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Article: The phosphine-catalyzed alkyne to 1,3-diene isomerization reaction

TitleThe phosphine-catalyzed alkyne to 1,3-diene isomerization reaction
Authors
Keywords1,3-dienes
Alkynes
Isomerization reactions
Organocatalysis
Phosphines
Issue Date2008
PublisherGeorg Thieme Verlag. The Journal's web site is located at www.thieme-chemistry.com
Citation
Synthesis, 2008 n. 15, p. 2307-2317 How to Cite?
AbstractThe alkyne to 1,3-diene isomerization reaction is a process in which a nucleophilic phosphine catalyst promotes the rearrangement of an electron-withdrawing group activated alkyne to the corresponding conjugated diene. The origin, mechanism, development, and application of this organocatalytic and stereoselective reaction in the synthesis of complex organic molecules are reviewed. © Georg Thieme Verlag Stuttgart.
Persistent Identifierhttp://hdl.handle.net/10722/58345
ISSN
2015 Impact Factor: 2.652
2015 SCImago Journal Rankings: 1.115
ISI Accession Number ID
Funding AgencyGrant Number
Hong Kong Special Administrative Region, P. R. of ChinaHKU 7045/06P
Funding Information:

Our research is supported financially by the University of Hong Kong and the Research Grants Council of the Hong Kong Special Administrative Region, P. R. of China (Project HKU 7045/06P). We also thank Polymer Laboratories for gifts of materials, and The Institute of Scientific and Industrial Research at Osaka University and Prof. Hiroaki Sasai for generously providing a Visiting Scholar position to P.H.T., during which time much of this manuscript was researched and prepared.

References
Grants

 

DC FieldValueLanguage
dc.contributor.authorKwong, CKWen_HK
dc.contributor.authorFu, MYen_HK
dc.contributor.authorLam, CSLen_HK
dc.contributor.authorToy, PHen_HK
dc.date.accessioned2010-05-31T03:28:41Z-
dc.date.available2010-05-31T03:28:41Z-
dc.date.issued2008en_HK
dc.identifier.citationSynthesis, 2008 n. 15, p. 2307-2317en_HK
dc.identifier.issn0039-7881en_HK
dc.identifier.urihttp://hdl.handle.net/10722/58345-
dc.description.abstractThe alkyne to 1,3-diene isomerization reaction is a process in which a nucleophilic phosphine catalyst promotes the rearrangement of an electron-withdrawing group activated alkyne to the corresponding conjugated diene. The origin, mechanism, development, and application of this organocatalytic and stereoselective reaction in the synthesis of complex organic molecules are reviewed. © Georg Thieme Verlag Stuttgart.en_HK
dc.languageengen_HK
dc.publisherGeorg Thieme Verlag. The Journal's web site is located at www.thieme-chemistry.comen_HK
dc.relation.ispartofSynthesisen_HK
dc.subject1,3-dienesen_HK
dc.subjectAlkynesen_HK
dc.subjectIsomerization reactionsen_HK
dc.subjectOrganocatalysisen_HK
dc.subjectPhosphinesen_HK
dc.titleThe phosphine-catalyzed alkyne to 1,3-diene isomerization reactionen_HK
dc.typeArticleen_HK
dc.identifier.emailToy, PH:phtoy@hkucc.hku.hken_HK
dc.identifier.authorityToy, PH=rp00791en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1055/s-2008-1067173en_HK
dc.identifier.scopuseid_2-s2.0-49649129658en_HK
dc.identifier.hkuros155624en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-49649129658&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.issue15en_HK
dc.identifier.spage2307en_HK
dc.identifier.epage2317en_HK
dc.identifier.isiWOS:000258374700001-
dc.publisher.placeGermanyen_HK
dc.relation.projectPolymer-supported phosphine and arsines as reagents, ligands and organic catalysts-
dc.identifier.scopusauthoridKwong, CKW=13306659700en_HK
dc.identifier.scopusauthoridFu, MY=24576708700en_HK
dc.identifier.scopusauthoridLam, CSL=24576830000en_HK
dc.identifier.scopusauthoridToy, PH=7006579247en_HK

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