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- Publisher Website: 10.1055/s-2008-1067173
- Scopus: eid_2-s2.0-49649129658
- WOS: WOS:000258374700001
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Article: The phosphine-catalyzed alkyne to 1,3-diene isomerization reaction
Title | The phosphine-catalyzed alkyne to 1,3-diene isomerization reaction | ||||
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Authors | |||||
Keywords | 1,3-dienes Alkynes Isomerization reactions Organocatalysis Phosphines | ||||
Issue Date | 2008 | ||||
Publisher | Georg Thieme Verlag. The Journal's web site is located at www.thieme-chemistry.com | ||||
Citation | Synthesis, 2008 n. 15, p. 2307-2317 How to Cite? | ||||
Abstract | The alkyne to 1,3-diene isomerization reaction is a process in which a nucleophilic phosphine catalyst promotes the rearrangement of an electron-withdrawing group activated alkyne to the corresponding conjugated diene. The origin, mechanism, development, and application of this organocatalytic and stereoselective reaction in the synthesis of complex organic molecules are reviewed. © Georg Thieme Verlag Stuttgart. | ||||
Persistent Identifier | http://hdl.handle.net/10722/58345 | ||||
ISSN | 2023 Impact Factor: 2.2 2023 SCImago Journal Rankings: 0.582 | ||||
ISI Accession Number ID |
Funding Information: Our research is supported financially by the University of Hong Kong and the Research Grants Council of the Hong Kong Special Administrative Region, P. R. of China (Project HKU 7045/06P). We also thank Polymer Laboratories for gifts of materials, and The Institute of Scientific and Industrial Research at Osaka University and Prof. Hiroaki Sasai for generously providing a Visiting Scholar position to P.H.T., during which time much of this manuscript was researched and prepared. | ||||
References | |||||
Grants |
DC Field | Value | Language |
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dc.contributor.author | Kwong, CKW | en_HK |
dc.contributor.author | Fu, MY | en_HK |
dc.contributor.author | Lam, CSL | en_HK |
dc.contributor.author | Toy, PH | en_HK |
dc.date.accessioned | 2010-05-31T03:28:41Z | - |
dc.date.available | 2010-05-31T03:28:41Z | - |
dc.date.issued | 2008 | en_HK |
dc.identifier.citation | Synthesis, 2008 n. 15, p. 2307-2317 | en_HK |
dc.identifier.issn | 0039-7881 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/58345 | - |
dc.description.abstract | The alkyne to 1,3-diene isomerization reaction is a process in which a nucleophilic phosphine catalyst promotes the rearrangement of an electron-withdrawing group activated alkyne to the corresponding conjugated diene. The origin, mechanism, development, and application of this organocatalytic and stereoselective reaction in the synthesis of complex organic molecules are reviewed. © Georg Thieme Verlag Stuttgart. | en_HK |
dc.language | eng | en_HK |
dc.publisher | Georg Thieme Verlag. The Journal's web site is located at www.thieme-chemistry.com | en_HK |
dc.relation.ispartof | Synthesis | en_HK |
dc.subject | 1,3-dienes | en_HK |
dc.subject | Alkynes | en_HK |
dc.subject | Isomerization reactions | en_HK |
dc.subject | Organocatalysis | en_HK |
dc.subject | Phosphines | en_HK |
dc.title | The phosphine-catalyzed alkyne to 1,3-diene isomerization reaction | en_HK |
dc.type | Article | en_HK |
dc.identifier.email | Toy, PH:phtoy@hkucc.hku.hk | en_HK |
dc.identifier.authority | Toy, PH=rp00791 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1055/s-2008-1067173 | en_HK |
dc.identifier.scopus | eid_2-s2.0-49649129658 | en_HK |
dc.identifier.hkuros | 155624 | en_HK |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-49649129658&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.issue | 15 | en_HK |
dc.identifier.spage | 2307 | en_HK |
dc.identifier.epage | 2317 | en_HK |
dc.identifier.isi | WOS:000258374700001 | - |
dc.publisher.place | Germany | en_HK |
dc.relation.project | Polymer-supported phosphine and arsines as reagents, ligands and organic catalysts | - |
dc.identifier.scopusauthorid | Kwong, CKW=13306659700 | en_HK |
dc.identifier.scopusauthorid | Fu, MY=24576708700 | en_HK |
dc.identifier.scopusauthorid | Lam, CSL=24576830000 | en_HK |
dc.identifier.scopusauthorid | Toy, PH=7006579247 | en_HK |
dc.identifier.issnl | 0039-7881 | - |