and Hong Kong Research Grants Council (HKU 7027/05P). We are grateful to a reviewer for pointing out the potential problem associated with the original X-ray structure determination.

References
References in Scopus
Grants
Functionalization of Iron-, Ruthenium-, and Osmium-Sulfur Clusters with Terminal Metal-Carbene, -Imido, or -Nitrido Bonds

 

DC FieldValueLanguage
dc.contributor.authorLiu, YJen_HK
dc.contributor.authorHuang, JSen_HK
dc.contributor.authorChui, SSYen_HK
dc.contributor.authorLi, CHen_HK
dc.contributor.authorZuo, JLen_HK
dc.contributor.authorZhu, Nen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2010-05-31T03:28:44Z-
dc.date.available2010-05-31T03:28:44Z-
dc.date.issued2008en_HK
dc.identifier.citationInorganic Chemistry, 2008, v. 47 n. 24, p. 11514-11518en_HK
dc.identifier.issn0020-1669en_HK
dc.identifier.urihttp://hdl.handle.net/10722/58348-
dc.description.abstractSequential reaction of a lower-rim functionalized calix[4]arene, 25,27-bis(hydroxycarbonylmethoxy)-26,28-dimethoxy-p-tert-butylcalix[4]arene (H 2L C4), with K 2CO 3 and CoCl 2·6H 2O in ethanol afforded a 3D coordination polymer [K 3Co 2(L C4) 3(EtOH) 6]Cl (1). X-ray crystal analysis revealed that 1 features a noninterpenetrated (10,3)-a net structure wherein octahedral Co 2+ ions serve as the three-connecting nodes and [K(L C4)] - units function as the bridges between the Co 2+ ions. The calixarene ligands in 1 adopt a 1,3-alternate conformation, and there are considerable cation-π interactions between the K + ion and the phenyl rings within each [K(L C4)] - unit. © 2008 American Chemical Society.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_HK
dc.relation.ispartofInorganic Chemistryen_HK
dc.titleA noncentrosymmetric 3D coordination polymer of metallocalix[4]areneen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0020-1669&volume=47&spage=11514&epage=11518&date=2008&atitle=A+Noncentrosymmetric+3D+Coordination+Polymer+of+Metallocalix[4]+Arene+en_HK
dc.identifier.emailHuang, JS: jshuang@hku.hken_HK
dc.identifier.emailChui, SSY: chuissy@hkucc.hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.authorityHuang, JS=rp00709en_HK
dc.identifier.authorityChui, SSY=rp00686en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ic8008859en_HK
dc.identifier.scopuseid_2-s2.0-60849136655en_HK
dc.identifier.hkuros155700en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-60849136655&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume47en_HK
dc.identifier.issue24en_HK
dc.identifier.spage11514en_HK
dc.identifier.epage11518en_HK
dc.identifier.eissn1520-510X-
dc.identifier.isiWOS:000261510100012-
dc.publisher.placeUnited Statesen_HK
dc.relation.projectFunctionalization of Iron-, Ruthenium-, and Osmium-Sulfur Clusters with Terminal Metal-Carbene, -Imido, or -Nitrido Bonds-
dc.identifier.scopusauthoridLiu, YJ=27171988400en_HK
dc.identifier.scopusauthoridHuang, JS=7407192639en_HK
dc.identifier.scopusauthoridChui, SSY=8297453100en_HK
dc.identifier.scopusauthoridLi, CH=35242660500en_HK
dc.identifier.scopusauthoridZuo, JL=7202871908en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.issnl0020-1669-

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