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Article: Crystallographic and infrared spectroscopic study of bond distances in Ln[Fe(CN)6]·4H2O (Ln=lanthanide)

TitleCrystallographic and infrared spectroscopic study of bond distances in Ln[Fe(CN)6]·4H2O (Ln=lanthanide)
Authors
KeywordsBond distance
Covalo-electrostatic model
Crystal structure
Infrared spectra
Lanthanide contraction
Issue Date2008
PublisherAcademic Press. The Journal's web site is located at http://www.elsevier.com/locate/jssc
Citation
Journal Of Solid State Chemistry, 2008, v. 181 n. 11, p. 3057-3064 How to Cite?
AbstractAlong with crystallographic data of Ln[Fe(CN)6]·4H2O (Ln=lanthanide), the infrared spectra are reassigned to examine bond length trends across the series of Ln. The changes in mean Ln-O, Ln-N, C{triple bond, long}N and Fe-C distances are discussed and the bond natures of Ln-N and Ln-O are studied by bond length linear or quadratic fitting and comparisons with relevant ionic radii. The two different C{triple bond, long}N bond distances have been simulated by the covalo-electrostatic model. © 2008 Elsevier Inc. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/58336
ISSN
2015 Impact Factor: 2.265
2015 SCImago Journal Rankings: 0.703
ISI Accession Number ID
Funding AgencyGrant Number
Hong Kong University Grants Commission Earmarked Research102607
National Natural Science Foundation of China10704090
Funding Information:

Financial support of this work by the Hong Kong University Grants Commission Earmarked Research Grant CityU 102607 is gratefully acknowledged. X.J. acknowledges the financial support from the National Natural Science Foundation of China (Grant no. 10704090). We thank Dr. Dominique Guillaumont for preliminary calculations and for drawing our attention to Refs. [25,26].

References

 

DC FieldValueLanguage
dc.contributor.authorZhou, Xen_HK
dc.contributor.authorWong, WTen_HK
dc.contributor.authorFaucher, MDen_HK
dc.contributor.authorTanner, PAen_HK
dc.date.accessioned2010-05-31T03:28:31Z-
dc.date.available2010-05-31T03:28:31Z-
dc.date.issued2008en_HK
dc.identifier.citationJournal Of Solid State Chemistry, 2008, v. 181 n. 11, p. 3057-3064en_HK
dc.identifier.issn0022-4596en_HK
dc.identifier.urihttp://hdl.handle.net/10722/58336-
dc.description.abstractAlong with crystallographic data of Ln[Fe(CN)6]·4H2O (Ln=lanthanide), the infrared spectra are reassigned to examine bond length trends across the series of Ln. The changes in mean Ln-O, Ln-N, C{triple bond, long}N and Fe-C distances are discussed and the bond natures of Ln-N and Ln-O are studied by bond length linear or quadratic fitting and comparisons with relevant ionic radii. The two different C{triple bond, long}N bond distances have been simulated by the covalo-electrostatic model. © 2008 Elsevier Inc. All rights reserved.en_HK
dc.languageengen_HK
dc.publisherAcademic Press. The Journal's web site is located at http://www.elsevier.com/locate/jsscen_HK
dc.relation.ispartofJournal of Solid State Chemistryen_HK
dc.subjectBond distanceen_HK
dc.subjectCovalo-electrostatic modelen_HK
dc.subjectCrystal structureen_HK
dc.subjectInfrared spectraen_HK
dc.subjectLanthanide contractionen_HK
dc.titleCrystallographic and infrared spectroscopic study of bond distances in Ln[Fe(CN)6]·4H2O (Ln=lanthanide)en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-4596&volume=181&spage=3057&epage=3064&date=2008&atitle=Crystallographic+and+Infrared+Spectroscopic+Study+of+Bond+Distances+in+Ln[Fe(CN)6].4H2O+(Ln=+Lanthanide)en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.jssc.2008.08.008en_HK
dc.identifier.scopuseid_2-s2.0-55649118664en_HK
dc.identifier.hkuros160659en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-55649118664&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume181en_HK
dc.identifier.issue11en_HK
dc.identifier.spage3057en_HK
dc.identifier.epage3064en_HK
dc.identifier.isiWOS:000266250200014-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridZhou, X=8615278600en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK
dc.identifier.scopusauthoridFaucher, MD=7007068467en_HK
dc.identifier.scopusauthoridTanner, PA=7101679850en_HK

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